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    22.
    发明专利
    未知

    公开(公告)号：BRPI0615856A2

    公开(公告)日：2012-12-18

    申请号：BRPI0615856

    申请日：2006-09-06

    Applicant: BASF SE

    Inventor： STROEFER EICKHARD ,  STAMMER ACHIM ,  SIEGERT MARKUS ,  LANG NEVEN

    IPC: C07D317/12

    Abstract: Processes comprising: providing a reactive distillation column having an upper region, a middle region and a lower region; feeding ethylene glycol and an aqueous formaldehyde solution into the reactive distillation column in the middle region of the reactive distillation column; reacting the ethylene glycol and the aqueous formaldehyde solution in the reactive distillation column in the presence of a catalyst to form dioxolane; removing a product stream comprising dioxolane in an amount of at least 75% by weight from the upper region of the reactive distillation column; and removing a bottom stream comprising one or more components having boiling points higher than dioxolane from the lower region of the reactive distillation column.

    25.
    发明专利
    未知

    公开(公告)号：AT518574T

    公开(公告)日：2011-08-15

    申请号：AT08708109

    申请日：2008-01-23

    Applicant: BASF SE

    Inventor： LANG NEVEN ,  THIEL JOACHIM ,  STROEFER ECKHARD ,  KIRSCHBAUM JULIA ,  SIEGERT MARKUS

    IPC: B01D3/14 ,  C07D323/06

    Abstract: A process for removing trioxane from a use stream I of formaldehyde, trioxane and water, by a) providing a use stream I which comprises formaldehyde as the main component and trioxane and water as the secondary components, b) feeding the use stream I, a recycle stream V and a recycle stream VII which comprises formaldehyde as the main component and water and trioxane as the secondary components into a first distillation stage and distilling to obtain a stream II a steam III and formaldehyde as the and a steam X c) distilling the stream III, in a second distillation stage the pressure in the second distillation stage being from 0.1 to 15 bar higher than the pressure in the first distillation stage, to obtain a stream IV and the recycle stream V as the secondary components, d) feeding the stream X and if appropriate a stream IX into a third distillation stage and distilling at a pressure of from 1 to 10 bar to obtain a stream VI which consists substantially of water and a recycle stream VII which comprises formaldehyde as the main component and water and trioxane as the secondary components.

    28.
    发明专利
    未知

    公开(公告)号：AT485287T

    公开(公告)日：2010-11-15

    申请号：AT08718289

    申请日：2008-03-27

    Applicant: BASF SE

    Inventor： STROEFER ECKHARD ,  LANG NEVEN ,  SIEGERT MARKUS ,  HASSE HANS

    IPC: C07D323/06

    Abstract: A process for preparing trioxane from trioxymethylene glycol dimethyl ether (POMDMEn=3) by converting trioxymethylene glycol dimethyl ether in the presence of an acidic catalyst and subsequent distillative workup of the reaction mixture, comprising the steps of: a) feeding trioxymethylene glycol dimethyl ether (POMDMEn=3) or a mixture comprising trioxymethylene glycol dimethyl ether into a reactor and converting it in the presence of an acidic catalyst to a mixture a comprising trioxane, formaldehyde, water, methylene glycol (MG), polyoxymethylene glycols (MGn>1), methanol, hemiformals (HF), methylal (POMDMEn=1) and polyoxymethylene glycol dimethyl ethers (POMDMEn>1); b) distillatively separating the reaction mixture a into a low boiler fraction b1 comprising formaldehyde, water, methylene glycol, methanol, hemiformal (HFn=1), methylal and dioxymethylene glycol dimethyl ether (POMDMEn=2), and a high boiler fraction b2 comprising trioxane, polyoxymethylene glycols (MGn>1), hemiformals (HFn>1) and polyoxymethylene glycol dimethyl ethers (POMDMEn>2); c) distillatively separating the high boiler fraction b2 into a low boiler fraction c1 comprising trioxane, and a high boiler fraction c2 comprising polyoxymethylene glycols (MGn>1), hemiformals (HFn>1) and polyoxymethylene glycol dimethyl ethers (POMDMEn>2).

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