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    22.
    发明专利
    未知

    公开(公告)号：DE19536363A1

    公开(公告)日：1997-04-03

    申请号：DE19536363

    申请日：1995-09-29

    Applicant: DEGUSSA

    Inventor： WIELAND STEFAN DR ,  AUER EMMANUEL DR ,  LANSINK-ROTGERINK HANS DR ,  JACOBSEN HAUKE DR ,  GRADL ROBERT

    IPC: C08G77/28 ,  C08G77/48 ,  C08G77/58 ,  C07F7/18 ,  C07F19/00 ,  C07B37/04 ,  C07C39/16 ,  C07C37/16 ,  B01J31/02 ,  B01J31/26

    Abstract: The formed sulphonate and SH gp.-contg. organo-polysiloxanes (OFP) contain units of formula (I) and (III): ÄO3/2SiR1SO3ÜxMx+ (I) O3/2SiR2SH (III) where R1 = 1-12 C alkylene, 5-8 C cycloalkylene or a gp. of formula -(CH2)n-Cy-(CH2)m- or -(CH2)n-Ph-(CH2)m- (II); where n and m = 0-6; Cy = cyclohexylene; Ph = phenylene; M = H, NH4 or a metal ion with a valency of 1-4; R2 = R1; the free valencies of the O atoms attached to Si are taken up by the Si atoms in other gps. (I) and/or (II) and/or by the metal atom-oxygen gps. in crosslinking bridging gps. of formula SiO4/2 (IV) and opt. R''SiO3/2, R'SiO3/2, AlO3/2, R'AlO2/2, TiO4/2, R'TiO3/2 (V), in which R' = Me or Et; R" = Ph or 2-12 C alkyl. The ratio of gps. (I):(III) is 10:1-1:10, the ratio of gps. (I):(IV) is 1:3-1:20 and the ratio of gps. (IV):(V) is 1:0-1:0.5. Also claimed is a process for the prodn. of OFP.

    23.
    发明专利
    未知

    公开(公告)号：DK0484755T3

    公开(公告)日：1995-12-18

    申请号：DK91118160

    申请日：1991-10-24

    Applicant: DEGUSSA

    Inventor： PANSTER PETER DR ,  GRADL ROBERT

    IPC: C08G77/26 ,  B01J31/00 ,  B01J31/16 ,  B01J31/18 ,  B01J31/24 ,  B01J31/28 ,  C07C45/50 ,  C08G77/22 ,  C08G77/28 ,  C08G77/30 ,  C08G77/38 ,  C08G77/54 ,  C08G77/58

    Abstract: The invention relates to shaped polymeric complexes of metals from sub-group 8 of the Periodic Table with ligands of an organosiloxane copolycondensate (random, block or mixed) which is optionally crosslinked by means of Si-, Ti-, Zr- and/or Al-containing crosslinking agents. This copolycondensate comprises units … … and … …… where R - R are … …… in which R is directly P- or N-bonded C1-C10-alkylene, C5-C8-cycloalkylene or … …. The ratio between the number of moles of units (II) and the number of moles of bonded metal atoms is from 1:1 to 1000:1, and the ratio between the units (I) and (II) is preferably from 5:95 to 95:5 mol%. … The polymeric complex compounds are in macroscopic form as spherical particles having a diameter of from 0.01 to 3.0 mm, a BET surface area of from >0 to 1000 m /g, a specific pore volume of from 0.01 to 6.5 ml/g and a bulk density of from 50 to 1000 g/l. … The invention also relates to a number of preparation processes for the substances according to the invention with specific aftertreatment steps, and the use of the polymeric metal complexes as catalysts in organic chemistry.

    24.
    发明专利
    未知

    公开(公告)号：ES2007314T3

    公开(公告)日：1994-09-01

    申请号：ES87117054

    申请日：1987-11-19

    Applicant: DEGUSSA

    Inventor： PANSTER PETER DR ,  GRADL ROBERT

    IPC: C08G77/26 ,  B01J23/46 ,  B01J31/00 ,  B01J31/12 ,  B01J31/16 ,  B01J31/18 ,  B01J31/20 ,  C07F7/14 ,  C08G77/28 ,  C08G77/38 ,  C08G77/54 ,  C08G77/58

    Abstract: New rhodium containing organopolysiloxane-ammonium compounds are described which consist of units of the formula (1) in which R1, R2 and R3 are R5-SiO3/2 (2), R5 is an alkylene group and the free valences of the oxygen atoms are saturated by silicon atoms of other groups (2), optionally with the insertion of cross-linking agents, R4 is hydrogen, an alkyl, cycloalkyl or benzyl group, xn- is a complex monovalent or polyvalent metal anion of rhodium and chloride, bromide or iodide. Methods for preparing these rhodium-containing organopolysiloxane-ammonium compounds as well as their use as catalysts in reactions with carbon monoxide are also disclosed.

    27.
    发明专利
    未知

    公开(公告)号：DE3226091A1

    公开(公告)日：1984-01-19

    申请号：DE3226091

    申请日：1982-07-13

    Applicant: DEGUSSA

    Inventor： PANSTER PETER DIPL CHEM DR ,  BUDER WOLFGANG DIPL CHEM DR ,  GRADL ROBERT ,  KLEINSCHMIT PETER DIPL CHEM DR

    IPC: C08G77/00 ,  B01J39/16 ,  B01J39/17 ,  B01J39/18 ,  C08G77/06 ,  C08G77/28 ,  C08G77/32 ,  C08G77/48 ,  C08G77/50 ,  C08G77/58

    Abstract: Polymeric mono-, di-, tri- and tetra-sulfides are described having an organopolysiloxane base structure of the units: R1-S1-4-R2 (1) wherein R1 and R2 may be the same or different and represent a group of the formula: R3-SiO3/2 (2) and which base structure may further optionally contain the heteroatoms titanium or aluminum, wherein R3 is an alkylene group and the free valencies of the oxygen atoms are saturated by silicon atoms of additional groups of formula (2), optionally with the insertion of cross-linking silicon-, titanium- or aluminum compounds, whereby the ratio of the silicon atoms in formula (2) to the silicon-, titanium- and aluminum atoms of any cross-linking agent may range from 1:0 to 1:10. In addition, processes for obtaining the sulfides and the use of these sulfides for the removal of certain ions from solutions are described.

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