公开(公告)号：DE2452804A1

公开(公告)日：1976-05-13

申请号：DE2452804

申请日：1974-11-07

Applicant: BASF AG

Inventor： HIMMELE WALTER DIPL CHEM DR ,  SIEGEL HARDO DIPL CHEM DR

IPC: C07D323/06 ,  C07D323/04

公开(公告)号：DE3001303A1

公开(公告)日：1981-07-23

申请号：DE3001303

申请日：1980-01-16

Applicant: BASF AG

Inventor： MARTIN CHRISTOPH DIPL CHEM DR ,  HIMMELE WALTER DIPL CHEM DR ,  SIEGEL HARDO DIPL CHEM DR

IPC: C12P7/40 ,  A01N43/84 ,  C07C27/00 ,  C07C33/18 ,  C07C33/20 ,  C07C33/24 ,  C07C41/00 ,  C07C43/20 ,  C07C43/23 ,  C07C43/303 ,  C07C51/00 ,  C07C57/30 ,  C07C59/64 ,  C07C67/00 ,  C07C69/612 ,  C07D265/30 ,  C07D295/02 ,  C07D295/03 ,  C12P7/16 ,  C12P7/22 ,  C12P7/24 ,  C12R1/865

Abstract: S-Configurated phenylpropane derivatives of the formula where R1 is alkyl, aryl or alkoxy, R2 is hydrogen, alkyl, aryl or alkoxy, and R3 is carboxyl or esterified carboxyl, acetalized formyl, hydroxymethyl or esterified hydroxymethyl, their preparation by microbiological hydrogenation, and their use for the preparation of fungicidal compounds.

公开(公告)号：DE2938698A1

公开(公告)日：1981-04-09

申请号：DE2938698

申请日：1979-09-25

Applicant: BASF AG

Inventor： GOETZ NORBERT DIPL CHEM DR ,  HIMMELE WALTER DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR

IPC: C07D265/30 ,  B01J23/60 ,  B01J23/656 ,  C07B61/00 ,  C07D295/023

公开(公告)号：DE2932527A1

公开(公告)日：1981-02-26

申请号：DE2932527

申请日：1979-08-10

Applicant: BASF AG

Inventor： HIMMELE WALTER DIPL CHEM DR ,  HOFFMANN WERNER DIPL CHEM DR

IPC: C07C41/16 ,  A61K8/33 ,  A61Q13/00 ,  B01J31/00 ,  C07B61/00 ,  C07C41/00 ,  C07C41/18 ,  C07C41/26 ,  C07C43/10 ,  C07C43/13 ,  C07C45/00 ,  C07C45/49 ,  C07C45/50 ,  C07C47/198 ,  C07C67/00 ,  C11B9/00 ,  C11D3/50 ,  C07C47/02 ,  C07C43/04 ,  A61K7/00 ,  A61L9/01

Abstract: Bis-tert.-butoxypentanals and bis-tert.butoxypentanols of the formula where R1 and R2 are H or C1 to C4 alkyl, one X is -CHO or -CH2OH and the others are H. These compounds, which are valuable as fragrances and for use in organic syntheses are obtained by carrying out a catalytic hydroformylation, using a rhodium catalyst, of a bis-ether of the formula

公开(公告)号：DE2911467A1

公开(公告)日：1980-10-02

申请号：DE2911467

申请日：1979-03-23

Applicant: BASF AG

Inventor： HIMMELE WALTER DIPL CHEM DR ,  NAARMANN HERBERT DIPL CHEM DR ,  PENZIEN KLAUS DIPL CHEM DR ,  VIEHE HEINZ GUENTER PROF DIPL ,  BEAUJEAN MICHEL

IPC: C08K5/20 ,  C08L101/00 ,  C07C103/82 ,  C07C103/44 ,  C07C127/15 ,  D06M13/20

Abstract: N-Alkylamides of formula R-CO-NR1R2 (I) (where R is opt. substd. aryl, -NR1R2, -(CH2)n-CONR1R2, -CH=CH-CO-NR1R2; n is 1-4; x is 1-3; Y is 1-4 and R1 and R2 are opt. identical, linear or branched 1-4C alkyl) are dimerised and/or oligomerised by heating with organic peroxides at 130-200 degrees C in a protective gas atmos. The dimers and oligomers are new. The prods. can be used as high-boiling solvents and as oligomeric C-C labile synergetic cpds. for the flame-retarding and antistatic finishing of fibres and plastic foils. The prods. do not "sweat" out of plastics and have a high complex bonding capacity for metal salts.

