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公开(公告)号:DE3617070A1
公开(公告)日:1987-11-26
申请号:DE3617070
申请日:1986-05-21
Applicant: BASF AG
Inventor: LAUSBERG DIETRICH DR , TAUBITZ CHRISTOF DR , KNOLL MANFRED
IPC: C08L7/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L67/02 , C08L67/03 , C08L69/00 , C08L101/00 , C08J5/00
Abstract: Thermoplastic molding materials contain, as essential components, (A) from 10 to 89% by weight of a blend of (A1) from 20 to 98% by weight, based on (A1)+(A2), of a polyester of an aromatic dicarboxylic acid and an aliphatic dihydroxy compound and (A2) from 2 to 80% by weight, based on (A1)+(A2), of a polyester of an aromatic dicarboxylic acid and an aromatic dihydroxy compound of the formula I (I) or its C1-C6-alkyl or halogen derivative substituted in the nucleus, where Z is an alkylene or cycloalkylene group of not more than 8 carbon atoms, an arylene group of not more than 12 carbon atoms, -O-, -S-, or a chemical bond and m is 0 or 1, (B) from 10 to 89% by weight of a polycarbonate and (C) from 1 to 30% by weight of a rubber toughener having a glass transition temperature of less than -30 DEG C.
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公开(公告)号:MY122687A
公开(公告)日:2006-04-29
申请号:MYPI20000257
申请日:2000-01-26
Applicant: BASF AG
Inventor: FISCHER MICHAEL DR , KNOLL MANFRED , GINSS CHRISTOPHE , BERZ STEPHAN
IPC: C08J5/04 , B32B5/18 , C08K7/02 , B32B27/36 , C08K3/04 , C08L25/12 , C08L51/00 , C08L51/04 , C08L55/02 , C08L67/00 , C08L67/02 , C08L69/00 , C08L87/00
Abstract: A PROCESS FOR THE PREPARATION OF FIBER-REINFORCED MOLDINGS FOR MOTOR VEHICLES WHEREIN THE MOLDING COMPRISES (A) FROM 1 TO 96.86% BY WEIGHT OF AT LEAST ONE POLYCONDENSATE, (B) FROM 1 TO 12% BY WEIGHT OF AT LEAST ONE PARTICULATE GRAFT COPOLYMER WHOSE SOFT PHASE HAS A GLASS TRANSITION TEMPERATURE BELOW 0?C. AND WHOSE MEDIAN PARTICLE SIZE IS FROM 50 TO 1000 NM, (C) FROM 1 TO 12% BY WEIGHT OF AT LEAST ONE COPOLYMER MADE FROM THE FOLLOWING MONOMERS, (C1) FROM 50 TO 90% BY WEIGHT OF AT LEAST ONE VINYLAROMATRIC MONOMER, AND (C2) FROM 10 TO 50% BY WEIGHT OF ACRYLONITRILE AND/OR METHACRYLONITRILE, BASED IN EACH CASE ON COMPONENT C, (D) FROM 0 TO 20% BY WEIGHT OF (E) FROM 0.01 TO 15% BY WEIGHT OF POLYCARBONATE, (F) FROM 0.01 TO 2% BY WEIGHT OF A CARBON BLACK, (G) FROM 0 TO 12% BY WEIGHT OF A POLYMER OTHER THAN COMPONENT B, (H) FROM 0 TO 20% BY WEIGHT OF A POLYESTER OTHER THAN COMPONENT A, (I) FROM 0.1 TO 10% BY WEIGHT OF CONVENTIONAL ADDITIVES, SUCH AS UV STABILIZERS, OXIDATION RETARDERS, LUBRICANTS AND MOLD-RELEASE AGENTS. MOLDINGS AND COMPOSITES MADE FROM THESE MOLDING COMPOSITIONS ARE AS DESCRIBED AS IS THE USE OF THE MOLDING COMPOSITIONS, THE MOLDINGS AND THE COMPOSITES.
