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    21.
    发明专利
    未知

    公开(公告)号：DE60222512T2

    公开(公告)日：2008-01-31

    申请号：DE60222512

    申请日：2002-08-28

    Applicant: DAICEL CHEM

    Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA ,  INOUE KEIZO

    IPC: C07C41/16 ,  C07B61/00 ,  C07C43/16 ,  C07C43/162 ,  C07C43/166 ,  C07C43/188 ,  C07C43/215 ,  C07C49/753 ,  C07C67/31 ,  C07C69/00 ,  C07C69/757 ,  C07D307/32 ,  C07D307/33 ,  C07D307/93 ,  C07D313/10 ,  C07D493/04

    Abstract: A vinyl ether compound represent by following Formula (4): wherein ring Z is any one of cyclic groups represented by following Formulae (5) through (12): wherein X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , X 7 , and X 8 are each a substituent combined with an atom constituting each ring and are each a halogen atom, an alkyl group, a haloalkyl group, an aryl group, a hydroxyl group which may be protected by a protecting group, a hydroxymethyl group which may be protected by a protecting group, an amino group which may be protected by a protecting group, a carboxyl group which may be protected by a protecting group, a sulfo group which may be protected by a protecting group, an oxo group, a nitro group, a cyano group, or an acyl group which may be protected by a protecting group, wherein, when there are two or more substituents X 1 s, these X 1 s may be combined to form a ring containing four or more members with a carbon atom constituting the cyclohexane ring in Formula (5); a, b, c, d, e, f, g, and h are each an integer of 0 or more, wherein when a, b, c, d, 3, f, g or h is 2 or more, the substituents in the parentheses may be the same or different; and p, q, and r are each an integer of from 0 to 3; W is a divalent hydrocarbon group; R 2 , R 3 , and R 4 are the same or different and are each a hydrogen atom or an organic group; n is 0 or 1; and m is an integer of from 1 to 8, wherein groups in the parentheses may be the same or different when m is 2 or more; wherein a in Formula (5) is 1 or more and b in Formula (6) is 1 or more when n is 0 and m is 1; and wherein c is 1 or more when p is 0 or 1, and X 3 is a group other than hydroxyl group when p is 0 and c is 1 in Formula (7).

    22.
    发明专利
    未知

    公开(公告)号：DE60308246D1

    公开(公告)日：2006-10-26

    申请号：DE60308246

    申请日：2003-03-06

    Applicant: DAICEL CHEM

    Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA ,  IWAHAMA TAKAHIRO

    IPC: C07C249/06 ,  C07B47/00 ,  C07B61/00 ,  C07C5/42 ,  C07C15/44 ,  C07C29/48 ,  C07C33/20 ,  C07C45/28 ,  C07C47/54 ,  C07C47/542 ,  C07C49/395 ,  C07C49/403 ,  C07C49/413 ,  C07C49/78 ,  C07C67/035 ,  C07C69/14 ,  C07C69/157 ,  C07C201/00 ,  C07C201/08 ,  C07C205/04 ,  C07C205/16 ,  C07C207/02 ,  C07C251/40 ,  C07C251/44 ,  C07C251/48 ,  C07C253/02 ,  C07C255/50

    Abstract: A process produces an organic compound by allowing (A) a compound capable of generating a free radical to react with (B) at least one of esters and salts of nitrous acid in the presence of a nitrogen-containing cyclic compound constitutively having a skeleton represented by following Formula (i) in its ring: wherein X is an oxygen atom or an -OR group, and wherein R is a hydrogen atom or a hydroxyl-protecting group. Examples of the nitrogen-containing cyclic compound are cyclic imide compounds having a cyclic imide skeleton represented by following Formula (I): wherein n is 0 or 1; X is an oxygen atom or an -OR group, and wherein R is a hydrogen atom or a hydroxyl-protecting group.A process produces an organic compound by allowing (A) a compound capable of generating a free radical to react with (B) at least one of esters and salts of nitrous acid in the presence of a nitrogen-containing cyclic compound constitutively having a skeleton represented by following Formula (i) in its ring: wherein X is an oxygen atom or an -OR group, and wherein R is a hydrogen atom or a hydroxyl-protecting group. Examples of the nitrogen-containing cyclic compound are cyclic imide compounds having a cyclic imide skeleton represented by following Formula (I): wherein n is 0 or 1; X is an oxygen atom or an -OR group, and wherein R is a hydrogen atom or a hydroxyl-protecting group.

