公开(公告)号：CA2339593A1

公开(公告)日：2000-02-17

申请号：CA2339593

申请日：1999-07-20

Applicant: BASF AG

Inventor： SIMON JOACHIM ,  FRIEDRICH HOLGER

IPC: C01B35/00 ,  C01B35/06 ,  H01M10/40

Abstract: The invention relates to a method for producing highly pure LiBF4 by prepari ng a solution of BF3 etherate in diethyl ether, suspending LiF in this solution , converting same into solid LiBF4 and then separating the resulting solid LiBF4. The invention also relates to the use of LiBF4 obtained in this manne r for the production of lithium-ion batteries.

公开(公告)号：DE10037786C1

公开(公告)日：2002-02-14

申请号：DE10037786

申请日：2000-08-03

Applicant: BASF AG

Inventor： WEIGL HAGEN ,  EBEL KLAUS ,  SIMON JOACHIM

IPC: C07D309/20 ,  B01J21/04 ,  C07B61/00 ,  C07D309/18

Abstract: The invention relates to a method for producing 3,4-dihydro-2H-pyran by reacting tetrahydrofurfuryl alcohol on solid oxidic catalysts at temperatures ranging from 150 to 400 DEG C and at pressures ranging from 0.001 to 50 bar. The inventive method is characterized in that the reaction is carried out in the gas phase inside a multi-tube reactor.

公开(公告)号：NO20013912L

公开(公告)日：2001-08-10

申请号：NO20013912

申请日：2001-08-10

Applicant: BASF AG

Inventor： RIECHERS HARTMUT ,  SIMON JOACHIM ,  HOEHN ARTHUR ,  KRAMER ANDREAS ,  FUNKE FRANK ,  SIEGEL WOLFGANG ,  NUEBLING CHRISTOPH

IPC: B01J23/755 ,  C07B55/00 ,  C07B57/00 ,  C07B61/00 ,  C07C209/68 ,  C07C209/88 ,  C07C211/03 ,  C07C213/02 ,  C07C213/08 ,  C07C217/08

Abstract: A process for the preparation of racemic amines of the formula I where R1 and R2 are different and R1, R2, R3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R3 can also be hydrogen, where the radicals can bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, which comprises simultaneously reacting in situ the corresponding optically active amine I and the secondary alcohol of the formula II and/or the unsymmetrical ketone of the formula III and the amine of the formula R3NH2 in the presence of hydrogen and a hydrogenation catalyst or dehydrogenation catalyst at elevated temperature.

公开(公告)号：DE19957672A1

公开(公告)日：2001-05-31

申请号：DE19957672

申请日：1999-11-30

Applicant: BASF AG

Inventor： SIMON JOACHIM ,  WAHL PETER ,  SCHMIDT WILLY

IPC: C07D295/02 ,  C07D295/023

Abstract: Purification of crude pyrrolidine (I) to give a composition containing over 99 wt.% (I) and less than 0.3 wt.% water comprises continuous distillation of crude (I), containing 40-98 wt.% (I) and over 2 wt.% water, in a column with distillation and concentration sections at a top pressure less than 950 hPa.

公开(公告)号：AU4140899A

公开(公告)日：2000-08-29

申请号：AU4140899

申请日：1999-05-10

Applicant: BASF AG

Inventor： RIECHERS HARTMUT ,  SIMON JOACHIM ,  HOEHN ARTHUR ,  KRAMER ANDREAS ,  FUNKE FRANK ,  SIEGEL WOLFGANG ,  NUEBLING CHRISTOPH

IPC: B01J23/755 ,  C07B55/00 ,  C07B57/00 ,  C07B61/00 ,  C07C209/68 ,  C07C209/88 ,  C07C211/03 ,  C07C213/02 ,  C07C213/08 ,  C07C217/08

Abstract: A process for the preparation of racemic amines of the formula I where R1 and R2 are different and R1, R2, R3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R3 can also be hydrogen, where the radicals can bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, which comprises simultaneously reacting in situ the corresponding optically active amine I and the secondary alcohol of the formula II and/or the unsymmetrical ketone of the formula III and the amine of the formula R3NH2 in the presence of hydrogen and a hydrogenation catalyst or dehydrogenation catalyst at elevated temperature.

