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    LIQUID OXYALKYLENE BRIDGED BIS- AND TRIS-PHOSPHITE ESTER MIXTURES
    2.
    发明申请
    LIQUID OXYALKYLENE BRIDGED BIS- AND TRIS-PHOSPHITE ESTER MIXTURES 审中-公开
    液体氧亚氨基双环和三磷酸酯混合物

    公开(公告)号：WO2010003809A2

    公开(公告)日：2010-01-14

    申请号：PCT/EP2009057751

    申请日：2009-06-23

    Applicant: BASF SE ,  KING ROSWELL EASTON ,  PADEGIMAS STANLEY J ,  BAKKE BRIAN ,  MOORE LUCAS R ,  SHUM SAI PING ,  CORDOVA ROBERT

    Inventor： KING ROSWELL EASTON ,  PADEGIMAS STANLEY J ,  BAKKE BRIAN ,  MOORE LUCAS R ,  SHUM SAI PING ,  CORDOVA ROBERT

    IPC: C07F9/145 ,  C08K5/526

    CPC classification number: C07F9/145 ,  C08K5/526 ,  C08K2201/014 ,  C08L23/02

    Abstract: Disclosed are liquid compositions comprising a) a compound of formula (I) and b) a compound of formula (II) where R is hydrogen or methyl, n and n' are independently an integer from 1 to 45 and R1, R2 and R3 are each independently hydrogen, straight or branched chain alkyl of 1 to 12 carbon atoms, phenylalkyl of 7 to 9 carbon atoms, phenylalkyl of 7 to 9 carbon atoms substituted on the phenyl ring by one to three straight or branched chain alkyl of 1 to 12 carbon atoms or R1, R2 and R3 are each independently -(CH2 ) k -COOR 4 where k is 0, 1 or 2 and R4 is hydrogen or straight or branched chain alkyl of 1 to 20 carbon atoms. The compositions comprising oxyalkylene bridged bis-and tris-phosphite esters of formulae I and II are liquid at ambient conditions and are effective stabilizers for polyolefins.

    Abstract translation: 公开了液体组合物，其包含a）式（I）化合物和b）式（II）化合物，其中R是氢或甲基，n和n'独立地是1至45的整数，并且R 1，R 2和R 3是 各自独立地为氢，1至12个碳原子的直链或支链烷基，7至9个碳原子的苯基烷基，7至9个碳原子的苯基烷基在苯基环上被1至3个直链或支链1至12个碳原子的烷基取代 原子或R 1，R 2和R 3各自独立地为 - （CH 2）k -COOR 4，其中k为0,1或2，R 4为氢或1至20个碳原子的直链或支链烷基。 包含式I和II的氧化烯桥接的双 - 和三 - 亚磷酸酯的组合物在环境条件下是液体并且是聚烯烃的有效稳定剂。

    LIQUID STABILIZER MIXTURES
    3.
    发明公开
    LIQUID STABILIZER MIXTURES 有权
    液体稳定剂混合物

    公开(公告)号：EP2766419A4

    公开(公告)日：2015-06-10

    申请号：EP12840357

    申请日：2012-09-27

    Applicant: BASF SE

    Inventor： YU JIONG ,  KING ROSWELL EASTON

    IPC: C08K5/00 ,  C08J3/00 ,  C08K5/05 ,  C08K5/134 ,  C08K5/52 ,  C08K5/526

    CPC classification number: C08K5/134 ,  C08K5/1345 ,  C08K5/52 ,  C08K5/526

    Abstract: The present invention relates to two processes for providing stable liquid blends of a) pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, b) octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate and c) tris-(2,4-di-tert-butylphenyl)phosphite. The first process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a), about 2 parts to about 3 parts by weight b) and about 2 parts to about 12 parts by weight c), heating the mixture to 185° C. or higher for a sufficient time to obtain a clear liquid blend of a), b) and c), cooling the liquid blend to a temperature of from 90° C. to 140° C. and maintaining the liquid blend at a temperature of from 90° C. to 140° C. The second process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a) and about 2 parts to about 3 parts by weight b), heating the mixture to 90° C. or higher for a sufficient time to obtain a clear liquid mixture of a) and b), adding about 2 parts to about 12 parts by weight c) thereto to obtain a clear liquid blend of a), b) and c) and maintaining the liquid blend at a temperature of from 90° C. to 140° C. The liquid blends of a), b) and c) are stable at the temperature at which they are maintained for greater than 120 hours.

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