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公开(公告)号：DE19637895A1
公开(公告)日：1998-03-19
申请号：DE19637895
申请日：1996-09-17
Applicant: BASF AG
Inventor： KANAND JUERGEN DR , ROEPER MICHAEL PROF DR
Abstract: In a process for producing n-butylalkyl ethers, (a) 1,3-butadiene or a butadiene-containing hydrocarbon mixture is reacted with an alcohol of formula ROH (I), in which the radical R is a C2-C20 alkyl or alkenyl group substituted or not with 1 to 2 C1-C10 alkoxy or hydroxy groups, a C6-C10 aryl or C7-C11 aralkyl group or a methyl group, at an increased temperature and pressure in the presence of a Brönsted acid or in the presence of a complex of an element of groups Ib, VIIb or VIIIb of the periodic table of elements with a phosphorus- or nitrogen-containing ligand, yielding a mixture of addition products of formulas (II) and (III); (b) the isomers are separated; (c) addition product III is isomerised into addition product II; (d) addition product II is hydrogenated in the presence of a homogeneous or heterogeneous transition metal element catalyst in the liquid phase or in the presence of a heterogeneous, transition metal element-containing catalyst in the gas phase, yielding n-butylalkyl ether of formula (IV).
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公开(公告)号：DE19637892A1
公开(公告)日：1998-03-19
申请号：DE19637892
申请日：1996-09-17
Applicant: BASF AG
Inventor： KANAND JUERGEN DR , ROEPER MICHAEL PROF DR
Abstract: In a process for producing alkoxybutenes, 1,3-butadiene or a butadiene-containing hydrocarbon mixture is reacted with an alcohol of formula ROH (I) at an increased temperature and pressure in the presence of a Brönsted acid, yielding a mixture of addition products of formulas (II) and (III), in which the radical R is a C2-C20 alkyl, alkenyl, cycloalkyl or cycloalkenyl group substituted or not with 1 to 2 C1-C10 alkoxy or hydroxy groups, or is a C2-C10 aryl or C7-C11 aralkyl group or a methyl group. The disclosed improvement consists in that the reaction is carried out in the presence of water.
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公开(公告)号：DE19631521A1
公开(公告)日：1998-02-05
申请号：DE19631521
申请日：1996-08-03
Applicant: BASF AG
Inventor： FISCHER ROLF DR , PACIELLO ROCCO DR , ROEPER MICHAEL PROF DR , SCHNURR WERNER DR
IPC: B01J31/18 , B01J31/24 , C07C209/26 , C07C253/30 , C07C255/24 , C07F9/6574 , C07C211/12 , C07C255/17
Abstract: Manufacture of 6-aminocapronitrile or 6-aminocapronitrile/hexamethylene diamine mixtures, involving a) the reaction of at least one pentennitrile, selected from the group consisting of 2,3 and 4-pentennitrile with carbon monoxide and hydrogen in the presence of catalysts, which contain at least one element of the eighth subgroup as active components, obtaining a hydrogenation formylating discharge (I), b) the optional separation of carbon monoxide, hydrogen and the catalyst from the hydrogenation formylating discharge (I), obtaining a hydrogenation formylating discharge (II), c) the separation of 5-formyl valeronitrile from the hydrogenation formylating discharge (I) or (II), d) the reaction of separated 5-formyl valeronitrile with ammonia and hydrogen in the presence of hydrogenating catalysts, selected from the group consisting of rhenium, copper and its compounds as well as metals and metallic compounds of the eighth group, obtaining a hydrogenation discharge, and e) obtaining 6-aminocapronitrile and if necessary hexamethylene diamine.
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公开(公告)号：DE19608559A1
公开(公告)日：1997-09-11
申请号：DE19608559
申请日：1996-03-06
Applicant: BASF AG
Inventor： KNEUPER HEINZ-JOSEF DR , KORMANN CLAUDIUS DR , ROEPER MICHAEL PROF DR
IPC: B01J31/40 , B01J37/34 , B01J38/00 , B03C1/01 , C07C209/26 , C07C211/09 , B01J31/20 , B01J31/28 , C08L33/08 , C08L33/10 , C08L33/24 , C08L45/00 , H01F1/44
Abstract: The invention concerns a process for preparing amines having more than four carbon atoms by simultaneous hydroformylation and hydrogenating amination of corresponding olefins containing one carbon atom less in the presence of at least equivalent amounts of ammonia or a low-molecular amine or polyamine with at least one primary or secondary amino group by means of an unmodified rhodium catalyst dissolved homogeneously in the reaction medium at high pressure and high temperature. The rhodium catalyst is separated out of the liquid reaction mixture by separating the homogeneously dissolved unmodified rhodium catalyst from the reaction medium by means of a magnetizable inorganic pigment which is suitable for the complex or adsorptive bonding of rhodium and is uncoated or coated with a binder. This pigment is separated from the liquid reaction medium after it has been charged with the rhodium present in the reaction medium by the application of an external magnetic field.
