Abstract:
The invention concerns tertrazonlinonecarboxylic acid amides of formula (I) and amide-containing herbicides. In formula (I), Het represents oxetan-3-yl, thietan-3-yl, tetrahydrofuran-3-yl, furan-3-yl, tetrahydrothiophene-3-yl, thiophene-3-yl, tetrahydro-2H-pyran-3-yl, tetrahydro-2H-thiopyran-3-yl, tetrahydro-2H-pyran-4-yl or tetrahydro-2H-thiopyran-4-yl, each being possibly substituted; R1 represents alkyl C¿1?-C6, alkyl halide C1-C6, cyanoalkyl C1-C4, alcoxy C1-C6 alkyl C1-C4, alkyl halide C1-C4 alkyl C1-C4, alkylthio C1-C4 alkyl C1-C4, alkylthio halide C1-C4 alkyl C1-C4, alkylsulfonyl C1-C4 alkyl C1-C4, alkylsulfonyl halide C1-C4 alkyl C1-C4, alcenyl C2-C6, cyanoalcenyl C3-C6, alcenyl halide C2-C6, alcinyl C3-C6, cycloalyl C3-C8, cycloalkyl C3-C8 alkyl C1-C4, cycloalcenyl C5-C8, cycloalcenyl C5-C8 alkyl C1-C4, phenyl, phenylakyl C1-C4, heterocyclyl having 3 to 7 links and capable of containing one carbonyl or thiocarbonyl cycle, or heterocyclylakyl C1-C4 having 3 to 7 links and capable of containing one carbonyl or thiocarbonyl cycle, the cycloalkyl, cycloalcenyl, phenyl or heterocyclyl cycles being possibly substituted; R?2¿ represents hydrogen, alkyl C¿1?-C6, alkyl halide C1-C6, alcenyl C3-C6, alcenyl halide C3-C6, alcinyl C3-C6, cycloalkyle C3-C8, cycloalkyl C3-C8 alkyl C1-C4, phenyl, phenylakyl C1-C4, heterocyclyl having 3 to 7 links and capable of containing one carbonyl or thiocarbonyl cycle, or heterocyclylalkyl C1-C4 having 3 to 7 links and capable of containing a carbonyl or thiocarbonyl cycle, the cylcoakyl, phenyl or heterocyclyl cycles being possibly substituted.
Abstract:
The invention relates to thiazolimines derivatives of formula (I), wherein the substituents have the following meanings: X, Y independently of each other stand for hydrogen, halogen, C1-C4-alkyl, C1-C4-haloalkyl, Z means hydrogen, C1-C8-alkyl, C2-C8-alkenyl, C2-C8-alkinyl, C1-C8-alkoxy, C1-C8-alkylthio, wherein these groups can be substituted by 1-5 halogen or C1-C4-alkoxy; aryl, hetaryl, benzyl, wherein these groups can be substituted with C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, halogen, nitro or cyano; or one of the following groups (a...); R1, R2 are hydrogen, halogen; C¿1?-C4-alkyl, C2-C4-alkenyl, C2-C4-alkinyl, wherein these groups can be substituted by 1-5 halogen or by C1-C4-alkoxy; n is 1 or 2; m is 0, 1 or 2, and R?3-R6¿ have the meaning cited in the application. The invention further relates to salts of compound I which can be used in agriculture.
Abstract:
The invention concerns pyrazol-4-yl-benzoyl derivatives of formula (I) in which the substituents L, M, X, Y, and n have the meanings given in claim 1, and Q is a pyrazol ring which is bonded in position 4 and corresponds to formula (II), in which: R15 designates a C¿1? - C4 alkyl; R?16¿ designates hydrogen, C¿1? - C4 alkyl or C1 - C4 alkyl halide; and R?17¿ designates hydrogen, C¿1? - C4 alkylsulphonyl, phenylsulphonyl or alkylphenylsulphonyl; wherein if Y = C=O, X is not NR?23¿. The invention further concerns salts for agricultural purposes, a process for their preparation and their use as herbicides.
