METHOD FOR PRODUCING 1-SUBSTITUTED 5- OR 3-HYDROXYPYRAZOLES
    22.
    发明申请
    METHOD FOR PRODUCING 1-SUBSTITUTED 5- OR 3-HYDROXYPYRAZOLES 审中-公开
    制备1-取代的5-或3-羟基吡唑的方法

    公开(公告)号:WO0031042A3

    公开(公告)日:2000-10-26

    申请号:PCT/EP9908516

    申请日:1999-11-06

    CPC classification number: C07D231/20

    Abstract: The invention relates to a method for producing 1-substituted 5- and/or 3-hydroxypyrazoles of formulas (I) and (II), wherein R represents C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, C3-C6-cycloalkyl or C1-C4-alkoxy, whereby these groups can be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or a cyclic ring system with 3-14 ring atoms, by reacting a 3-alkoxyacrylic acid alkyl ester of formula (III), wherein R , R independently mean C1-C6-alkyl or C3-C6-cycloalky, with a hydrazine of formula (IV), wherein R has the above cited meaning, a) at a pH value of 6-11 to form 5-hydroxypyrazoles of formula (I), or b) at a pH value of 11-14 to form 3-hydroxypyrazoles of formula (II).

    Abstract translation: 本发明涉及一种制备1-取代的5和/或所述式(I)和(II),其中R <1> C1-C6-烷基,C2-C6链烯基,C2-C6的3-羟基吡 炔基,C3-C6环烷基或C1-C4烷氧基,其中这些基团被卤素,C1-C4烷氧基,苯氧基,C1-C6烷氧羰基,C1-C6烷硫基羰基或具有3-14个环原子的环系 可以由式(III)的烷基3- alkoxyacrylates被取代,其中R <2>,R <3>独立地是C1-C6烷基或C3-C6环烷基与式的肼(Ⅳ) 其中R <1>具有上面给出的含义,a)在pH值下式I)的6-11(约5-羟基吡唑反应而,或b)在pH为11-14,得到3- hydroxypyrazoles 的式(II)。

    1-(1,2-DIPHENYL-ETHYL)-3-(2-HYDROXYETHYL)-THIOUREA COMPOUNDS FOR COMBATING ANIMAL PESTS
    23.
    发明申请
    1-(1,2-DIPHENYL-ETHYL)-3-(2-HYDROXYETHYL)-THIOUREA COMPOUNDS FOR COMBATING ANIMAL PESTS 审中-公开
    1-(1,2-二苯基乙基)-3-(2-羟基乙基) - 硫脲化合物,用于组合动物饲料

    公开(公告)号:WO2006125745A3

    公开(公告)日:2007-05-10

    申请号:PCT/EP2006062413

    申请日:2006-05-18

    CPC classification number: C07C335/12 A01N47/28

    Abstract: The present invention relates to a method of combating animal pests which comprises contacting the animal pest, their habit, breeding ground, food supply, plant, seed, soil, area, material or environment in which the animal pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from animal at- tack or infestation, with a pesticidally effective amount of at least one 1-(1 ,2-diphenyl- ethyl)-3-(2-hydroxyethyl)-thiourea compound I or an agriculturally acceptable salt thereof, wherein m is 0 to 5, n is 0 to 5, R 3 and R 4 are H or optionally substituted alkyl, haloalkyl, cycloalkyl, phenyl or benzyl, R 7 , R 8 , R 9 and R 10 are H or optionally substituted C 1 -C 6 -alkyl, C 1 -C 6 -haloalkyl, C 1 -C 6 - alkylamino, C 1 -C 6 -alkoxy, C 3 -C 6 -cycloalkyl, phenyl or benzyl and the variables R 1 , R 2 , R 5 and R 6 are as defined in the claims. The invention relates also to a method for protecting crops from attack or infestation by animal pests, a method for protecting non-living materials from attack or infestation by animal pests, novel 1-(1 ,2-diphenyl-ethyl)-3-(2-hydroxyethyl)-thiourea compounds I and their agriculturally acceptable salts as well as to an agricultural composition comprising a 1-(1 ,2-diphenyl-ethyl)-3-(2-hydroxyethyl)-thiourea compound I or a salt thereof.

