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    PRODUCTION OF N-SUBSTITUTED CYCLIC AMINE
    1.
    发明专利
    PRODUCTION OF N-SUBSTITUTED CYCLIC AMINE 失效

    公开(公告)号：JPH1072454A

    公开(公告)日：1998-03-17

    申请号：JP15828297

    申请日：1997-06-16

    Applicant: BASF AG

    Inventor： SIMON JOACHIM DR ,  DOSTALEK ROMAN DR ,  LINGK HEINZ ,  BECKER RAINER DR ,  HENNE ANDREAS DR ,  ROLF REEPUKYUUHIYAA ,  FREIRE ERDBRUEGGER CRISTINA DR ,  HESSE MICHAEL DR ,  KRATZ DETLEF DR

    IPC: C07D295/02 ,  B01J23/72 ,  B01J37/02 ,  C07B61/00 ,  C07D295/03

    Abstract: PROBLEM TO BE SOLVED: To enable to industrially simply and profitably obtain the subject compound from a primary amine and a diol by using a specific copper- containing hydrogenation/dehydrogenation catalyst. SOLUTION: This method for producing an N-substituted cyclic amine of formula I comprises reacting (C) a compound of the formula: R -NH2 [R is an (alkoxy)alkyl, an aryl, etc.,] with (D) a compound of the formula: HO-A-OH A is an alkylene (substituted by a group of the formula: R (R is R ), a group of the formula: (CH2 )n -[O-(CH )m ]r , [(m), (n) are each 2-8; (r) is 1-3]} in the presence of a coppercontaining catalyst. The copper-containing catalyst is obtained by impregnating an inactive carrier (e.g. silicon dioxide, a silicate or zeolite) with (A) hydrogen and (B) the aqueous ammine complex solution of an easily pyrolytic copper compound (e.g. copper carbonate, copper oxalate or copper formate)(preferably an ammoniacal copper carbonate solution), drying the impregnated carrier, and subsequently calcining the dried product, and contains the copper in an amount of 5-50wt.% converted into CuO on the basis of the whole amount of the calcined catalyst.

    VAPOR-PHASE DEHYDROGENATION OF 1,4-BUTANEDIOL INTO GAMMA-BUTYROLACTONE
    2.
    发明专利
    VAPOR-PHASE DEHYDROGENATION OF 1,4-BUTANEDIOL INTO GAMMA-BUTYROLACTONE 失效

    公开(公告)号：JPH10152485A

    公开(公告)日：1998-06-09

    申请号：JP23922397

    申请日：1997-09-04

    Applicant: BASF AG

    Inventor： MERCKER HANS JOCHEN DR ,  PAPE FRANK-FRIEDRICH DR ,  SIMON JOACHIM DR ,  HENNE ANDREAS DR ,  HESSE MICHAEL DR ,  KOEHLER ULRICH DR ,  DOSTALEK ROMAN DR ,  FREIRE ERDBRUEGGER CRISTINA DR ,  KRATZ DETLEF DR

    IPC: C07D307/33 ,  B01J23/72 ,  B01J23/78 ,  C07B61/00 ,  C07D307/32 ,  C07D315/00

    Abstract: PROBLEM TO BE SOLVED: To provide a method which effects the subject reaction in the vapor phase advantageously from industrial, economical and environmental aspects in the presence of a catalyst composed of copper and Na2 O supported by a carrier composed of SiO2 and CaO. SOLUTION: This method effects the subject reaction in the presence of free hydrogen by passing 1,4-butanediol over an immobilized phase of catalyst composed of 4 to 40wt.%, preferably 4 to 32wt.%, of copper and 0 to 5wt.%, preferably 0 to 2wt.%, of Na2 O, each percentage being based on the total quantity of the catalyst, supported by a carrier composed of 80 to 100wt.%, preferably 90 to 100wt.%, of SiO2 and 0 to 20wt.%, preferably 0 to 10wt.%, of CaO, where the copper grains having an average diameter of 10 to 100nm are dispersed at a rate of 20 to 50% so as to have a surface area of 10 to 50m /g over the carrier, under the conditions of temperature: 150 to 300 deg.C, preferably 190 to 230 deg.C, absolute pressure: 1 to 40 bar, preferably about 1 bar, and hourly space velocity of 1,4-butanediol: 0.2 to 20kg, preferably 0.5 to 7.5kg, per kg copper, with the carrier gas containing free hydrogen being reused as the recycle gas.

