SUBSTITUIERTE HERBIZIDE TETRAZOLINONCARBONSÄUREAMIDE
    21.
    发明公开
    SUBSTITUIERTE HERBIZIDE TETRAZOLINONCARBONSÄUREAMIDE 失效
    SUBSTITUIERTE HERBIZIDE四氮唑碳酰胺

    公开(公告)号:EP1003741A1

    公开(公告)日:2000-05-31

    申请号:EP98941362.0

    申请日:1998-07-20

    CPC classification number: C07D405/12 A01N47/38 C07D409/12

    Abstract: The invention concerns tertrazonlinonecarboxylic acid amides of formula (I) and amide-containing herbicides. In formula (I), Het represents oxetan-3-yl, thietan-3-yl, tetrahydrofuran-3-yl, furan-3-yl, tetrahydrothiophene-3-yl, thiophene-3-yl, tetrahydro-2H-pyran-3-yl, tetrahydro-2H-thiopyran-3-yl, tetrahydro-2H-pyran-4-yl or tetrahydro-2H-thiopyran-4-yl, each being possibly substituted; R1 represents alkyl C¿1?-C6, alkyl halide C1-C6, cyanoalkyl C1-C4, alcoxy C1-C6 alkyl C1-C4, alkyl halide C1-C4 alkyl C1-C4, alkylthio C1-C4 alkyl C1-C4, alkylthio halide C1-C4 alkyl C1-C4, alkylsulfonyl C1-C4 alkyl C1-C4, alkylsulfonyl halide C1-C4 alkyl C1-C4, alcenyl C2-C6, cyanoalcenyl C3-C6, alcenyl halide C2-C6, alcinyl C3-C6, cycloalyl C3-C8, cycloalkyl C3-C8 alkyl C1-C4, cycloalcenyl C5-C8, cycloalcenyl C5-C8 alkyl C1-C4, phenyl, phenylakyl C1-C4, heterocyclyl having 3 to 7 links and capable of containing one carbonyl or thiocarbonyl cycle, or heterocyclylakyl C1-C4 having 3 to 7 links and capable of containing one carbonyl or thiocarbonyl cycle, the cycloalkyl, cycloalcenyl, phenyl or heterocyclyl cycles being possibly substituted; R?2¿ represents hydrogen, alkyl C¿1?-C6, alkyl halide C1-C6, alcenyl C3-C6, alcenyl halide C3-C6, alcinyl C3-C6, cycloalkyle C3-C8, cycloalkyl C3-C8 alkyl C1-C4, phenyl, phenylakyl C1-C4, heterocyclyl having 3 to 7 links and capable of containing one carbonyl or thiocarbonyl cycle, or heterocyclylalkyl C1-C4 having 3 to 7 links and capable of containing a carbonyl or thiocarbonyl cycle, the cylcoakyl, phenyl or heterocyclyl cycles being possibly substituted.

    Abstract translation: 本发明涉及式(I)的特拉唑啉酮羧酸酰胺和含酰胺的除草剂。 式(I)中,Het表示氧杂环丁烷-3-基,硫杂环丁烷-3-基,四氢呋喃-3-基,呋喃-3-基,四氢噻吩-3-基,噻吩-3-基,四氢-2H-吡喃-3-基, 三氢吡喃-3-基,四氢-2H-噻喃-3-基,四氢-2H-吡喃-4-基或四氢-2H-噻喃-4-基,每一个都可能被取代; R 1表示C 1 -C 6烷基,烷基卤C 1 -C 6,氰基烷基C 1 -C 4,烷氧基C 1 -C 6烷基C 1 -C 4,烷基卤C 1 -C 4烷基C 1 -C 4,烷硫基C 1 -C 4烷基C 1 -C 4, 烷基磺酰基C1-C4烷基C1-C4,烷基磺酰卤C1-C4烷基C1-C4,烯丙烯基C2-C6,氰基烯丙基C3-C6,烯丙烯基卤C2-C6,炔丙基C3-C6,环烷基 C 3 -C 8环烷基C 3 -C 8烷基C 1 -C 4环烯基C 5 -C 8环烯基C 5 -C 8烷基C 1 -C 4苯基C 1 -C 4苯基烷基C 3-7具有3-7个环节并且能够含有一个羰基或硫代羰基环的杂环基, 或具有3-7个连接且能够含有一个羰基或硫代羰基环的杂环烷基C1-C4,所述环烷基,环烯基,苯基或杂环基可能被取代; R 2'代表氢,烷基C 1 -C 6,烷基卤C 1 -C 6,烯丙烯基C 3 -C 6,烯丙基卤C 3 -C 6,炔丙基C 3 -C 6,环烷基C 3 -C 8,环烷基C 3 -C 8烷基C 1 -C 4 ,苯基,苯基烷基C 1 -C 4,具有3-7个连接并且能够含有一个羰基或硫代羰基环的杂环基,或具有3-7个连接并且能够含有羰基或硫代羰基循环的杂环基烷基C 1 -C 4,环癸基,苯基或杂环基 周期可能被取代。