公开(公告)号：DE2907614A1

公开(公告)日：1980-09-04

申请号：DE2907614

申请日：1979-02-27

Applicant: BASF AG

Inventor： HIMMELE WALTER DIPL CHEM DR ,  POMMER ERNST-HEINRICH DR ,  SIEGEL HARDO DIPL CHEM DR

IPC: A01N43/84 ,  C07D265/30 ,  C07D295/02 ,  C07D295/03 ,  A01N9/22

公开(公告)号：DE2753152A1

公开(公告)日：1979-06-07

申请号：DE2753152

申请日：1977-11-29

Applicant: BASF AG

Inventor： KARG JOCHEN DIPL CHEM DR ,  PATSCH MANFRED DIPL CHEM DR ,  HIMMELE WALTER DIPL CHEM DR

IPC: C09B57/08 ,  C07D221/14 ,  D06L3/12 ,  C07D405/06

公开(公告)号：DE2611664A1

公开(公告)日：1977-09-29

申请号：DE2611664

申请日：1976-03-19

Applicant: BASF AG

Inventor： HIMMELE WALTER DIPL CHEM DR ,  AQUILA WERNER DIPL CHEM DR ,  WOERZ OTTO DIPL CHEM DR

IPC: C07C69/02

Abstract: Prodn. of allyl esters (I) of the formula CH2=CH-CHR'-O-CO-R" (in which R' is 1-4C alkyl, opt. with an acyloxy substit. with max. 4C. alkyl or H) involves isomerisation of allyl esters (II) of the formula R'-CH=CH-CH2-O-CO-R" at elevated temp., as in DT 2406058, in the presence of Cu and/or Cu (I) or Cu (II) cpds. and in the presence of carboxylic acids (III). The improvement comprises the use of carbocylic anhydride (IV) in addn. to (III). (IV) pref. is the anhydride of (III), esp. acetic anhydride (IVa), and is used in an amt. of 0.1-10 mole-% wrt (III). In an example but-2-en-1,4-diyl acetate was isomerise to but-2-en-3,4-diyl acetate in the presence of (IVa) the yield being 10% and amt. of by-prods. 1%. If (IVa) was omitted, the yield was up to 2.5% and amt of by-prods. 1.5%. (I) are used as starting materials in organic syntheses.

公开(公告)号：DE2551172A1

公开(公告)日：1977-05-26

申请号：DE2551172

申请日：1975-11-14

Applicant: BASF AG

Inventor： HOFFMANN WERNER DIPL CHEM DR ,  HIMMELE WALTER DIPL CHEM DR

IPC: C07C45/49 ,  C07C45/66 ,  C07C49/403 ,  C07C49/613 ,  C07C49/753 ,  C11B9/00 ,  C07C49/48

Abstract: Prepn. of cyclohex-2-en-1-ones having formula (I) (where R1 and R2 each is satd. 1-20C hydrocarbyl or Ph or R1 and R2 are linked to form a 5- or 6-membered cycloalkyl gp. R3 and R4 may be H or non-linked R1 and R2-type gps.). Prepn. comprises hydroformylating a ketone having formula (II), using Rh catalysts, and dehydrating the obtd. formyl derivs., (III), under acid conditions, with ring-closure. (I) are odoriferous materials with a wide range of wood-notes. (I) can also be used as intermediates in prepn. of mono-, sesqui- and diterpenes. E.g. 4-isopropyl-cyclohex-2-en-1-one can be converted to menth-2-en-1-ol, followed by allyl rearrangement and hydrogenation to d,1-menthol. In an example, 4-isopropyl-cyclohex-2-en-1-one was prepd. by (i) hydroformylation of 6-methyl-hept-5-en-2-one to 5-formyl-6-methyl-heptan-2-one and (ii) dehydration and ring-closure with H3PO4.

公开(公告)号：DE2526748A1

公开(公告)日：1976-12-30

申请号：DE2526748

申请日：1975-06-14

Applicant: BASF AG

Inventor： HIMMELE WALTER DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR ,  TOUSSAINT HERBERT DIPL CHEM DR ,  PAUL GERHARD DIPL CHEM DR

IPC: C07C49/175 ,  C07C41/42 ,  C07C45/00 ,  C07C67/00 ,  C07C45/24