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公开(公告)号:ES2093136T3
公开(公告)日:1996-12-16
申请号:ES92106987
申请日:1992-04-24
Applicant: BASF AG
Inventor: HORN PETER DR , MUELLER ULRICH DR , HOELDERICH WOLFGANG PROF DR , SATTLER ULF , TADDEY RUDOLF , TINTELNOT DIETER
IPC: C08G18/08 , C08G18/00 , C08G101/00 , C08J9/00 , C08J9/02 , C08J9/10 , C08J9/34 , C08K3/36 , C08L75/00 , C08L75/04
Abstract: The invention relates to a process for the preparation of CFC-free, soft and elastic, semi-rigid or rigid mouldings containing urethane groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one amorphous, microporous silica gel which preferably has a mean pore diameter with more than 40 % in range from 0.1 to 10 nm, a pore volume of from 0.15 to 1.8 ml/g and a BET surface area of from 200 to 900 m /g, and optionally further additives, and g) assistants, in a closed mould with compaction. t
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公开(公告)号:CA2054170C
公开(公告)日:1996-12-03
申请号:CA2054170
申请日:1991-10-24
Applicant: BASF AG
Inventor: HORN PETER , HOELDERICH WOLFGANG , TADDEY RUDOLF , TINTELNOT DIETER
IPC: B29C45/00 , B29C44/00 , B29K75/00 , B29L31/56 , C08G18/00 , C08G18/08 , C08G101/00 , C08J9/00 , C08J9/02 , C08J9/34 , C08K7/26 , C08L75/00 , B29C67/20
Abstract: Chlorofluorocarbon-free urethane-containing, soft-elastic moldings having a cellular core, a compacted peripheral zone and an essentially pore-free smooth surface are produced by reacting a) an organic and/or modified organic polyisocyanate with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and, if desired, c) a low-molecular-weight chain extender and/or crosslinking agent, in the presence of d) a blowing agent, e) a catalyst, f) a crystalline, microporous molecular sieve having a cavity diameter of less than 1.3 nm and comprising metal oxides or metal phosphates, and, if desired, further additives and g) assistants, in a closed mold with compaction, expediently by RIN.
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公开(公告)号:DK0545175T3
公开(公告)日:1996-11-18
申请号:DK92119790
申请日:1992-11-20
Applicant: BASF AG
Inventor: SCHUSTER LUDWIG DR , HORN PETER DR , TADDEY RUDOLF , TINTELNOT DIETER , MUELLER ULRICH DR , HOELDERICH WOLFGANG PROF DR
IPC: B65D6/14 , C08G18/08 , C08G18/10 , C08G18/12 , C08G18/66 , C08J9/00 , B65D1/12 , C08J9/02 , C08J9/34 , C08K3/04 , C08K3/36 , C08K7/24 , C08L75/00
Abstract: The invention relates to a process for the preparation of chlorofluorocarbon-free (CFC-free), elastomeric, semi-rigid or rigid mouldings containing urethane groups or urethane and urea groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one microporous activated charcoal and/or a microporous carbon molecular sieve, which preferably has a mean pore diameter with more than 40% in the range from 0.3 to 3 nm, a pore volume of from 0.20 to 1.4 ml/g and a BET surface area of from 500 to 2500 m /g or greater, and optionally further additives and g) auxiliaries, in a closed mould with compaction.
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公开(公告)号:ES2090463T3
公开(公告)日:1996-10-16
申请号:ES92119790
申请日:1992-11-20
Applicant: BASF AG
Inventor: HORN PETER DR , MUELLER ULRICH DR , HOELDERICH WOLFGANG PROF DR , TADDEY RUDOLF , TINTELNOT DIETER , SCHUSTER LUDWIG DR
IPC: B65D6/14 , C08G18/08 , C08G18/10 , C08G18/12 , C08G18/66 , C08J9/00 , B65D1/12 , C08J9/02 , C08J9/34 , C08K3/04 , C08K3/36 , C08K7/24 , C08L75/00
Abstract: The invention relates to a process for the preparation of chlorofluorocarbon-free (CFC-free), elastomeric, semi-rigid or rigid mouldings containing urethane groups or urethane and urea groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one microporous activated charcoal and/or a microporous carbon molecular sieve, which preferably has a mean pore diameter with more than 40% in the range from 0.3 to 3 nm, a pore volume of from 0.20 to 1.4 ml/g and a BET surface area of from 500 to 2500 m /g or greater, and optionally further additives and g) auxiliaries, in a closed mould with compaction.
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公开(公告)号:DE4139520A1
公开(公告)日:1993-06-03
申请号:DE4139520
申请日:1991-11-30
Applicant: BASF AG
Inventor: HORN PETER DR , MUELLER ULRICH DR , HOELDERICH WOLFGANG DR , TADDEY RUDOLF , TINTELNOT DIETER , SCHUSTER LUDWIG DR
IPC: B65D6/14 , C08G18/08 , C08G18/10 , C08G18/12 , C08G18/66 , C08J9/00 , C08J9/02 , C08J9/34 , C08K3/04 , C08K3/36 , B65D1/12 , C08K7/24 , C08L75/00
Abstract: The invention relates to a process for the preparation of chlorofluorocarbon-free (CFC-free), elastomeric, semi-rigid or rigid mouldings containing urethane groups or urethane and urea groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one microporous activated charcoal and/or a microporous carbon molecular sieve, which preferably has a mean pore diameter with more than 40% in the range from 0.3 to 3 nm, a pore volume of from 0.20 to 1.4 ml/g and a BET surface area of from 500 to 2500 m /g or greater, and optionally further additives and g) auxiliaries, in a closed mould with compaction.
