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    24.
    发明专利
    未知

    公开(公告)号：ES2143702T3

    公开(公告)日：2000-05-16

    申请号：ES96117834

    申请日：1996-11-07

    Applicant: BASF AG

    Inventor： HIBST HARTMUT PROF DR ,  TENTEN ANDREAS DR ,  MAROSI LASZLO DR

    IPC: C01G1/00 ,  B01J23/00 ,  B01J23/20 ,  B01J23/28 ,  B01J23/30 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  C01G31/00 ,  C01G39/00 ,  C01G41/00 ,  C07B61/00 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C45/38 ,  C07C51/235 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055

    Abstract: A multimetal oxide of formula (I) Mo12-a-b-cVaM bM cOx is new, where: M = tungsten (W) and/or niobium (Nb); M = titanium (Ti), zirconium (Zr), hafnium (Hf), tantalum (Ta), chromium (Cr), silicon (Si) and/or germanium (Ge); a = 0.1-6; b = 0-6; c = 0-6; a+b+c = 0.1-6; and x = number determined by the valency and frequency of the element in (I) except oxygen. Its atomic space arrangement is determined by powder X-ray diffraction (the intensity A of the diffracted X-ray beam as a function of two-fold diffraction angle (2&thetas; )) using Cu-K alpha -radiation ( lambda = 1.54178 Angstrom ), so that in the 2&thetas; region of 5-50 degrees the following diffraction lines are produced: Al(X-ray diffraction line) = 8.3 plus or minus 0.7 (2&thetas; degrees ); A2=14.4 plus or minus 0.7; A3=22.3 plus or minus 0.2; A4=23.5 plus or minus 0.7; A5=27.2 plus or minus 0.4; A6=32.0 plus or minus 0.8; A7=34.8 plus or minus 0.6; A8=38.7 plus or minus 0.5; A9=45.4 plus or minus 0.4; and A10=48.8 plus or minus 0.4. Also claimed are: (i) a process for catalytic gas phase oxidation of organic compounds using the above multimetal oxide; and (ii) a finely divided mixture containing the above multimetal oxide (I) and a multimetal oxide (II) of formula: M 12CudHeOy, where: M = molybdenum (Mo), W, vanadium (V), Nb and/or Ta; d = 4-30; e = 0-20; and y = a number determined by the valency and frequency of the elements in (II) except oxygen.

    MATERIALS BASED ON MULTI-METAL OXIDES
    26.
    发明专利
    MATERIALS BASED ON MULTI-METAL OXIDES 未知

    公开(公告)号：CZ214696A3

    公开(公告)日：1997-08-13

    申请号：CZ214696

    申请日：1996-07-19

    Applicant: BASF AG

    Inventor： HIBST HARTMUT PROF DR ,  TENTEN ANDREAS DR ,  MAROSI LASZLO DR

    IPC: B01J23/88 ,  B01J23/00 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  C01G31/00 ,  C01G39/00 ,  C07B61/00 ,  C07C51/235 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055

    Abstract: Multi-metal oxide compsn. of general formula ÄAÜpÄBÜq (I) is new (where, A = Mo12Va(X b)(X c)(X d)X e)(X f )(X g)Ox, B = X 12CuhHiOy (promoter phase); X = W, Nb, Ta, Cr and/or Ce; X = Cu, Ni, Co, Fe, M n and/or Zn; X = Sb and/or Bi; X = Li, Na, K, Rb, Cs and/or H; X = Mg, Ca, Sr and/or Br; X = Si, Al, Ti and/or Zr; X = Mo, W, V, Nb and/or Ta; a = 1-8; b = 0.2-5; c = 0-23; d = 0-50; e = 0-2; f = 0-5; g = 0-50; h = 4-30; i = 0-20; x, y = values determining the valency and frequency of elements different from oxygen in the compsn.; and p, q = values other than zero, whose ratio p/q = 160-1:1. The proportions of (A)p and (B)q are in the form of chemical compsns. differing from their local environment. A and B are distributed relative to each other such as a mixt. of finely divided A and finely divided B, with the proviso that B contains crystals B* of oxometallates of formula CuMoaWbVcNbdTeOy (II) (where, a/(A+B+C+D+E)=0.7-1.3; (B+C+D+E)/A = 0.01-1; and Y = a value determined by the valency and frequency of elements in (II) different from oxygen) of a new structure type (HT-Cu molybdate) defined by the X-ray diffraction pattern: d(A)=6.79+/-0.3; 3.56+/-0.3; 3.54+/-0.3, 3.40+/-0.3; 3.04+/-0.3, 2.96+/-0.3; 2.67+/-0.2; 2.66+/-0.2; 2.56+/-0.2, 2.36+/-0.2; 2.35+/-0.2; 2.27+/-0.2; 2.00+/-0.2;1.87+/-0.3; 1.70+/-0.2; 1.64+/-0.2; 1.59+/-0.2; 1.57+/-0.2; 1.57+/-0.2; 1.55+/-0.2; 1.51+/-0.2; 1.44+/-0.2. Also claimed are: (i) the oxometallates of formula (II); (ii) mixt. of oxometallates (II); (iii) prodn. of the multi-metal oxide compsn..