    SUBSTITUIERTE PYRAZOL-3-YLBENZAZOLE
    25.
    发明公开
    SUBSTITUIERTE PYRAZOL-3-YLBENZAZOLE 失效
    取代的吡唑-3- YLBENZAZOLE

    公开(公告)号:EP0944623A2

    公开(公告)日:1999-09-29

    申请号:EP97954346.0

    申请日:1997-12-01

    CPC classification number: C07D413/04 A01N43/74 C07D417/04

    Abstract: The invention concerns substituted pyrazole-3-yl benzazoles of formula (I) and salts thereof, in the formula R1 designating H, C¿1?-C4 alkyl, C1-C4 alkyl halide; R?2¿ designating CN, C¿1?-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulphinyl, C1-C4-haloalkylsulphinyl, C1-C4-alkylsulphonyl, C1-C4-haloalkylsulphonyl; R?3¿ = H, CN, NO¿2?, halogen, C1-C4-alkyl, C1-C4-haloalkyl; R?4¿ designating H, halogen; R5 designating H, CN, halogen, C¿1?-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; Z designating -N=C(XR?6¿)-O- or -N=C(XR6)-S-, bonded to α by the nitrogen, oxygen or sulphur; X designating a chemical bond, oxygen, sulphur, -S(O)-, -SO¿2?-, -NH- or -N(R?7); R6, R7¿ designating C¿1?-C6-alkyl, C1-C6-haloalkyl, cyano-C1-C4-alkyl, hydroxy-C1-C4-alkyl, C3-C6-alkenyl, cyano-C3-C6-alkenyl, C3-C6-haloalkenyl, C3-C6-alkinyl, cyano-C3-C6-alkinyl, C3-C6-haloalkinyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C3-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkinyloxy-C1-C4-alkyl, C3-C8-cycloalkyloxy-C1-C4-alkyl, amino-C1-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di(C1-C4-alkyl)amino-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-haloalkylthio-C1-C4-alkyl, C3-C4-alkenylthio- C1-C4-alkyl, C3-C4-alkinylthio-C1-C4-alkyl, C1-C4-alkyl-sulphinyl-C1-C4-alkyl, C1-C4-haloalkylsulphinyl-C1-C4-alkyl, C3-C4-alkenylsulphinyl-C1-C4-alkyl, C3-C4-alkinylsulphinyl-C1-C4-alkyl, C1-C4-alkylsulphonyl-C1-C4-alkyl, C1-C4-haloalkylsulphonyl-C1-C4-alkyl, C3-C4-alkenylsulphonyl-C1-C4-alkyl, C3-C4-alkinylsulphonyl-C1-C4-alkyl, hydroxycarbonyl-C1-C4-alkyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl, which can carry a CN oder C1-C4-alkoxycarbonyl group, C1-C4-alkylthiocarbonyl-C1-C4-alkyl, aminocarbonyl-C1-C4-alkyl, C1-C4-alkylaminocarbonyl-C1-C4-alkyl, di(C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, di(C1-C4-alkyl)-phosphonyl-C1-C4-alkyl, C1-C4-alkoxyimino-C1-C4-alkyl, C3-C4-alkenyloxyimino-C1-C4-alkyl, optionally substituted C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, phenyl, phenyl-C1-C4-alkyl, 3- to 7-member heterocyclic or heterocyclyl-C1-C4-alkyl, wherein each cycloalkyl ring and each heterocyclyl ring contain a CO or CS ring member; if X is a chemical bond, -O-, -S-, -NH- or -N(R?7)-, R6¿ also being C¿1?-C4 alkylcarbonyl, C1-C4 haloalkylcarbonyl, C1-C4 alkoxycarbonyl, C1-C4 alkylsulphonyl or C1-C4 haloalkylsulphonyl; if X is a chemical bond, R?6¿ additionally designating CN, SH, NH¿2?, halogen, -CH2-CH(halogen)-R?8¿, -CH=CH-R8 or -CH=C(halogen)-R8, R8 designating COOH, C¿1?-C4 alkoxycarbonyl, C1-C4 alkylthiocarbonyl, CONH2, C1-C4 alkylaminocarbonyl, di(C1-C4 alkyl)aminocarbonyl or di(C1-C4 alkyl)phosphonyl; or R?6 plus R7¿ designating an optionally substituted 1,3-propylene, tetramethylene, pentamethylene or ethylene oxyethylene chain. The invention also concerns the use of these substances as herbicides and for the desiccation and/or defoliation of plants.

