CARBOXYL-CONTAINING BUTADIENE-STYRENE COPOLYMERS

    公开(公告)号:AU544153B2

    公开(公告)日:1985-05-16

    申请号:AU7488181

    申请日:1981-09-02

    Applicant: BASF AG

    Abstract: Aqueous low-emulsifier dispersions of emulsion copolymers which contain, as copolymerized units, (a) from 35 to 55% by weight of butadiene, (b) from 35 to 60% by weight of styrene, (c) from 1 to 3% by weight of alpha , beta -monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 6 carbon atoms, (d) from 1 to 3% by weight of amides of alpha , beta -monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 5 carbon atoms, (e) from 1 to 4% by weight of N-methylolamides of alpha , beta -monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 5 carbon atoms, or their alkyl ethers, and (f) from 1 to 3% by weight of acrylic acid and/or methacrylic acid monoesters of alkanediols of 2 to 6 carbon atoms, the emulsion containing, as emulsifier, from 0.1 to 0.8% by weight, based on emulsion copolymers, of fatty alcohol-sulfonates and/or alkylbenzenesulfonates, where alkyl is of 12 to 16 carbon atoms, are of particular value as binders for aqueous anti-corrosion paints.

    PROCEDIMIENTO PARA LA OBTENCION DE UNA DISPERSION ACUOSA DE POLIMEROS.

    公开(公告)号:ES2285470T3

    公开(公告)日:2007-11-16

    申请号:ES04739590

    申请日:2004-06-04

    Applicant: BASF AG

    Abstract: Procedimiento para la obtención de una dispersión acuosa de polímeros mediante polimerización de, al menos, un monómero B etilénicamente insaturado en medio acuoso en presencia de partículas de, al menos, un polímero A (partículas polímeras A) y de, al menos, un agente dispersante, caracterizado porque se lleva a cabo la polimerización de, al menos, un monómero B, etilénicamente insaturado, en presencia de partículas polímeras A con un diámetro de las partículas, promedio en peso, = 1 nm, habiéndose obtenido el polímero A bien a) mediante una polimerización iniciada con, al menos, un iniciador por medio de radicales o b) mediante una polimerización iniciada con, al menos, un complejo de metal de transición de al menos un monómero A etilénicamente insaturado (monómero A) y la polimerización de, al menos, un monómero B etilénicamente insaturado (monómero B) se inicia i) en el caso a) por medio de, al menos, un complejo de metal de transición y ii) en el caso b) por medio de, al menos, un iniciador por medio de radicales.

    CARBOXYL-CONTAINING BUTADIENE-STYRENE COPOLYMERS

    公开(公告)号:AU7488181A

    公开(公告)日:1982-03-11

    申请号:AU7488181

    申请日:1981-09-02

    Applicant: BASF AG

    Abstract: Aqueous low-emulsifier dispersions of emulsion copolymers which contain, as copolymerized units, (a) from 35 to 55% by weight of butadiene, (b) from 35 to 60% by weight of styrene, (c) from 1 to 3% by weight of alpha , beta -monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 6 carbon atoms, (d) from 1 to 3% by weight of amides of alpha , beta -monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 5 carbon atoms, (e) from 1 to 4% by weight of N-methylolamides of alpha , beta -monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 5 carbon atoms, or their alkyl ethers, and (f) from 1 to 3% by weight of acrylic acid and/or methacrylic acid monoesters of alkanediols of 2 to 6 carbon atoms, the emulsion containing, as emulsifier, from 0.1 to 0.8% by weight, based on emulsion copolymers, of fatty alcohol-sulfonates and/or alkylbenzenesulfonates, where alkyl is of 12 to 16 carbon atoms, are of particular value as binders for aqueous anti-corrosion paints.

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