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公开(公告)号:DE59904844D1
公开(公告)日:2003-05-08
申请号:DE59904844
申请日:1999-01-26
Applicant: BASF AG
Inventor: HORN PETER , SCUPIN HANSJOACHIM , STADLER EDMUND , TINTELNOT DIETER , TREULING ULRICH
IPC: C08G18/08 , C08G18/09 , C08G18/12 , C08G18/16 , C08G18/20 , C08G18/34 , C08G18/40 , C08G18/65 , C08G18/66 , C08G18/79 , C08J9/00 , C08J9/08 , C08J9/34
Abstract: The present invention relates to a method for producing soft and elastic, semi-hard or hard moulded bodies of polyurethane which are fluorochlorohydrocarbon-free and have a cellular core as well as a compacted side area. This method comprises reacting a) polyisocyanates with b) at least one compound having at least two reactive hydrogen atoms, with c) foaming agents, with d) catalysts and with e) optional auxiliary agents and/or additives. This method is characterised in that the foaming agents c) contain c1) at least one carbodiimide-forming catalyst and c2) at least one carboxylic acid and/or the anhydride thereof.
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公开(公告)号:DE19942616A1
公开(公告)日:2001-03-15
申请号:DE19942616
申请日:1999-09-08
Applicant: BASF AG
Inventor: HITSCHFELD KLAUS , TINTELNOT DIETER , BURGHARDT ANDRE , HAEBERLE KARL
Abstract: The invention relates to a method for producing skins from polyurethane dispersions, comprising the following steps: 1) two-dimensionally coating the surface of a substrate or the surface of a film covering the substrate by simultaneously spraying an aqueous dispersion containing a polyurethane (polyurethane A) with ionic groups and an ionic or potentially ionic precipitating agent (precipitating agent F) in liquid form onto the surface of the substrate or the surface of the film covering the substrate, so that a covering is formed; and 2) removing the covering, or if the surface of the substrate was covered by a film, the composite structure consisting of the covering and the film, from the substrate.
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公开(公告)号:AU2830099A
公开(公告)日:1999-08-23
申请号:AU2830099
申请日:1999-01-26
Applicant: BASF AG
Inventor: HORN PETER , SCUPIN HANSJOACHIM , STADLER EDMUND , TINTELNOT DIETER , TREULING ULRICH
IPC: C08G18/08 , C08G18/09 , C08G18/12 , C08G18/16 , C08G18/20 , C08G18/34 , C08G18/40 , C08G18/65 , C08G18/66 , C08G18/79 , C08J9/00 , C08J9/08 , C08J9/34
Abstract: The present invention relates to a method for producing soft and elastic, semi-hard or hard moulded bodies of polyurethane which are fluorochlorohydrocarbon-free and have a cellular core as well as a compacted side area. This method comprises reacting a) polyisocyanates with b) at least one compound having at least two reactive hydrogen atoms, with c) foaming agents, with d) catalysts and with e) optional auxiliary agents and/or additives. This method is characterised in that the foaming agents c) contain c1) at least one carbodiimide-forming catalyst and c2) at least one carboxylic acid and/or the anhydride thereof.
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公开(公告)号:DE59207363D1
公开(公告)日:1996-11-21
申请号:DE59207363
申请日:1992-04-24
Applicant: BASF AG
Inventor: HORN PETER DR , MUELLER ULRICH DR , HOELDERICH WOLFGANG PROF DR , SATTLER ULF , TADDEY RUDOLF , TINTELNOT DIETER
IPC: C08G18/08 , C08G18/00 , C08G101/00 , C08J9/00 , C08J9/02 , C08J9/10 , C08J9/34 , C08K3/36 , C08L75/00 , C08L75/04
Abstract: The invention relates to a process for the preparation of CFC-free, soft and elastic, semi-rigid or rigid mouldings containing urethane groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one amorphous, microporous silica gel which preferably has a mean pore diameter with more than 40 % in range from 0.1 to 10 nm, a pore volume of from 0.15 to 1.8 ml/g and a BET surface area of from 200 to 900 m /g, and optionally further additives, and g) assistants, in a closed mould with compaction. t
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公开(公告)号:DE59206854D1
公开(公告)日:1996-09-05
申请号:DE59206854
申请日:1992-11-20
Applicant: BASF AG
Inventor: HORN PETER DR , MUELLER ULRICH DR , HOELDERICH WOLFGANG PROF DR , TADDEY RUDOLF , TINTELNOT DIETER , SCHUSTER LUDWIG DR
IPC: B65D6/14 , C08G18/08 , C08G18/10 , C08G18/12 , C08G18/66 , C08J9/00 , B65D1/12 , C08J9/02 , C08J9/34 , C08K3/04 , C08K3/36 , C08K7/24 , C08L75/00
Abstract: The invention relates to a process for the preparation of chlorofluorocarbon-free (CFC-free), elastomeric, semi-rigid or rigid mouldings containing urethane groups or urethane and urea groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one microporous activated charcoal and/or a microporous carbon molecular sieve, which preferably has a mean pore diameter with more than 40% in the range from 0.3 to 3 nm, a pore volume of from 0.20 to 1.4 ml/g and a BET surface area of from 500 to 2500 m /g or greater, and optionally further additives and g) auxiliaries, in a closed mould with compaction.
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