公开(公告)号：CA2362365A1

公开(公告)日：2000-08-17

申请号：CA2362365

申请日：1999-05-10

Applicant: BASF AG

Inventor： FUNKE FRANK ,  SIEGEL WOLFGANG ,  NUBLING CHRISTOPH ,  KRAMER ANDREAS ,  RIECHERS HARTMUT ,  SIMON JOACHIM ,  HOHN ARTHUR

IPC: B01J23/755 ,  C07B55/00 ,  C07B57/00 ,  C07B61/00 ,  C07C209/68 ,  C07C209/88 ,  C07C211/03 ,  C07C213/02 ,  C07C213/08 ,  C07C217/08

Abstract: The invention relates to a method for producing racemic amines of formula (I ), in which R1 and R2 are not the same and R1, R2, R3 are alkyl-, cycloalkyl-, arylalkyl-, aryl-, heteroaryl rests and heterocyclic rests and R3 also represents hydrogen. Said rests can carry substituents selected from the gro up of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino. T he method is characterized in that the corresponding optically active amine (I) and the secondary alcohol of formula (II) and/or the asymmetrical ketone of formula (III) and the amine of the formula R3NH2 are simultaneously reacted in situ in the presence of hydrogen and a hydrogenation or dehydrogenation catalyst at an elevated temperature.

公开(公告)号：DE19901198A1

公开(公告)日：2000-07-20

申请号：DE19901198

申请日：1999-01-14

Applicant: BASF AG

Inventor： RIECHERS HARTMUT ,  SIMON JOACHIM ,  HENNE ANDREAS ,  HOEHN ARTHUR

IPC: C07D295/08 ,  B01J23/72 ,  C07D295/088

Abstract: 2,2'-Dimorpholinodiethyl ether is produced by reacting diethylene glycol with ammonia under pressure at elevated temperature in the presence of hydrogen. The active hydrogenation catalyst, before reduction with hydrogen, contains 20-85 wt.% alumina, zirconium dioxide, titanium dioxide and/or silica, 1-70 wt.% copper oxide (CuO), less than 20 wt.% nickel oxide with respect to CuO and 0-50 wt.% other metal oxide(s). In the production of 2,2'-dimorpholinodiethyl ether (DMDEE) by reacting diethylene glycol with ammonia under pressure at elevated temperature in the presence of hydrogen and a hydrogenation catalyst, the active catalyst, before reduction with hydrogen, contains 20-85 wt.% aluminum oxide (Al2O3), zirconium dioxide (ZrO2), titanium dioxide (TiO2) and/or silica (SiO2), 1-70 wt.% copper oxide (expressed as CuO), 0-50 wt.% magnesium, chromium, zinc, barium and/or calcium oxide (expressed as MgO, Cr2O3, ZnO, BaO and CaO) and less than 20 wt.% nickel oxide (expressed as NiO) with respect to CuO.

公开(公告)号：DE19859775A1

公开(公告)日：2000-06-29

申请号：DE19859775

申请日：1998-12-23

Applicant: BASF AG

Inventor： RIECHERS HARTMUT ,  SIMON JOACHIM ,  HOEHN ARTHUR ,  KRAMER ANDREAS ,  FUNKE FRANK ,  SIEGEL WOLFGANG ,  NUEBLING CHRISTOPH

IPC: C07C209/00 ,  C07C209/68 ,  C07C213/08 ,  C07C217/08 ,  C07B55/00

Abstract: Gas phase racemisation of an optically active amine uses a hydrogenation or dehydrogenation catalyst in the presence of hydrogen at an elevated temperature. Production of racemic amines (I) comprises racemisation of a corresponding optically active amine by reaction with a hydrogenation or dehydrogenation catalyst in the presence of hydrogen at an elevated temperature in the gas phase. R , R = different and are alkyl, cycloalkyl, aralkyl, aryl, heteroaryl or heterocyclyl, all optionally substituted by Q; provided that R and R = different; R = H or alkyl, cycloalkyl, aralkyl, aryl, heteroaryl or heterocyclyl, all optionally substituted by Q; Q = alkyl, cycloalkyl, alkoxy, aryloxy, NH2, NH(alkyl) or N(alkyl)2.

公开(公告)号：AU4034699A

公开(公告)日：2000-06-05

申请号：AU4034699

申请日：1999-04-28

Applicant: BASF AG

Inventor： RIECHERS HARTMUT ,  SIMON JOACHIM ,  HOHN ARTHUR ,  KRAMER ANDREAS DR ,  FUNKE FRANK ,  SIEGEL WOLFGANG ,  NUBLING CHRISTOPH

IPC: B01J23/72 ,  B01J23/755 ,  B01J37/18 ,  C07B55/00 ,  C07B61/00 ,  C07C209/00 ,  C07C209/68 ,  C07C211/00 ,  C07C211/07 ,  C07C213/08 ,  C07C217/08

Abstract: Optically active amines are racemized by reaction of the optically active amine in the gas phase at elevated temperature in the presence of hydrogen and a hydrogenation or dehydrogenation catalyst.

公开(公告)号：AU5370599A

公开(公告)日：2000-02-28

申请号：AU5370599

申请日：1999-07-20

Applicant: BASF AG

Inventor： FRIEDRICH HOLGER ,  SIMON JOACHIM

IPC: C01B35/00 ,  C01B35/06 ,  H01M10/40