公开(公告)号：CA867390A

公开(公告)日：1971-03-30

申请号：CA867390D

Applicant: BASF AG

Inventor： METZGER HORST ,  KOENIG HORST ,  REIF WERNER

公开(公告)号：GB1136747A

公开(公告)日：1968-12-18

申请号：GB1722566

申请日：1966-04-20

Applicant: BASF AG

Inventor： BEER LUDWIG ,  PAPE MARTIN ,  METZGER HORST

IPC: B01J19/12

Abstract: 1,136,747. Cyclododecane oxime. BADISCHE ANILIN- & SODA-FABRIK A.G. 20 April, 1966 [21 April, 1965], No. 17225/66. Heading C2C. Cyclododecane is converted to its oxime by treating a solution of cyclododecane in chlorobenzene with a nitrosating agent and with light having a wavelength of 360-600 millimicrons while mixing the reaction mixture with turbulence, the cyclododecane oxime being removed from the reaction mixture outside the reaction zone by extraction with strong sulphuric acid. Suitable nitrosating agents are, for example, nitrosyl chloride or compounds which form nitrosyl chloride in the reaction medium. If desired, the process may be carried out in the presence of hydrogen chloride.

公开(公告)号：GB1087603A

公开(公告)日：1967-10-18

申请号：GB505265

申请日：1965-02-05

Applicant: BASF AG

Inventor： METZGER HORST ,  PAPE MARTIN

Abstract: e -Cyanocaproic acid is obtained by reacting a -cyanocyclohexanone with an alkali metal glycolate in a glycol as solvent at 150 DEG -250 DEG C., with substantial exclusion of water, i.e. more than 50 mole per cent of the alkali metal ions present being in the form of glycolate. The preferred reaction temperature is 150 DEG -250 DEG C.

公开(公告)号：CA737520A

公开(公告)日：1966-06-28

申请号：CA737520D

Applicant: BASF AG

Inventor： METZGER HORST ,  BEER LUDWIG ,  BRUNNMUELLER FRIEDRICH

公开(公告)号：FR1423579A

公开(公告)日：1966-01-03

申请号：FR4601

申请日：1965-02-05

Applicant: BASF AG

Inventor： METZGER HORST ,  PAPE MARTIN

公开(公告)号：FR1408203A

公开(公告)日：1965-08-13

申请号：FR969639

申请日：1964-04-03

Applicant: BASF AG

Inventor： METZGER HORST ,  KOENIG HORST

IPC: C08G18/38

公开(公告)号：CA697452A

公开(公告)日：1964-11-10

申请号：CA697452D

Applicant: BASF AG

Inventor： SCHICKH OTTO VON ,  METZGER HORST

公开(公告)号：FR1365110A

公开(公告)日：1964-06-26

申请号：FR943588

申请日：1963-08-02

Applicant: BASF AG

Inventor： METZGER HORST

公开(公告)号：GB948544A

公开(公告)日：1964-02-05

申请号：GB4658361

申请日：1961-12-29

Applicant: BASF AG

Inventor： METZGER HORST ,  URBACH HANS

IPC: C07D20060101

Abstract: o -Laurolactam is prepared by mixing cyclododecane carboxylic acid or an alkali metal or alkaline earth metal salt thereof with at least one, and up to two, equivalents of nitroacting agent derived from nitrous acid in the presence of at least one mole of sulphuric acid and/or oleum per mole of cyclododecane carboxylic acid. Suitable nitrosating agents are, for example, nitrosyl chloride, alkyl nitrites, sodium nitrite, dinitrogen trioxide or, preferably, nitrosylsulphonic acid or anhydride. The reaction temperature in general is 0 DEG to 150 DEG C, but it is recommendable to use at least 35 DEG C., and the reaction may be initiated by addition of a small amount, e.g. 1 to 20% by weight, of o -laurolactam to the mixture of reactants or by temporarily increasing the reaction temperature. In a preferred embodiment the nitrosating agent in sulphuric acid or oleum solution is introduced into a solution or suspension of cyclododecane carboxylic acid, or salt thereof, in sulphuric acid or a solvent, e.g. cyclohexane, at such a rate that CO2 escapes continuously. After the complete addition the mixture is stirred for a short time and poured on to ice or into water to precipitate the o -laurolactam. The cyclododecane carboxylic acid or alkali metal or alkaline earth metal salts thereof may be prepared by the trimerisation of butadiene to cyclododecatriene (1, 5, 9), conversion of the trimer into monohydroxymethyl cyclododecane by the oxo synthesis and oxidation of the last mentioned compound to the acid by, for example, alkali fusion.

公开(公告)号：CA650055A

公开(公告)日：1962-10-09

申请号：CA650055D

Applicant: BASF AG

Inventor： SCHICKH OTTO VON ,  METZGER HORST