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公开(公告)号:AU2541600A
公开(公告)日:2000-08-18
申请号:AU2541600
申请日:2000-01-14
Applicant: BASF AG
Inventor: FISCHER MICHAEL , KNOLL MANFRED , GINSS CHRISTOPHE , BERZ STEPHAN
IPC: C08J5/04 , B32B5/18 , B32B27/36 , C08K3/04 , C08K7/02 , C08L25/12 , C08L51/00 , C08L51/04 , C08L55/02 , C08L67/02 , C08L69/00 , C08L87/00
Abstract: A process for the preparation of fiber-reinforced moldings for motor vehicles wherein the molding comprisesa) from 1 to 96.86% by weight of at least one polycondensate,b) from 1 to 12% by weight of at least one particulate graft copolymer whose soft phase has a glass transition temperature below 0° C. and whose median particle size is from 50 to 1000 nm,c) from 1 to 12% by weight of at least one copolymer made from the following monomers,c1) from 50 to 90% by weight of at least one vinylaromatic monomer, andc2) from 10 to 50% by weight of acrylonitrile and/or methacrylonitrile, based in each case on component c,d) from 0 to 20% by weight ofe) from 0.01 to 15% by weight of a polycarbonate,f) from 0.01 to 2% by weight of a carbon black,g) from 0 to 12% by weight of a polymer other than component B,h) from 0 to 20% by weight of a polyester other than component A,i) from 0.1 to 10% by weight of conventional additives, such as UV stabilizers, oxidation retarders, lubricants and mold-release agents. Moldings and composites made from these molding compositions are as described as is the use of the molding compositions, the moldings and the composites.
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公开(公告)号:AU3275700A
公开(公告)日:2000-08-01
申请号:AU3275700
申请日:2000-01-04
Applicant: BASF AG
Inventor: WEBER MARTIN , ULMERICH KARLHEINZ , ZELTNER DORIS , KNOLL MANFRED
IPC: C08K5/5393 , C08L67/02 , C08L67/00
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公开(公告)号:AU6467499A
公开(公告)日:2000-04-26
申请号:AU6467499
申请日:1999-10-01
Applicant: BASF AG
Inventor: FISCHER MICHAEL , KNOLL MANFRED , GINSS CHRISTOPHE , BERZ STEPHAN
IPC: C08F265/04 , C08F279/02 , C08K3/04 , C08K5/00 , C08L25/08 , C08L25/12 , C08L25/14 , C08L51/00 , C08L51/06 , C08L55/02 , C08L67/02 , C08L101/00
Abstract: A thermoplastic molding composition comprises, based on the total of components A to C and, if desired, D and E, which in total give 100% by weight,a) as component A, from 10 to 98% by weight of at least one aromatic polyester,b) as component B, from 1 to 50% by weight of at least one particulate graft copolymer whose soft phase has a glass transition temperature below 0° C. and whose median particle size is from 50 to 1000 nm,c) as component C, from 1 to 50% by weight of at least one copolymer made from the following monomersc1) as component C1, from 50 to 90% by weight of at least one vinylaromatic monomer, andc2) as component C2, from 10 to 25% by weight of acrylonitrile and/or methacrylonitrile,d) as component D, from 0 to 25% by weight of other compatible polymers hormogeneously miscible with components A and/or C or dispersible in these, ande) as component E, from 0 to 10% by weight of conventional additives, such as UV stabilizers, carbon black, pigments, oxidation retarders, lubricants and mold-release agents.Moldings made from these molding compositions and used in motor vehicle interiors are also described, as is the use of the molding compositions to produce the moldings.
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公开(公告)号:ES2122734T3
公开(公告)日:1998-12-16
申请号:ES96104698
申请日:1996-03-25
Applicant: BASF AG
Inventor: GAREISS BRIGITTE , KNOLL MANFRED , PLACHETTA CHRISTOPH
IPC: C09K21/14 , C08K3/00 , C08K3/01 , C08K3/22 , C08K3/30 , C08K3/38 , C08K5/03 , C08K5/103 , C08K13/02 , C08L67/00 , C08L67/02 , C08L69/00
Abstract: A flameproof thermoplastic moulding compsn. contains (A) 10-97.9 wt.% of a thermoplastic polyester, (B) 1-20% of decabromodiphenylethane (I), (C) 1-15% of a metal oxide, a metal sulphide and/or metal borate, (D) 0.1-5% of an ester of an alcohol with at least 3 OH gps. and a 5-34C aliphatic mono- or di-carboxylic acid and (E) 0-70% of the usual additives and processing aids.