Abstract:
The invention concerns substituted pyrazole-3-yl benzazoles of formula (I) and salts thereof, in the formula R1 designating H, C¿1?-C4 alkyl, C1-C4 alkyl halide; R?2¿ designating CN, C¿1?-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulphinyl, C1-C4-haloalkylsulphinyl, C1-C4-alkylsulphonyl, C1-C4-haloalkylsulphonyl; R?3¿ = H, CN, NO¿2?, halogen, C1-C4-alkyl, C1-C4-haloalkyl; R?4¿ designating H, halogen; R5 designating H, CN, halogen, C¿1?-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; Z designating -N=C(XR?6¿)-O- or -N=C(XR6)-S-, bonded to α by the nitrogen, oxygen or sulphur; X designating a chemical bond, oxygen, sulphur, -S(O)-, -SO¿2?-, -NH- or -N(R?7); R6, R7¿ designating C¿1?-C6-alkyl, C1-C6-haloalkyl, cyano-C1-C4-alkyl, hydroxy-C1-C4-alkyl, C3-C6-alkenyl, cyano-C3-C6-alkenyl, C3-C6-haloalkenyl, C3-C6-alkinyl, cyano-C3-C6-alkinyl, C3-C6-haloalkinyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C3-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkinyloxy-C1-C4-alkyl, C3-C8-cycloalkyloxy-C1-C4-alkyl, amino-C1-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di(C1-C4-alkyl)amino-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-haloalkylthio-C1-C4-alkyl, C3-C4-alkenylthio- C1-C4-alkyl, C3-C4-alkinylthio-C1-C4-alkyl, C1-C4-alkyl-sulphinyl-C1-C4-alkyl, C1-C4-haloalkylsulphinyl-C1-C4-alkyl, C3-C4-alkenylsulphinyl-C1-C4-alkyl, C3-C4-alkinylsulphinyl-C1-C4-alkyl, C1-C4-alkylsulphonyl-C1-C4-alkyl, C1-C4-haloalkylsulphonyl-C1-C4-alkyl, C3-C4-alkenylsulphonyl-C1-C4-alkyl, C3-C4-alkinylsulphonyl-C1-C4-alkyl, hydroxycarbonyl-C1-C4-alkyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl, which can carry a CN oder C1-C4-alkoxycarbonyl group, C1-C4-alkylthiocarbonyl-C1-C4-alkyl, aminocarbonyl-C1-C4-alkyl, C1-C4-alkylaminocarbonyl-C1-C4-alkyl, di(C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, di(C1-C4-alkyl)-phosphonyl-C1-C4-alkyl, C1-C4-alkoxyimino-C1-C4-alkyl, C3-C4-alkenyloxyimino-C1-C4-alkyl, optionally substituted C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, phenyl, phenyl-C1-C4-alkyl, 3- to 7-member heterocyclic or heterocyclyl-C1-C4-alkyl, wherein each cycloalkyl ring and each heterocyclyl ring contain a CO or CS ring member; if X is a chemical bond, -O-, -S-, -NH- or -N(R?7)-, R6¿ also being C¿1?-C4 alkylcarbonyl, C1-C4 haloalkylcarbonyl, C1-C4 alkoxycarbonyl, C1-C4 alkylsulphonyl or C1-C4 haloalkylsulphonyl; if X is a chemical bond, R?6¿ additionally designating CN, SH, NH¿2?, halogen, -CH2-CH(halogen)-R?8¿, -CH=CH-R8 or -CH=C(halogen)-R8, R8 designating COOH, C¿1?-C4 alkoxycarbonyl, C1-C4 alkylthiocarbonyl, CONH2, C1-C4 alkylaminocarbonyl, di(C1-C4 alkyl)aminocarbonyl or di(C1-C4 alkyl)phosphonyl; or R?6 plus R7¿ designating an optionally substituted 1,3-propylene, tetramethylene, pentamethylene or ethylene oxyethylene chain. The invention also concerns the use of these substances as herbicides and for the desiccation and/or defoliation of plants.
