24.
    发明专利
    未知

    公开(公告)号:NL194503C

    公开(公告)日:2002-06-04

    申请号:NL9301488

    申请日:1993-08-30

    Applicant: BASF AG

    Abstract: Caprolactam is purified by oxidative treatment in which mixtures which essentially contain the caprolactam to be purified and unsaturated lactams are treated with oxygen or an oxygen-containing gas mixture in an alkaline medium.

    Production of pentaerythritol trichlorohydrin

    公开(公告)号:GB925467A

    公开(公告)日:1963-05-08

    申请号:GB3262661

    申请日:1961-09-12

    Applicant: BASF AG

    Abstract: A process for the production of pentaerythritol trichlorhydrin comprises dissolving pentaerythritol in a reaction product of pentaerythritol and hydrogen chloride, passing hydrogen chloride in at least the amount theoretically necessary through the resultant solution at a temperature between about 170 DEG to 200 DEG C., at a pressure between atmospheric and about 5 atmos, and recovering the pentaerythritol trichlorhydrin thus produced. Specified pentaerythritol -HCl reaction products are the mono-, di- and trichlorhydrins and 5,5-bischlormethyldioxan-1,3 and mixtures thereof. The effluent HCl may be recirculated after condensation of liquid entrained substances. Batchwise and continuous operation is possible. A series of reaction vessels may be used, the pentaerythritol, preferably dissolved in dichlorhydrin, being chlorinated up to about the dichlorhydrin stage in the first vessel at 130-175 DEG C., and converted to the trichlorhydrin at 170-200 DEG C. in subsequent vessel(s). Specification 764,664 is referred to.

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