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公开(公告)号:AT171717T
公开(公告)日:1998-10-15
申请号:AT96104698
申请日:1996-03-25
Applicant: BASF AG
Inventor: GAREISS BRIGITTE , KNOLL MANFRED , PLACHETTA CHRISTOPH
IPC: C09K21/14 , C08K3/00 , C08K3/01 , C08K3/22 , C08K3/30 , C08K3/38 , C08K5/03 , C08K5/103 , C08K13/02 , C08L67/00 , C08L67/02 , C08L69/00
Abstract: A flameproof thermoplastic moulding compsn. contains (A) 10-97.9 wt.% of a thermoplastic polyester, (B) 1-20% of decabromodiphenylethane (I), (C) 1-15% of a metal oxide, a metal sulphide and/or metal borate, (D) 0.1-5% of an ester of an alcohol with at least 3 OH gps. and a 5-34C aliphatic mono- or di-carboxylic acid and (E) 0-70% of the usual additives and processing aids.
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公开(公告)号:DE3877681D1
公开(公告)日:1993-03-04
申请号:DE3877681
申请日:1988-10-01
Applicant: BASF AG
Inventor: LAUSBERG DIETRICH DR , SEYDL WOLFGANG DR , KNOLL MANFRED , SEILER ERHARD DR , GUTSCHE HERBERT , KOLM PETER
Abstract: Thermoplastic moulding materials comprises as essential components (A) 49-90 wt.% of a mixt. of (a1) 50-80 wt.% of a polyester, (a2) 10-25 wt.% of a graft polymer made from (a21) 50-90 wt.% of a backbone of a rubbery elastic polymer based on (a211) 95-99.9 wt.% of a 2-10C alkyl acrylate and (a212) 0.1-5 wt.% of a polyfunctional monomer with at least two olefinic, non-conjugated double bonds, and (a22) 10-50 wt.% grafted material comprising (a221) 50-90 wt.% of styrene or a substd. styrene of formula (I) in which R = 1-8C alkyl, H, or halogen, R1 = 1-8C alkyl or halgoen and n = 0,1,2 or 3 mixts. of these, (a222) wt.% (meth)acrylonitrile, and (a223) 0-10 wt.% monomers contg. carboxyl, carboxyl deriv., OH or epoxy gps.; and (a3) 10-25% of a copolymer of (a31) 55-90 wt.% of a styrene or substd. styrene of formula (I), (a32) 10-45 wt.% (meth)acrylonitrile and (a33) 0-10 wt.% monomers contg. carboxyl, carboxyl deriv., OH or epoxy gps.; and (B) 5-50 wt.% glass fibres, with the proviso that the proportion of component (a32) calculated on total wt. of component (a3) is at least 5 wt.% lower than the proportion by wt. of component (a222) calculated on the total wt. of component (a22).
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公开(公告)号:DE3877680D1
公开(公告)日:1993-03-04
申请号:DE3877680
申请日:1988-10-01
Applicant: BASF AG
Inventor: LAUSBERG DIETRICH DR , SEILER ERHARD DR , HECKMANN WALTER DR , KNOLL MANFRED
Abstract: Thermoplastic moulding materials comprising (A) 49-90 wt.% of a mixt. of (a1) 50-80 wt.% of a polyester, (a2) 10-25 wt.% of a graft polymer made from (a21) 50-90 wt.% of a backbone of a rubbery elastic polymer based on (a211) 95-99.9 wt.% of a 2-10C alkyl acrylate and (a212) 0.1-5 wt.% of a polyfunctional monomer with at least two olefinic, non-conjugated double bonds, and (a22) 10-50 wt.% grafted material comprising (a221) 5-50 wt.% of a first shell of styrene or substd. styrene of formula (I) in which R = 1-8C alkyl, H, or halogen, R1 = 1-8C alkyl or halogen and n = 0, 1, 2 or 3 or mixts. of these, and (a222) 50-95 wt.% of a second grafted shell of (a2221) 80-100 wt.% methacrylic acid or its esters whose polymers in the absence of (a21) have a Tg of more than 40 deg. C, and 0-20 wt.% further comonomers, and (a3) 10-25 wt.% of a copolymer of (a31) 50-90 wt.% of a styrene or subt. styrene of formula (I) or mixts. of these, (a32) 10-50 wt.% (meth)acrylonitrile and (a33) 0-10 wt.% monomers contg. carboxyl, carboxyl derivs., OH or epoxy gps.; and (B) 5-50 wt.% glass fibres.
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公开(公告)号:DE4022988A1
公开(公告)日:1992-01-23
申请号:DE4022988
申请日:1990-07-19
Applicant: BASF AG
Inventor: MCKEE GRAHAM EDMUND DR , HECKMANN WALTER DR , BUESCHL RAINER DR , KNOLL MANFRED
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