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公开(公告)号：DE19607957A1
公开(公告)日：1997-09-04
申请号：DE19607957
申请日：1996-03-01
Applicant: BASF AG
Inventor： LANGGUTH ERNST DR , ROEPER MICHAEL PROF DR , ZELLER EDGAR DR
IPC: C07C45/49 , C07C49/523 , B01J31/12 , C07C45/50
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Patent Agency Ranking
公开(公告)号：DE19603201A1
公开(公告)日：1997-07-31
申请号：DE19603201
申请日：1996-01-30
Applicant: BASF AG
IPC: B01J31/22 , B01J31/16 , B01J31/18 , B01J31/40 , C07B61/00 , C07C27/22 , C07C29/16 , C07C31/125 , C07C45/50 , C07C45/80 , C07C47/02 , C07D213/38 , C07D213/74 , C07C31/02 , C07D221/00 , C08G73/02 , C08L23/20
Abstract: A process is proposed for producing aldehydes and alcohols by hydroformylation of olefins with more than three carbon atoms. The process involves a hydroformylation stage, in which the olefin is hydroformylated at a pressure of 50-1000 bar and a temperature of 50-180 DEG C with the aid of a rhodium catalyst dissolved in an homogeneous reaction medium, and a catalyst recovery stage, in which the rhodium catalyst is extracted. The process involves the following steps: (a) hydroformylation carried out in the presence of a rhodium complex containing a ligand in the form of a phosphorous-free multidentate organic nitrogen compound capable of forming complexes with group VIII metals, said nitrogen compound containing in addition at least one tertiary nitrogen rest which can be protonated with a weak acid; (b) extraction of the product from the hydroformylation stage, where appropriate after separation or partial separation of the aldehydes and alcohols, using an aqueous solution of a distillable acid; (c) heat treatment of the aqueous acid extract in the presence of an organic solvent or solvent mixture which is inert under the hydroformylation conditions, the aqueous acid being distilled off, in order to de-protonate the complex and convert it to the organic phase; and (d) recycling of the organic phase containing the catalyst complex into the hydroformylation stage.
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公开(公告)号：DE59306778D1
公开(公告)日：1997-07-24
申请号：DE59306778
申请日：1993-09-08
Applicant: BASF AG
Inventor： KNEUPER HEINZ-JOSEF DR , ROEPER MICHAEL PROF DR , PACIELLO ROCCO DR
Abstract: Process for the preparation of aldehydes by the hydroformylation of olefins having more than 7 carbon atoms, comprising the stage of hydroformylation by means of a rhodium catalyst dissolved in homogeneous reaction medium, the separation of the rhodium catalyst from the material discharged from the hydroformylation reaction and the recycling of the rhodium separated from the material discharged from the hydroformylation to the hydroformylation stage, in which the rhodium catalyst is extracted into the aqueous phase from the material discharged from the hydroformylation by means of an aqueous solution of a nitrogen-containing complexing agent from the group consisting of the optionally substituted pyridines, quinolines, 2,2'-bipyridines, 1,10-phenanthrolines, 2,2'-biquinolines, 2,2',6',2''-terpyridines and porphines which are sulphonated or carry sulphonated substituents, and/or from the group consisting of the carboxylated pyridines, the carboxylated quinolines, the optionally substituted 2,2'-bipyridines, 1,10-phenanthrolines, 2,2'-biquinolines, 2,2',6',2''-terpyridines and porphines which are carboxylated or carry carboxylated substituents, and the aqueous, rhodium-containing extract is recycled to the hydroformylation stage.
