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公开(公告)号:AT421378T
公开(公告)日:2009-02-15
申请号:AT01936136
申请日:2001-03-23
Applicant: BASF SE
Inventor: FISCHER ROLF-HARTMUTH , PINKOS ROLF , SCHUNK STEPHAN , WULFF-DOERING JOACHIM
IPC: B01J23/36 , B01J21/18 , B01J23/656 , B01J23/889 , C07B61/00 , C07C29/136 , C07C29/149 , C07C31/20 , C07C31/27
Abstract: A catalyst (I) comprises 0.01-50 wt.% rhenium and 0-20 wt.% of an additional metal comprising Zn, Cu, Ag, Au, Ni, Fe, Cr or V on an oxidatively pretreated activated carbon support. An independent claim is included for production of alcohols by catalytic hydrogenation of carbonyl compounds by means of a catalyst (I).
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公开(公告)号:DE50113838D1
公开(公告)日:2008-05-21
申请号:DE50113838
申请日:2001-09-20
Applicant: BASF SE
Inventor: OHLBACH FRANK , LUYKEN HERMANN , ANSMANN ANDREAS , FISCHER ROLF-HARTMUTH , MELDER JOHANN-PETER , BASSLER PETER
IPC: B01J38/52 , B01J23/86 , B01J23/94 , C07B61/00 , C07C209/48 , C07C211/12
Abstract: A process is provided for the regeneration of a heterogeneous catalyst used for the preparation of compounds containing NH 2 groups by the hydrogenation, with hydrogen, of compounds containing at least one unsaturated carbon-nitrogen bond, wherein a) the feed of the compound to be hydrogenated is stopped and b) the heterogeneous catalyst is treated with a compound of the formula R 1 R 2 N-CO-R 3 (I), in which R 1 is hydrogen or C 1 -C 4 alkyl and R 2 , R 3 independently of one another are each hydrogen or C 1 -C 4 alkyl or together are a C 3 -C 6 alkylene group, or mixtures of such compounds, at a pressure ranging from 0.1 to 30 MPa and a temperature ranging from 100 to 300° C., with the proviso that the compound of formula (I) is in liquid form during the treatment.
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