    SUBSTITUIERTE 1-METHYL-3-BENZYLURACILE
    27.
    发明公开
    SUBSTITUIERTE 1-METHYL-3-BENZYLURACILE 失效
    取代的1-甲基-3- BENZYLURACILE

    公开(公告)号:EP0891336A1

    公开(公告)日:1999-01-20

    申请号:EP97907086.0

    申请日:1997-03-10

    Abstract: The invention concerns substituted 1-methyl-3-benzyluracils (I) and their salts and enol ethers as herbicides or desiccating/defoliating agents. In formula (I), R1 is C1-C4 alkyl halide; R2 is H or halogen; R3 is R2, CN, SCN, C¿1?-C4 alkyl halide, C1-C4 alkoxy halide or C1-C4 alkylthio halide; R?4 is R3, C¿1-C4 alkyl, C1-C4 alkoxy or (C1-C6 alkylamino)-CO-; R5 is R2, CN, NO¿2?, OH, optionally substituted amino, alkoxy, alkylthio, alkyl-CO2-, alkyl-COS-, alkyl-SO2-O- or alkyl-SO2-, the six last-mentioned groups optionally being functionalized and/or substituted; R?6¿, if it is in the α position with R5 then being in the β position, is OH, SH, alkyl, alkoxy, alkylthio, alkyl-CO¿2?-, alkyl-COS-, alkoxy-CO-, alkoxy-CO2-, alkyl-SO2-O-, alkyl-SO2-, alkyl-CO-, alkyl-CS-, alkyl-(N-alkyl)-imino or alkyl-(N-alkoxy)-imino, the thirteen last-mentioned groups optionally being functionalized and/or substituted, or methyl substituted twice by optionally substituted alkoxy and alkylthio and optionally substituted once by alkyl; or R?6¿ in the β position, with R5 then being in the α position, has the above meanings, as well as alkyl-amino-CO-, alkoxy-CO-, alkylthio-CO-, alkyl-CO-, alkylimino-oxycarbonyl, alkyl-(N-alkoxy)-imino, alkoxy-(N-alkoxy)-imino or alkylthio-(N-alkoxy)-imino, the eight last-mentioned groups optionally being functionalized and/or substituted, or methyl substituted three times by optionally substituted alkoxy, alkylthio and alkylamino.

    SUBSTITUIERTE N-PHENYLGLUTARIMIDE UND N-PHENYLGLUTARSÄUREAMIDE, DEREN HERSTELLUNG UND VERWENDUNG IN DER LANDWIRTSCHAFT
    28.
    发明授权
    SUBSTITUIERTE N-PHENYLGLUTARIMIDE UND N-PHENYLGLUTARSÄUREAMIDE, DEREN HERSTELLUNG UND VERWENDUNG IN DER LANDWIRTSCHAFT 失效
    取代的N- phenylglutarimide和正PHENYLGLUTARSÄUREAMIDE,生产和使用农业