    Abstract translation: 本发明涉及一种防治动物害虫的方法,包括使动物害虫,其习惯,繁殖地,食物供应,植物,种子,土壤,区域,动物害虫生长或可能生长的物质或环境接触;或 防止动物死亡或侵染的材料,植物,种子,土壤,表面或空间,具有杀虫有效量的至少一种1-(1,2-二苯基 - 乙基)-3-(2-羟乙基 ) - 硫脲化合物I或其农业上可接受的盐,其中m为0至5,n为0至5,R 3和R 4为H或任选取代的烷基 ,卤代烷基,环烷基,苯基或苄基,R 7,R 8,R 9和R 10是H 或任选取代的C 1 -C 6 - 烷基,C 1 -C 6 - 卤代烷基,C 1,R 2,R 5和R 6如权利要求中所定义。 本发明还涉及一种保护作物免受动物害虫侵袭或侵袭的方法,一种保护非生物材料免受动物害虫侵袭或侵染的方法,新的1-(1,2-二苯基 - 乙基)-3-( 2-羟乙基) - 硫脲化合物I及其农业上可接受的盐,以及包含1-(1,2-二苯基 - 乙基)-3-(2-羟乙基) - 硫脲化合物I或其盐的农业组合物。

    N-CYCLOALKYL-3-ALKENYLBENZOYL-PYRAZOLE DERIVATIVES
    25.
    发明申请
    N-CYCLOALKYL-3-ALKENYLBENZOYL-PYRAZOLE DERIVATIVES 审中-公开
    N-环烷基-3- ALKENYLBENZOYL-吡唑衍生物

    公开(公告)号:WO0104096A2

    公开(公告)日:2001-01-18

    申请号:PCT/EP0005860

    申请日:2000-06-23

    CPC classification number: A01N43/56 C07D231/20

    Abstract: The invention relates to cycloalkyl-substituted benzoyl pyrazoles of formula (I) wherein said variables can, for example, have the following meanings: R = hydrogen, nitro, halogen, cyano, rhodano or an optionally substituted aliphatic radical; R = an optionally substituted aliphatic radical, halogen, nitro, in addition to substituted sulfonyl or amino groups; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-halogenalkyl, C1-C6-alkoxy, C2-C6-alkenyl or C2-C6-alkinyl; R , R = hydrogen, nitro, halogen, cyano, rhodano, an optionally substituted aliphatic radical or substituted sulfonyl or amino groups; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R = a cyclic ring system with 3 - 14 ring atoms; R = hydroxy or a substituted hydroxy group; in addition to tautomers or agriculturally useful salts thereof. The invention also relates to methods for the production of compounds of formula (I), agents containing said compounds, the use of compounds of formula (I) and agents containing said compounds as pesticides.

    Abstract translation: 本发明的目的是式(I),其中变量具有环烷基取代的benzoylpyrazoles,例如,以下的含义:R t <1>为氢,硝基,卤素,氰基,氰硫基或任选取代的脂族基团; [R <2>是任选取代的脂族基,卤素,硝基,和取代的磺酰基或氨基; [R <3>是氢,卤素,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C2-C6烯基或C2-C6炔基; [R <4>,R <5>为氢,硝基,卤素,氰基,氰硫基,任选取代的脂族基或取代的磺酰基或氨基基团; [R <6>是氢,卤素,C1-C6烷基,C1-C6烷氧基,C3-C8环烷基; [R <7>具有3-14个环原子的环状环体系; [R <16>为羟基或取代羟基; 和互变异构体或可农用盐。 此外,本发明提供了制备式(I)的化合物的方法,是指含有它们,并使用式(I)和组合物的化合物的包含它们用于控制有害植物而言。

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