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公开(公告)号:DE1567449B1
公开(公告)日:1970-11-12
申请号:DE1567449
申请日:1965-12-10
Applicant: DEGUSSA
Inventor: BIEGLER HANS DR , KALLRATH GOTTFRIED , KLEIN KURT
IPC: B01J2/04 , C01B33/113 , C01B33/32
Abstract: A granular composition is made by spraying a latex, for example Buna-Huls 220, into a granulating drum containing spray-dried water glass in the form of hollow spheres of bulk density 50-200 g./1. which have been rendered hydrophobic by treatment with a vaporous organic halogen silane, such as dimethyl chlorosilane. The latex is used in the amount of 10-50% by weight based on the dry weight of the hollow spheres.ALSO:Water-glass, spray-dried from aqueous solution, having the form of hollow spheres and a powder density of 50-200 g./l., is treated with vapours of organohalogen silanes and then heated for 30 minutes at 300 DEG C. The preferred organohalogen silane is dimethyl dichlorosilane, used in quantities of 2-20% by weight, based on the spray-dried waterglass. The vapours of mineral acids, preferably hydrogen chloride, can be used in addition to the organohalogen silanes in order to completely neutralize the alkali in the waterglass. The above-treated waterglass may be granulated by spraying with a latex emulsion in quantities of 10-50% based on the weight of spray-dried waterglass. The above materials are suitable for adsorbing water-immiscible organic materials, e.g. oil, from water.
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公开(公告)号:DE1519994A1
公开(公告)日:1969-06-19
申请号:DED0048613
申请日:1965-11-10
Applicant: DEGUSSA
Inventor: HANNS BIEGLER DR , KALLRATH GOTTFRIED , KLEIN KURT
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公开(公告)号:DE1229504B
公开(公告)日:1966-12-01
申请号:DED0040544
申请日:1962-12-19
Applicant: DEGUSSA
Inventor: KALLRATH GOTTFRIED
IPC: C01B33/145 , C01B33/146 , C01B33/149 , C01B33/152 , C01B33/18 , C09C1/30
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公开(公告)号:CA1018704A
公开(公告)日:1977-10-11
申请号:CA192988
申请日:1974-02-19
Applicant: DEGUSSA
Inventor: REINHARDT HELMUT , TREBINGER KARL , KALLRATH GOTTFRIED
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公开(公告)号:DE2513608A1
公开(公告)日:1976-10-07
申请号:DE2513608
申请日:1975-03-27
Applicant: DEGUSSA
Abstract: Finely divided hydrophobic silica or silicate is produced by treating the dry, moving particles with an organic silane at elevated temperature. The silica or silicate which had been prepared by wet precipitation or pyrogenically and which is in powdered form is heated to a temperature of about 200 DEG to 300 DEG C. with agitation and is brought to a fluidized condition and then is treated dropwise with an organosilane which is stable and boils below 300 DEG C.
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公开(公告)号:DE2365839A1
公开(公告)日:1976-07-29
申请号:DE2365839
申请日:1973-02-19
Applicant: DEGUSSA
IPC: C09C1/26
Abstract: Berlin blue is prepd by (a) reacting calcium ferrocyanide or sodium ferrocyanide at a pH value below 7 with a ferrous salt to give an acidic ferrous salt of hydrogerrocyanic acid (FeH2Fe CN 6), (b) opt. washing out the calcium or sodium ions from the precipitated salt, (c) converting the precipitate to Berlin white by treating with (in)org. potasiium salts, and (d) oxidising the Berlin white to Berlin blue.
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公开(公告)号:DE1567454A1
公开(公告)日:1970-08-06
申请号:DE1567454
申请日:1966-03-10
Applicant: DEGUSSA
Inventor: BIEGLER DR HANS , KALLRATH GOTTFRIED
IPC: C01B33/113 , C01B33/141 , C01B33/145
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公开(公告)号:DE1521210A1
公开(公告)日:1970-04-09
申请号:DE1521210
申请日:1965-11-12
Applicant: DEGUSSA
Inventor: KALLRATH GOTTFRIED , HANNS BIEGLER DR , HELMUT KNORRE DR , EUGEN MEYER-SIMON DR
Abstract: 1,164,459. Coating with metals. DEUTSCHE GOLD-UND SILBER-SCHEIDEANSTALT. Nov.11, 1966 [Nov.12, 1965], No.50754/66. Heading C7F. In the electroless plating of a non-conductor e.g. PVC, polyethylene,polypropylene, cellulose hydrate or rubber with e. g. Cu, Ni or Cr, from 10 to 50% by weight of a filler is worked into the non-conductor before plating, the filler, e. g. silicas with Si-H bonds, metal oxides or alkali- or alkaline earth metal silicates or aluminosilicates, is such as will combine with a plating catalyst e. g. Pd or Ag, either before or after mixing with the non-conductor. The non-conductor may be applied to a metal, e. g. Fe or Al, substrate and the electroless coating may be subsequently electroplated. In an example silica with 6% silanol is worked into polythene, the formed resin is dipped in sulphuric acid, rinsed, immersed in an ammoniacal solution or Pd C1 2 and then plated.
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