    PROCESS FOR PRODUCING HYDROGEN PEROXIDE
    23.
    发明专利
    PROCESS FOR PRODUCING HYDROGEN PEROXIDE 未知

    公开(公告)号：MY119957A

    公开(公告)日：2005-08-30

    申请号：MYPI20000384

    申请日：2000-02-03

    Applicant: DAICEL CHEM

    Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA

    IPC: C01B15/026

    Abstract: A PROCESS PRODUCES HYDROGEN PEROXIDE BY REACTING A PRIMARY OR SECONDARY ALCOHOL WITH OXYGEN IN THE PRESENCE OF AN IMIDE COMPOUND OF THE FOLLOWING FORMULA (1) :WHEREIN EACH OF R1 AND R2 IS, IDENTICAL TO OR DIFFERENT FROM EACH OTHER, A HYDROGEN ATOM, A HALOGEN ATOM, AN ALKYL GROUP, AN ARYL GROUP, A CYCLOALKYL GROUP, A HYDROXYYL GROUP, AN ALKOXY GROUP, A CARBOXYL GROUP, AN ALKOXYCARBONYL GROUP, OR AN ACYL GROUP, WHERE R1 AND R2 MAY BE COMBINED TO FORM A DOUBLE BOND, OR AN AROMATIC OR NON-AROMATIC RING; X IS AN OXYGEN ATOM OR A HYDROXYL GROUP, WHERE ONE OR TWO N-SUBSTITUTED CYCLIC IMIDO GROUPS INDICATED IN THE FORMULA (1) MAY BE FURTHER BONDED TO THE R1, R2, OR TO THE DOUBLE BOND OR AROMATIC OR NON-AROMATIC RING FORMED TOGETHER BY R1 AND R2, TO YIELD HYDROGEN PEROXIDE. ACCORDING TO THE PROCESS, HYDROGEN PEROXIDE CAN BE EASILY AND EFFICIENTLY OBTAINED FROM READLY AVAILABLE MATERIALS.

    26.
    发明专利
    未知

    公开(公告)号：DE60002529T2

    公开(公告)日：2003-11-20

    申请号：DE60002529

    申请日：2000-02-01

    Applicant: DAICEL CHEM

    Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA

    IPC: C01B15/026

    Abstract: The invented process produces hydrogen peroxide by reacting a primary or secondary alcohol with oxygen in the presence of an imide compound of the following formula (1): wherein each of R and R is, identical to or different from each other, a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cycloalkyl group, a hydroxyl group, an alkoxy group, a carboxyl group, an alkoxycarbonyl group, or an acyl group, where R and R may be combined to form a double bond, or an aromatic or non-aromatic ring; X is an oxygen atom or a hydroxyl group, where one or two N-substituted cyclic imido groups indicated in the formula (1) may be further bonded to the R , R , or to the double, bond or aromatic or non-aromatic ring formed together by R and R , to yield hydrogen peroxide. According to the process, hydrogen peroxide can be easily and efficiently obtained from readily available materials.

    METHOD FOR SURFACE MODIFICATION OF MOLDED ARTICLE OF PLASTIC AND METHOD FOR MODIFYING POLYMER
    29.
    发明公开
    METHOD FOR SURFACE MODIFICATION OF MOLDED ARTICLE OF PLASTIC AND METHOD FOR MODIFYING POLYMER 有权
    方法用于改性聚合物表面改性形塑料对象和方法

    公开(公告)号：EP1120438A4

    公开(公告)日：2004-06-09

    申请号：EP00915398

    申请日：2000-04-07

    Applicant: DAICEL CHEM

    Inventor： ISHII YASUTAKA ,  FUNAKI YOSHINORI ,  NAKANO TATSUYA

    IPC: C08J7/12 ,  C08J3/00

    CPC classification number: C08J7/12

    Abstract: A method for the surface modification of a molded article of a plastic comprising treating a molded article of a plastic with an oxygen-containing gas such as oxygen, carbon monoxide, a nitrogen oxide or a sulfur oxide in the presence of an imide compound such as N-hydroxy, phthalimide which is represented by formula (1): wherein R and R may be the same or different and each represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cycloalkyl group, a hydroxyl group, an alkoxy group, a carboxyl group, an alkoxycarbonyl group or an acyl group, and R and R may be bonded to each other to form together a double bonding or an aromatic or non-aromatic ring, and X represents an oxygen atom or a hydroxyl group; and a method for modifying a polymer comprising treating the polymer with an oxygen-containing gas such as oxygen, carbon monoxide, a nitrogen oxide or a sulfur oxide in the presence of an imide compound which is represented by formula (1).

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