    3.
    发明专利
    未知

    公开(公告)号：DE4316138A1

    公开(公告)日：1994-11-17

    申请号：DE4316138

    申请日：1993-05-14

    Applicant: BASF AG

    Inventor： DOSTALEK ROMAN DR ,  FISCHER ROLF DR ,  MUELLER ULRICH DR ,  BECKER RAINER DR

    IPC: B01J21/12 ,  C08G63/668 ,  C08G65/10 ,  C08G65/16 ,  C08G65/20 ,  C08G65/26

    Abstract: PCT No. PCT/EP94/01403 Sec. 371 Date Nov. 7, 1995 Sec. 102(e) Date Nov. 7, 1995 PCT Filed May 3, 1994 PCT Pub. No. WO92/26803 PCT Pub. Date Nov. 24, 1994Polytetrahydrofuran or polytetrahydrofuran monoesters of C1-C20-monocarboxylic acids or polytetrahydrofuran monoethers of monohydric C1-C20-alcohols, having an average molecular weight of from 250 to 10,000 Dalton and liquid at room temperature, are prepared by the cationic polymerization of tetrahydrofuran in the presence of a telogen by a process in which tetrahydrofuran is polymerized in the presence of water, 1,4-butanediol and/or polytetrahydrofuran having an average molecular weight of from 200 to 700 Dalton and/or of a C1-C20-monocarboxylic acid and/or of a monohydric C1-C20-alcohol with the aid of a catalytic amount of a zeolite catalyst which has an SiO2/Al2O3 molar ratio of from 4:1 to 100:1 and in which the population ratio P of the acid centers on the external surface of the zeolite to the total number of acid centers of the zeolite is 0.03/l or more.

    METHOD OF PRODUCING TRIETHANOLAMINE
    8.
    发明专利
    METHOD OF PRODUCING TRIETHANOLAMINE 未知

    公开(公告)号：MY137794A

    公开(公告)日：2009-03-31

    申请号：MYPI20053816

    申请日：2005-08-15

    Applicant: BASF AG

    Inventor： HAESE FRANK DR ,  MELDER D JOHANN-PETER ,  DOSTALEK ROMAN DR ,  JULIUS MANFRED

    Abstract: METHOD OF PRODUCING TRIETHANOLAMINE IN WHICH PHOSPHOROUS AND/OR HYPOPHOSPHOROUS ACID AND A BASIC COMPOUND CHOSEN FROM ALKALI METAL HYDROXIDE, ALKALINE EARTH METAL HYDROXIDE AND [R1R2R3(2-HYDROXYETHYL)AMMONIUM] HYDROXIDE, WHERE R1, R2 AND R3, INDEPENDENTLY OF ONE ANOTHER, ARE C1-30-A1KYL OR C2-10HYDROXYALKYL, ARE ADDED TO THE TRIETHANOLAMINE AND IN THE CASE OF ALKALI METAL HYDROXIDE AS BASIC COMPOUND THE MOLAR RATIO OF ACID(S):HYDROXIDE IS IN THE RANGE FROM 1:0.1 TO 1:1 AND IN THE CASE OF ALKALINE EARTH METAL HYDROXIDE AS BASIC COMPOUND THE MOLAR RATIO OF ACID(S):HYDROXIDE IS IN THE RANGE FROM 1 :0.05 TO 1 :0.5.

    10.
    发明专利
    未知

    公开(公告)号：DE4203220A1

    公开(公告)日：1993-08-12

    申请号：DE4203220

    申请日：1992-02-05

    Applicant: BASF AG

    Inventor： FISCHER ROLF DR ,  DOSTALEK ROMAN DR ,  LASZLO MAROSI DR

    IPC: B01J23/89 ,  C07B61/00 ,  C07C5/11 ,  C07C13/20

    Abstract: Process for the preparation of cyclohexene by partial hydrogenation of benzene with hydrogen in the presence of water and ruthenium catalysts which are modified with nickel, at elevated temperature in the liquid phase, characterised in that the catalysts used are ruthenium/nickel alloys.

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