Abstract:
The invention concerns substituted 1-methyl-3-benzyluracils (I) and their salts and enol ethers as herbicides or desiccating/defoliating agents. In formula (I), R1 is C1-C4 alkyl halide; R2 is H or halogen; R3 is R2, CN, SCN, C¿1?-C4 alkyl halide, C1-C4 alkoxy halide or C1-C4 alkylthio halide; R?4 is R3, C¿1-C4 alkyl, C1-C4 alkoxy or (C1-C6 alkylamino)-CO-; R5 is R2, CN, NO¿2?, OH, optionally substituted amino, alkoxy, alkylthio, alkyl-CO2-, alkyl-COS-, alkyl-SO2-O- or alkyl-SO2-, the six last-mentioned groups optionally being functionalized and/or substituted; R?6¿, if it is in the α position with R5 then being in the β position, is OH, SH, alkyl, alkoxy, alkylthio, alkyl-CO¿2?-, alkyl-COS-, alkoxy-CO-, alkoxy-CO2-, alkyl-SO2-O-, alkyl-SO2-, alkyl-CO-, alkyl-CS-, alkyl-(N-alkyl)-imino or alkyl-(N-alkoxy)-imino, the thirteen last-mentioned groups optionally being functionalized and/or substituted, or methyl substituted twice by optionally substituted alkoxy and alkylthio and optionally substituted once by alkyl; or R?6¿ in the β position, with R5 then being in the α position, has the above meanings, as well as alkyl-amino-CO-, alkoxy-CO-, alkylthio-CO-, alkyl-CO-, alkylimino-oxycarbonyl, alkyl-(N-alkoxy)-imino, alkoxy-(N-alkoxy)-imino or alkylthio-(N-alkoxy)-imino, the eight last-mentioned groups optionally being functionalized and/or substituted, or methyl substituted three times by optionally substituted alkoxy, alkylthio and alkylamino.
Abstract:
Substituted N-phenylglutarimides (I), wherein X1, X2 = O, S; R1 = halogen, NO¿2?, CN, CF3; R?2¿ = H, halogen; R?3, R4, R5¿ = H, halogen, CN, alkyl, cycloalkyl, alkenyl, alkinyl, alkyl halide, alkoxy, alkoxy halide, alkyl thio, alkyl thio halide, cyanoalkyl, alkoxy carbonyl, possibly substituted phenyl or benzyl, or 2 substituents of a C atom of the glutarimide ring are linked via a possibly substituted chain, or 2 substituents of adjacent C atoms of the glutarimide ring are linked via a possibly substituted chain; A = CHR6-CHR7-CO-B or CR6=CR8-CO-B; R6 = H, C¿1?-C6-alkyl or C1-C6-alkyl halide; R?7¿ = halogen, alkyl halide, OH, alkoxy or alkyl carbonyl alkoxy; R8 = H, halogen, CN, alkyl, alkyl halide, OH, alkoxy, alkyl carbonyl, alkoxy carbonyl or alkyl carbonyloxy; B = H, alkyl, alkenyl, alkinyl, alkyl halide, cycloalkyl, alkoxy alkyl, dialkoxy alkyl, alkyl thioalkyl, OR?9, SR9, NR10, R11; R9¿ = H, alkyl, alkenyl, alkinyl, cycloalkyl, alkyl halide, cyanoalkyl, alkenyl halide, alkoxy carbonyl alkyl, alkoxyalkyl, alkyl thioalkyl, alkylimino, alkylimino alkyl, possibly substituted phenyl or benzyl; R10, R11 = H, alkyl, alkenyl, alkinyl, cycloalkyl, alkyl halide, alkyl carbonyl, alkoxy carbonyl, alkoxy alkyl, possibly substituted phenyl, or R?10 und R11¿ together with the common N atom = saturated or unsaturated 4- to 7- membered heterocycle with 1-2 other heteroatoms, as well as salts of (I) that are tolerable to plants; their preparation and use as herbicides and desiccants/defoliants, as well as preproducts for preparing the N-phenylglutarimides (I).