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公开(公告)号：DE59301714D1
公开(公告)日：1996-04-04
申请号：DE59301714
申请日：1993-08-12
Applicant: BASF AG
Inventor： THOME ALFRED DR , ROEPER MICHAEL PROF DR , KNEUPER HEINZ-JOSEF DR
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公开(公告)号：DE4228887A1
公开(公告)日：1994-03-03
申请号：DE4228887
申请日：1992-08-29
Applicant: BASF AG
Inventor： THOME ALFRED DR , ROEPER MICHAEL PROF DR , KNEUPER HEINZ-JOSEF DR
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公开(公告)号：MY135832A
公开(公告)日：2008-07-31
申请号：MYPI20041926
申请日：2004-05-20
Applicant: BASF AG
Inventor： STUER WOLFRAM DR , SCHEIDEL JENS DR , VOSS HARTWIG DR , BASSLER PETER DR , ROEPER MICHAEL PROF DR
IPC: C07C67/347 , C07C51/353 , C07C51/36 , C07C51/47 , C07C67/303 , C07C67/56
Abstract: A PROCESS FOR CONTINUOUSLY PREPARING A COMPOUND WHICH BEARS AT LEAST TWO FUNCTIONAL GROUPS WHICH ARE EACH INDEPENDENTLY SELECTED FROM THE GROUP CONSISTING OF NITRILE GROUP, CARBOXYLIC ACID GROUP, CARBOXYLIC ESTER GROUP AND CARBOXAMIDE GROUP, COMPRISING THE STEPS OF A) ADDING TWO TERMINAL OLEFINS WHICH BEAR THE FUNCTIONAL GROUPS REQUIRED TO PREPARE THE COMPOUND AS PER A1) CONTAINING AT LEAST TWO FUNCTIONAL GROUPS, IN THE PRESENCE OF A COMPOUND AS PER A3) WHCH IS SUITABLE AS A CATALYST FOR THIS ADDITION AND IS HOMOGENEOUS WITH RESPECT TO THE REACTION MIXTURE TO OBTAIN A MIXTURE COMPRISING A1)A COMPOUND WHICH IS OBTAINED BY MONOADDITION OF THE TWO TERMINAL OLEFINS MENTIONED AND BEARS AT LEAST TWO FUNCTIONAL GROUPS WHICH ARE EACH INDEPENDENTLY SELECTED FROM THE GROUP CONSISTING OF NITRILE GROUP, CARBOXYLIC ACID GROUP, CARBOXYLIC ESTER GROUP AND CARBOXAMIDE GROUP, A2) A COMPOUND WHICH IS OBTAINED BY POLYADDITION OF THE TWO TERMINAL OLEFINS MENTIONED AND A3) THE COMPOUND WHICH IS SUITABLE AS A CATALYST FOR THIS ADDITION AND IS HOMOGENEOUS WITH RESPECT TO THE REACTION MIXTURE, B) DISTILLING THE MIXTURE OBTAINED IN STEP A) TO OBTAIN B1) THE COMPOUND WHICH IS OBTAINED BY MONOADDITION OF THE TWO TERMINAL OLEFINS MENTIONED AND BEARS AT LEAST TWO FUNCTIONAL GROUPS WHICH ARE EACH INDEPENDENTLY SELECTED FROM THE GROUP CONSISTING OF NITRILE GROUP, CARBOXYLIC ACID GROUP, CARBOXYLIC ESTER GROUP AND CARBOXAMIDE GROUP, AS THE TOP PRODUCT AND B2) A MIXTURE COMPRISING B2A)A COMPOUND WHICH IS OBTAINED BY MONOADDITION OF THE TWO TERMINALS OLEFINS MENTIONED AND BEARS AT LEAST TWO FUNCTIONAL GROUPS WHICH ARE EACH INDEPENDENTLY SELECTED FROM THE GROUP CONSISTING OF NITRILE GROUP, CARBOXYLIC ACID GROUP, CARBOXYLIC ESTER GROUP AND CARBOXAMIDE GROUP, B2B) A COMPOUND WHICH IS OBTAINED BY POLYADDITION OF THE TWO TERMINAL OLEFINS MENTIONED AND B2C) THE COMPOUND WHICH IS SUITABLE AS A CATALYST FOR THIS ADDITION AND IS HOMOGENEOUS WITH RESPECT TO THE REACTION MIXTURE, C) SEPARATING THE ENTIRE MIXTURE OBTAINED IN STEP B2) OR A PORTION THREOF BY MEANS OF A SEMIPERMEABLE MEMBRANE TO OBTAIN A PERMEATE AND A RETENTATE, IN SUCH A WAY THAT THE WEIGHT RATION OF COMPONENT B2B) TO COMPONENT B2C) IN THE MIXTURE B2) FED IN STEP C) IS SMALLER THAN IN THE RETENTATE, D) RECYCLING THE PERMEATE OBTAINED IN STEP B2) PARTLY OR FULLY INTO STEP A) AND E) RECYCLING THE PORTION OF THE MIXTURE OBTAINED IN STEP B2) WHICH HAS NOT BEEN SEPARATED IN C) PARTLY OR FULLY INTO STEP A).
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