公开(公告)号：DE3123302A1

公开(公告)日：1983-01-05

申请号：DE3123302

申请日：1981-06-12

Applicant: BASF AG

Inventor： GOETZ NORBERT DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR ,  FRANZISCHKA WOLFGANG DIPL ING

IPC: B01J23/00 ,  B01J23/44 ,  B01J23/48 ,  B01J23/50 ,  B01J23/56 ,  B01J23/58 ,  B01J23/60 ,  B01J23/63 ,  B01J23/656 ,  B01J23/89 ,  C07B61/00 ,  C07D207/32 ,  C07D207/323

公开(公告)号：DE2651578A1

公开(公告)日：1978-06-22

申请号：DE2651578

申请日：1976-11-12

Applicant: BASF AG

Inventor： DOCKNER TONI DIPL CHEM DR ,  KRUG HERBERT ,  TOUSSAINT HERBERT DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR ,  DECKER MARTIN DIPL CHEM DR

IPC: C07C209/18 ,  C07C87/62

Abstract: In parent patent, the continuous prodn. of N-alkylarylamines (I) comprises gas-phase reaction of arylamines (II) with alcohols (III) and/or dialkyl ethers (IV) at 180-450 degrees C in presence of carriers contg. oxyacids of P. The catalyst used is silica of internal surface 50-500 m2/g and H3PO4 content 0.1-20 wt.% and during the reaction H3PO4 and/or alkyl phosphates are continuously supplied to the catalyst. In this addition (II) and (III) or (IV) are introduced as gases at a temp. equal to or greater than the reaction temp. By using the reactants to heat the catalyst, surface coking is reduced.

公开(公告)号：DE2725669A1

公开(公告)日：1978-12-07

申请号：DE2725669

申请日：1977-06-06

Applicant: BASF AG

Inventor： MERKEL KARL DR ,  TOUSSAINT HERBERT DIPL CHEM DR ,  MUELLER HERBERT DIPL CHEM DR ,  HOFFMANN HERWIG DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR ,  MERCKER HANS JOCHEN DIPL CHEM

IPC: C07C209/26 ,  C07C87/127 ,  C07C85/08

公开(公告)号：DE2547623A1

公开(公告)日：1977-04-28

申请号：DE2547623

申请日：1975-10-24

Applicant: BASF AG

Inventor： HUPFER LEOPOLD DIPL CHEM DR ,  MUELLER HERBERT DIPL CHEM DR ,  FLIEGE WERNER DIPL CHEM DR ,  MERKEL KARL ,  HOFFMANN HERWIG DIPL CHEM DR

IPC: C07C93/04

Abstract: New 3-methyl-pentan-1,5-diol-bis(3-aminopropyl) ether is produced by hydrogenation (viz., e.g. DS 2254720) of the corresp. dinitrile which, in turn is made by reaction of 3-methyl-pentan-1,5-diol with 2 mols acrylonitrile (viz. DT 2121325). In an example, an 80% methanolic soln. of the dinitrile was hydrogenated at 200 bars. (I) was obtd. in 98% yield.

公开(公告)号：DE2543279A1

公开(公告)日：1977-04-07

申请号：DE2543279

申请日：1975-09-27

Applicant: BASF AG

Inventor： GOETZ NORBERT DIPL CHEM DR ,  ZEEH BERND DIPL CHEM DR ,  DECKER MARTIN DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR ,  TOUSSAINT HERBERT DIPL CHEM DR

IPC: C07D295/02 ,  C07D295/023 ,  C07D295/03 ,  C07D295/033 ,  C07D265/30

Abstract: A new process for the manufacture of N-substituted tetrahydro-1,4-oxazines, also called morpholines, by conversion of N-substituted bis-(2-hydroxyalkyl)-amines in the presence of catalysts.

公开(公告)号：DE3209148A1

公开(公告)日：1983-09-22

申请号：DE3209148

申请日：1982-03-13

Applicant: BASF AG

Inventor： GOETZ NORBERT DIPL CHEM DR ,  ROHR WOLFGANG DIPL CHEM DR ,  MANGOLD DIETRICH DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR ,  DOCKNER TONI DIPL CHEM DR ,  KEMPE UWE DIPL CHEM DR

IPC: C07D231/12

公开(公告)号：DE3039085A1

公开(公告)日：1982-05-27

申请号：DE3039085

申请日：1980-10-16

Applicant: BASF AG

Inventor： GOETZ NORBERT DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR ,  HOFFMANN WERNER DIPL CHEM DR ,  BAUMANN MANFRED DIPL CHEM DR

IPC: B01J23/00 ,  B01J23/44 ,  C07C67/00 ,  C07C209/00 ,  C07C209/18 ,  C07C209/24 ,  C07C209/26 ,  C07C211/45 ,  C07C213/00 ,  C07C213/02 ,  C07C85/08 ,  C07C87/50 ,  C07C87/66 ,  C07C93/14

Abstract: Aromatic amines, in particular substituted amines, are obtained from corresponding alicyclic alcohols or ketones, in one step, by amination and dehydrogenation with ammonia in the presence of hydrogen and of a palladium catalyst which also contains zinc or cadmium.

公开(公告)号：DE2938698A1

公开(公告)日：1981-04-09

申请号：DE2938698

申请日：1979-09-25

Applicant: BASF AG

Inventor： GOETZ NORBERT DIPL CHEM DR ,  HIMMELE WALTER DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR

IPC: C07D265/30 ,  B01J23/60 ,  B01J23/656 ,  C07B61/00 ,  C07D295/023

公开(公告)号：DE2545655A1

公开(公告)日：1977-04-21

申请号：DE2545655

申请日：1975-10-11

Applicant: BASF AG

Inventor： HUPFER LEOPOLD DIPL CHEM DR ,  MUELLER HERBERT DIPL CHEM DR ,  FLIEGE WERNER DIPL CHEM DR ,  MERKEL KARL DR ,  HOFFMANN HERWIG DIPL CHEM DR

IPC: C07C121/34

Abstract: New 3-methyl-pentan-2,5-diol-bis(2-cyanoethyl) ether is of formula NC-(CH2)2-O-(CH2)2-CH(CH3)-(CH2)2-O-(CH2)2-CN (I) (I) is an intermediate in the prodn. of the corresponding diamine which in turn can be used to prepare epoxy resins and polyurethanes. (I) is also useful as a polar solvent and an additive for minerals and propellants. (I) is made by reaction of 2 mols acrylonitrile and 3-methyl-penta-1,5-diol.

公开(公告)号：DE2526748A1

公开(公告)日：1976-12-30

申请号：DE2526748

申请日：1975-06-14

Applicant: BASF AG

Inventor： HIMMELE WALTER DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR ,  TOUSSAINT HERBERT DIPL CHEM DR ,  PAUL GERHARD DIPL CHEM DR

IPC: C07C49/175 ,  C07C41/42 ,  C07C45/00 ,  C07C67/00 ,  C07C45/24