    27.
    发明专利
    未知

    公开(公告)号：ES2100373T3

    公开(公告)日：1997-06-16

    申请号：ES93101155

    申请日：1993-01-27

    Applicant: BASF AG

    Inventor： FISCHER ROLF DR ,  DOSTALEK ROMAN DR ,  MAROSI LASZLO DR

    IPC: B01J23/89 ,  C07B61/00 ,  C07C5/11 ,  C07C13/20

    Abstract: Process for the preparation of cyclohexene by partial hydrogenation of benzene with hydrogen in the presence of water and ruthenium catalysts which are modified with nickel, at elevated temperature in the liquid phase, characterised in that the catalysts used are ruthenium/nickel alloys.

    28.
    发明专利
    未知

    公开(公告)号：DE59306144D1

    公开(公告)日：1997-05-22

    申请号：DE59306144

    申请日：1993-01-27

    Applicant: BASF AG

    Inventor： FISCHER ROLF DR ,  DOSTALEK ROMAN DR ,  MAROSI LASZLO DR

    IPC: B01J23/89 ,  C07B61/00 ,  C07C5/11 ,  C07C13/20

    Abstract: Process for the preparation of cyclohexene by partial hydrogenation of benzene with hydrogen in the presence of water and ruthenium catalysts which are modified with nickel, at elevated temperature in the liquid phase, characterised in that the catalysts used are ruthenium/nickel alloys.

    Multi:metal oxide useful as catalyst esp. in gas phase oxidn. of acrolein to acrylic acid
    29.
    发明专利
    Multi:metal oxide useful as catalyst esp. in gas phase oxidn. of acrolein to acrylic acid 未知

    公开(公告)号：DE4405514A1

    公开(公告)日：1995-08-24

    申请号：DE4405514

    申请日：1994-02-22

    Applicant: BASF AG

    Inventor： TENTEN ANDREAS DR ,  HIBST HARTMUT DR ,  MARTIN FRIEDRICH-GEORG DR ,  MAROSI LASZLO DR ,  KOHL VERONIKA DR

    IPC: B01J23/00 ,  B01J23/885 ,  B01J23/887 ,  B01J35/00 ,  C07C51/25 ,  C07C57/055 ,  C01G39/02 ,  B01J23/72

    Abstract: Multimetal oxide compsn. of formula (I) is new: (A)p (B)q (I): A = Mo12VaX bX cX dX eX fX gOx (co-phase); B = X 12CuhHiOy (key phase); X = W, Nb, Ta, Cr and/or Ce; X = Cu, Ni, Co, Fe, Mn and/or Zn; X = Sb and/or Bi; X = Li, Na, K, Rb, Cs and/or H; X = Mg, Ca, Sr and/or Ba; X = Si, Al, Ti and/or Zr; X = Mo, W, V, Nb and/or Ta; a = 1-8; b = 0.2-5; c = 0-23; d, g = 0-50; e = 0-2; f = 0-5; h = 4-30; i = 0-20; x, y = values depending on the valency and content of elements other than O; p, q = values other than O, with the ratio p/q = 160:1 to 1:1. The A and B fractions are each in the form of 30 zones, which differ in chemical compsn. from their local surroundings, and the relative distribution of the A and B zones is as in a mixt. of finely-divided A and finely-divided B. Also claimed are multimetal oxide compsns. of wolframite structural type, of formulae (II), (III), (IV) and (V): in (II), 1/(A+B+C+D+E) = 0.7-1.3; F = 0-1; and B+C+D+E = over 0 to 1. In (III), 1/(A+B+C) = 0.7-1.3; A, B, C all = more than O and B+C = at most 1; In (IV), 1/(A+B) = 0.7-1.3; A, B both = more than O and B = at most 1; In (V), 1/(A+C) = 0.7-1.3; A, C both - more than O and C - at most 1.

    30.
    发明专利
    未知

    公开(公告)号：DE3710433A1

    公开(公告)日：1988-10-06

    申请号：DE3710433

    申请日：1987-03-28

    Applicant: BASF AG

    Inventor： MAROSI LASZLO DR ,  STABENOW JOACHIM DR ,  EGER KNUT DR ,  IRGANG MATTHIAS DR ,  ZIRKER GUENTER DR

    IPC: B01J23/72 ,  B01J37/30 ,  C01B33/20 ,  C01B33/22 ,  B01J23/74

    Abstract: Amorphous metal/magnesium silicates of the general formula MxMgy(SiO2).nH2O. where M is a divalent, reducible metal atom from the group consisting of Cu, FeII, Co and Ni, x and y are numbers which together can add up to a value of 1.5 and n after drying, expressed in % by weight, ranges from 0 to 80 are prepared by subjecting a freshly precipitated magnesium silicate to an ion exchange, washing the product and then neutralizing it with an alkali and are used in catalytic reactions after the reducible metal in the metal/magnesium silicates has been converted into the metallic state with a reducing gas.

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