    公开(公告)号:EP0666848B1

    公开(公告)日:1998-12-30

    申请号:EP94900070.7

    申请日:1993-10-19

    Abstract: Substituted N-phenylglutarimides (I), wherein X1, X2 = O, S; R1 = halogen, NO¿2?, CN, CF3; R?2¿ = H, halogen; R?3, R4, R5¿ = H, halogen, CN, alkyl, cycloalkyl, alkenyl, alkinyl, alkyl halide, alkoxy, alkoxy halide, alkyl thio, alkyl thio halide, cyanoalkyl, alkoxy carbonyl, possibly substituted phenyl or benzyl, or 2 substituents of a C atom of the glutarimide ring are linked via a possibly substituted chain, or 2 substituents of adjacent C atoms of the glutarimide ring are linked via a possibly substituted chain; A = CHR6-CHR7-CO-B or CR6=CR8-CO-B; R6 = H, C¿1?-C6-alkyl or C1-C6-alkyl halide; R?7¿ = halogen, alkyl halide, OH, alkoxy or alkyl carbonyl alkoxy; R8 = H, halogen, CN, alkyl, alkyl halide, OH, alkoxy, alkyl carbonyl, alkoxy carbonyl or alkyl carbonyloxy; B = H, alkyl, alkenyl, alkinyl, alkyl halide, cycloalkyl, alkoxy alkyl, dialkoxy alkyl, alkyl thioalkyl, OR?9, SR9, NR10, R11; R9¿ = H, alkyl, alkenyl, alkinyl, cycloalkyl, alkyl halide, cyanoalkyl, alkenyl halide, alkoxy carbonyl alkyl, alkoxyalkyl, alkyl thioalkyl, alkylimino, alkylimino alkyl, possibly substituted phenyl or benzyl; R10, R11 = H, alkyl, alkenyl, alkinyl, cycloalkyl, alkyl halide, alkyl carbonyl, alkoxy carbonyl, alkoxy alkyl, possibly substituted phenyl, or R?10 und R11¿ together with the common N atom = saturated or unsaturated 4- to 7- membered heterocycle with 1-2 other heteroatoms, as well as salts of (I) that are tolerable to plants; their preparation and use as herbicides and desiccants/defoliants, as well as preproducts for preparing the N-phenylglutarimides (I).

    SUBSTITUIERTE 2-PHENYLPYRIDINE ALS HERBIZIDE
    30.
    发明公开
    SUBSTITUIERTE 2-PHENYLPYRIDINE ALS HERBIZIDE 失效
    取代基2-苯基吡啶ALS HERBIZ

    公开(公告)号:EP0851858A1

    公开(公告)日:1998-07-08

    申请号:EP96932485.0

    申请日:1996-09-09

    CPC classification number: C07D213/61 A01N43/40

    Abstract: The invention concerns 2-phenylpyridines (I) and their salts, in which, n = 0, 1; R1 = halogen, C¿1?-C4 alkylhalide; R?2, R3¿ = H, halogen; R4 = CN, halogen; R5 = -CO-O-( C¿1?-C4 alkylene)-CO-OR?6¿, -CO-O-(C¿1?-C4 alkylene)-CO-N(R?7)R8¿, -O-(C¿1?-C4 alkylene)-CO-O-(C1-C4 alkylene)-CO-OR?6¿, -O-(C¿1?-C4 alkylene)-CO-O-(C1-C4 alkylene)-CO-N(R?7)R8¿, -S-(C¿1?-C4 alkylen)-CO-O-(C1-C4 alkylene)-CO-OR?6¿ or -S-(C¿1?-C4 alkylene)-CO-O-(C1-C4 alkylene)-CO-N(R?7)R8; R6¿ = H, C¿1?-C4 alkyl,(C1-C4 alkoxy)(C1-C4 alkyl), C2-C4 alkenyle, C3-C4 alkinyl; R?7¿ = H, C¿1?-C4 alkyl, carboxyl(C1-C4 alkyl), (C1-C4 alcoxycarbonyl)(C1-C4 alkyl); R?8¿ = H or C¿1?-C4 alkyl. Such compounds are suitable for use as herbicides and as plant desiccants/defoliants.

    Abstract translation: 本发明涉及2-苯基吡啶(I)及其盐,其中n = 0,1; R1 =卤素,C1-C4烷基卤化物; R 2,R 3'= H,卤素; R4 = CN,卤素; R 5 = -CO-O-(C 1 -C 4亚烷基)-CO-OR 6,-CO-O-(C 1 -C 4亚烷基)-CO-N(R 7)R 8, (C 1 -C 4亚烷基)-CO-O-(C 1 -C 4亚烷基)-CO-OR 6', - O-(C 1 -C 4亚烷基)-CO-O-(C1 (亚烷基)-CO-N(R 7)R 8,-S-(C 1 -C 4亚烷基)-CO-O-(C 1 -C 4亚烷基)-CO-OR 6或-S- (C 1 -C 4亚烷基)-CO-O-(C 1 -C 4亚烷基)-CO-N(R 7)R 8; (C 1 -C 4烷氧基)(C 1 -C 4烷基),C 2 -C 4烯烯基,C 3 -C 4炔基; R 6是H,C 1 -C 4烷基, (C 1 -C 4烷基),(C 1 -C 4烷氧基羰基)(C 1 -C 4烷基); R 4为H,C 1 -C 4烷基。 R 8 = H或C 1 -C 4烷基。 这样的化合物适合用作除草剂和植物干燥剂/脱叶剂。

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