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    21.
    发明专利
    未知

    公开(公告)号：AT493387T

    公开(公告)日：2011-01-15

    申请号：AT07786819

    申请日：2007-06-25

    Applicant: BASF SE

    Inventor： SCHOENING KAI-UWE ,  FISCHER WALTER ,  BASBAS ABDEL-ILAH ,  DICHTL ALEXANDER

    IPC: C07D211/94 ,  C07B43/00

    Abstract: The present invention relates to a novel process for the preparation of a sterically hindered nitroxyl ether from the corresponding sterically hindered nitroxyl radical by reacting it with a carbonyl compound and a hydroperoxide. The compounds prepared by this process are effective stabilizers for polymers against harmful effects of light, oxygen and/or heat, as flame-retardants for polymers and as polymerization regulators.

    5H-FURAN-2-ONE DERIVATIVES FOR STABILIZATION OF ORGANIC MATERIAL
    23.
    发明专利
    5H-FURAN-2-ONE DERIVATIVES FOR STABILIZATION OF ORGANIC MATERIAL 未知

    公开(公告)号：SG194519A1

    公开(公告)日：2013-12-30

    申请号：SG2013077276

    申请日：2012-04-25

    Applicant: BASF SE

    Inventor： FISCHER WALTER ,  BASBAS ABDEL-ILAH ,  SCHOENING KAI-UWE ,  TARTARINI CINZIA ,  HOELZL WERNER ,  ROTZINGER BRUNO

    Abstract: A composition, which comprises a) an organic material susceptible to oxidative, thermal or light-induced degradation; and b) a compound of formula I (Formula I) (I) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 are independently from each other H, C1-C8-alkyl, C4-C8-cycloalkyl, phenyl, C1-C4-alkoxy or halogen; n is 1, 2, 3, or 4; and when n is 1 A is -C(=0)-OR'1,-C(=0)-N(R'2)(R'3), -CN, phenyl, which is unsubstituted or substituted by one or more C1-C8-alkyl, C4-C8-alkoxy, C5-C7-cycloalkyl or halogen, -H or -S02-phenyl; when n is 2 A is -C(=0)-0-Z1-O-C(=0)-, -C(=0)-N(R" 1)-Z2-N(R"2)-C(=0)- or piperazine-N,N'-biscarbonyl.

    SULPHUR CEMENT PRODUCT
    27.
    发明专利
    SULPHUR CEMENT PRODUCT 未知

    公开(公告)号：CA2762361A1

    公开(公告)日：2010-12-16

    申请号：CA2762361

    申请日：2010-06-01

    Applicant: BASF SE

    Inventor： SCHOENING KAI-UWE ,  EDENHARTER ADRIANA ,  HAUCK STEFAN

    IPC: C07D471/10

    Abstract: The instant invention pertains to sterically hjndered amine Nght stabilizers (HALS) with low basicity at the nitrogen atom and high thermal stability. They are characterized by their spiro- substitution in the 4-position of the tetramethylpiperidine ring (Spiro-NOR-HALS). These compounds are particularly effective in stabilizing polymers, especially thermoplastic polyolefins, against the deleterious effects of oxidative, thermal and actinic radiation. The compounds are also particularly effective in stabilizing acid catalyzed and ambient cured coatings systems. They are particularly useful when high processing temperatures are additional required.

    28.
    发明专利
    未知

    公开(公告)号：AT483819T

    公开(公告)日：2010-10-15

    申请号：AT03743326

    申请日：2003-02-25

    Applicant: BASF SE

    Inventor： OEHRLEIN REINHOLD ,  SCHOENING KAI-UWE ,  BAISCH GABRIELE ,  SCHMIDT JEMIMA ,  BAUDIN GISELE ,  JUNG TUNJA

    IPC: C12N11/08 ,  C12P9/00 ,  C07F7/08 ,  C07F7/10

    Abstract: The invention relates to a process for preparing organosilicon group containing photoinitiators of the formula (I), wherein m is a number from 1 to 200; q is 0 or 1; A is IN-C(O)-O-CHR 3 -Y- or IN-C(O)-NH-CHR 3 -Y-; A' is A or R 1 '; R 1 and R 1 ', R 2 and R 2 ' are C 1 -C 18 alkyl or phenyl, or -(O) q -SiR 1 R 1 'R 2 ; R 3 is hydrogen or C 1 -C 6 alkyl, Y is a divalent group selected from C 1 -C 10 alkeylene, C 2 -C 10 alkenylene or -(CH 2 ) b -O-(CH 2 ) a -; and b are each independently of the other a number of 1 to 6; IN is a photolabile functional moiety of the formula (II) or (III), wherein R 4 is hydrogen or -C(O)-C(O)-OH or -C(O)-C(O)-OC 1 -C 6 alkyl and n is 1-3; R 5 and R 6 are C 1 -C 1-2 alkyl or together are cycloC 5 -C 7 alkyl; R 7 is hydroxy, C 1 -C 6 alkoxy or morpholinyl; X is -(CH 2 ) a -, -(CH 2 ) b -O-(CH 2 ) a - or -(CH 2 ) b -O-CO-(CH 2 ) a -; a and b are each independently of the other a number of 1 to 6; whereby the process is characterized in that a photolabile functional moiety containing a carboxy group (IN-COOH) or an alkoxycarbonyl group (IN-CO-OC 1 -C 6 alkyl) is reacted with a carbinol- or amino terminated organosilicon compound of the formula (IV), wherein m, R 1 and R 1 ', R 2 and R 2 ' are as defined above and B is -Y-CHR 3 -OH or -Y-CHR 3 -NH 2 ; B' is B or R 1 ', in the presence of an enzyme which catalyzes the esterification, transesterification or amidation reaction.

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