Preparation containing at least one type of fungicidal conazole

    公开(公告)号:AU2011254094B2

    公开(公告)日:2013-09-05

    申请号:AU2011254094

    申请日:2011-12-16

    Applicant: BASF SE

    Abstract: The invention relates to preparations, in particular plant preparations which contain a mixture of at least two different active plant-protective substances, wherein a) at least one active substance is selected from a conazole group (active substance 1) and b) another active plant-protective substance (active substance 2) whose water solubility at a temperature of 20 0C is less than 20 g/l, c) at least one type of copolymer CP consisting of M monomers comprising a) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group and P) at least one type of neutral monoethylenically unsaturated monomer M2, wherein the quantitative ratio between the active substance 1 and the other active plant protective substance 2 ranges from 1:10 to 10:1. Said invention also relates to novel copolymers CP which are embodied in the form of polymers consisting of at least three types of different monoethylenically unsaturated monomers M and comprise, in the polymerisation incorporated form, a) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group, Pl) at least one type of neutral monoethylenically unsaturated monomer M2 whose water solubility at a temperature of 20 0C is less than 30 g/l and P2) at least one type of neutral monoethylenically unsaturated monomer M2b whose solubility at a temperature of 20 0C is greater than 50 g/l.

    Preparation containing at least one type of fungicidal conazole

    公开(公告)号:AU2011254094A1

    公开(公告)日:2012-01-19

    申请号:AU2011254094

    申请日:2011-12-16

    Applicant: BASF SE

    Abstract: The invention relates to preparations, in particular plant preparations which contain a mixture of at least two different active plant-protective substances, wherein a) at least one active substance is selected from a conazole group (active substance 1) and b) another active plant-protective substance (active substance 2) whose water solubility at a temperature of 20 0C is less than 20 g/l, c) at least one type of copolymer CP consisting of M monomers comprising a) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group and P) at least one type of neutral monoethylenically unsaturated monomer M2, wherein the quantitative ratio between the active substance 1 and the other active plant protective substance 2 ranges from 1:10 to 10:1. Said invention also relates to novel copolymers CP which are embodied in the form of polymers consisting of at least three types of different monoethylenically unsaturated monomers M and comprise, in the polymerisation incorporated form, a) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group, Pl) at least one type of neutral monoethylenically unsaturated monomer M2 whose water solubility at a temperature of 20 0C is less than 30 g/l and P2) at least one type of neutral monoethylenically unsaturated monomer M2b whose solubility at a temperature of 20 0C is greater than 50 g/l.

    FORMULACIONES DE SUSTANCIA ACTIVA QUE CONTIENEN COPOLIMEROS CON ACIDO SULFONICO Y ACRILATO DE FENOXIETILO.

    公开(公告)号:ES2364660T3

    公开(公告)日:2011-09-08

    申请号:ES04790621

    申请日:2004-10-19

    Applicant: BASF SE

    Abstract: Formulación de sustancia activa que contiene a) al menos una sustancia activa seleccionada del grupo de las sustancias protectoras de vegetales b) al menos un copolímero radical aleatorio estructurado de los monómeros i), ii) y iii), en cuyo caso i) es al menos un ácido sulfónico insaturado olefínicamente de la fórmula I **Fórmula** donde n es 0 a 10 X es O o NR5 R1 es hidrógeno o metilo R2, R3 independientemente uno de otro son hidrógeno, alquilo de C1 a C6 R5 es hidrógeno, alquilo, arilo, alquilarilo, arilalquilo, alcoxialquilo, ariloxialquilo, alcoxiarilo, hidroxialquilo, (di)alquilaminoalquilo, (di)alquilaminoarilo, (di)arilaminoalquilo, alquilarilaminoalquilo, alquilarilaminoarilo, en cuyo caso los residuos de arilo pueden estar sustituidos o son sales de los mismos o mezclas de ácido y sales y ii) fenoxietilacrilato, iii) opcionalmente otros monómeros insaturados olefínicamente de la fórmula IIb **Fórmula** en cuyo caso Y es O o NR5, R10 es hidrógeno o metilo, R5, R6 significan hidrógeno, alquilo, arilo, alquilarilo, arilalquilo, alcoxialquilo, aril-oxialquilo, alcoxiarilo, hidroxialquilo, (di)alquilaminoalquilo, (di)alquilaminoarilo, (di)arilaminoalquilo, alquilarilaminoalquilo, alquilarilaminoarilo, en cuyo caso los residuos arilo pueden estar sustituidos y c) opcionalmente otros aditivos, que puede prepararse mediante un método, caracterizada porque se disuelven (i) los componentes a) y b) y opcionalmente c) así como opcionalmente otros aditivos separados unos de otro en solventes iguales o diferentes y se mezclan las soluciones unas con otras y opcionalmente a continuación se retira el solvente de manera usual en la mayor medida posible; o (ii) se prepara una solución conjunta de los componentes a) y b) y opcionalmente c) así como opcionalmente otros aditivos, cargando uno de los componentes disuelto en un solvente orgánico, adicionando los otros componentes y disolviendo y opcionalmente a continuación se retira el solvente de manera usual en la mayor medida posible; o (iii) se lleva el componente b) así como opcionalmente otros aditivos a solución acuosa, los componentes a) y dado el caso c) y opcionalmente se disuelven otros aditivos en uno o varios solventes orgánicos miscibles con agua, se mezclan las soluciones de los componentes entre sí, mediante suministro de energía se obtiene la formulación de sustancia activa en forma dispersada y opcionalmente a continuación se retira el solvente de manera usual en la mayor medida posible.

    PROCESS FOR THE PREPARATION OF RANDOM RADICAL COPOLYMERS, AND ACTIVE SUBSTANCE COMPOSITIONS OBTAINABLE THEREFROM

    公开(公告)号:CA2745249A1

    公开(公告)日:2010-06-10

    申请号:CA2745249

    申请日:2009-11-30

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing random radical copolymers, characterized by the following steps: a) dissolving by heating a) at least one olefinically unsaturated sulfonic acid of formula (I); wherein n is 0 to 10; X represents O or NR5; R1 represents hydrogen or methyl; R2, R3 independently represent hydrogen or C1 to C6 alkyl and R5 represents hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, wherein the aryl groups can be mono- or polysubstituted, the salts thereof or mixtures of acid and salts and b) at least two structurally distinct olefinically unsaturated monomers of formula (II), wherein Y represents O or NR7; R5 represents hydrogen or methyl; R6 represents alkyl, hydroxyalkyl, (di)alkylaminoalkyl or (di)alkylaminoaryl and R7 represents hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, and c) optionally one or more olefinically unsaturated monomers which can be structurally distinct from components (a) and (b), and at least one initiator, either (i) in a solvent mixture which contains water and a solvent having a boiling point below 140°C and being soluble in water, or (ii) in one or more pure alcohols, and polymerizing said mixture in solution, the copolymer formed also remaining dissolved. The copolymers obtainable according to the above method are suitable as formulation adjuvants in agrochemical active ingredient compositions.

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