-
公开(公告)号:CZ293623B6
公开(公告)日:2004-06-16
申请号:CZ2000676
申请日:2000-02-24
Applicant: DEGUSSA
Inventor: HAGER HARALD DR , SCHMITZ GUIDO DR , BAUMANN FRANZ-ERICH DR , FRANZMANN GISELHER DR , OENBRINK GEORG DR
IPC: C08J5/12 , A61K31/44 , B32B27/32 , B32B27/34 , B32B27/36 , C04B35/46 , C07C275/24 , C08L67/02 , C08L77/00 , C08L77/06 , C09J167/02 , C09J177/00
Abstract: In the present invention, there is disclosed a thermoplastic multilayer composite containing: I. layer I of polyamide molding material: II. layer II of polyester molding material; a binding agent layer interposed between the layer I and layer II and containing at least 50 percent by weight of a mixture of the following components: a) 20 to 80 percent by weight of polyamide made of (a) diamine having 6 to 12 carbon atoms and (b) dicarboxylic acid in substantially stoichiometric amount thereto, whereby the dicarboxylic acid contains at least 5 percent by mole of a dicarboxylic acid having 10 to 36 carbon atoms and b) 80to 20 percent by weight of polyester made of aa) a mixture of 30 to 95 percent by mole of aromatic dicarboxylic acid having 6 to 20 carbon atoms and 70 to 5 percent by mole of the same dicarboxylic acid containing 10 to 36 carbon atoms as a binding agent present in polyamide, and bb) a diol having 2 to 12 carbon atoms.
-
公开(公告)号:CZ20014551A3
公开(公告)日:2002-08-14
申请号:CZ20014551
申请日:2001-12-17
Applicant: DEGUSSA
Inventor: SCHULER RALF DR , PEIRICK HEINZ , SCHMITZ GUIDO DR , OENBRINK GEORG DR , HAGER HARALD DR
IPC: B65D1/00 , B32B1/08 , B32B27/32 , B32B27/36 , C08J5/00 , C08L23/02 , C08L23/08 , C08L23/26 , C08L33/00 , C08L33/06 , C08L53/00 , C08L53/02 , C08L67/00 , C08L67/02 , C08L77/00 , C08L79/02 , F16L9/12
Abstract: The present invention relates to a molding composition containing thermoplastic polyesters, impact-modifying component which contains anhydride groups, a copolymer of alpha-olefin, acrylic compound, olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline and/or oxazinone, which has improved low-temperature impact strength; methods of making molding with the molding composition and molding containing the composition.
-
公开(公告)号:BRPI0517546B1
公开(公告)日:2015-11-17
申请号:BRPI0517546
申请日:2005-08-10
Applicant: EVONIK DEGUSSA GMBH
Inventor: SCHMITZ GUIDO DR , RIES HANS DR , HÄGER HARALD
Abstract: composto de camadas múltiplas com camada evoh e camada protetora. a presente invenção refere-se a um composto de camadas múltiplas contendo as seguintes etapas: uma camada interna (1) escolhida de uma massa de moldagem de fluorpolímero e uma massa de moldagem de poliolefina; (ii) um camada promotora de aderência (ii), com a seguinte composição: a) 0 até 80 partes em peso de um copolímero de enxerto de poliamina-poliamida, b) 0 até 100 partes em peso de poliamida, e) 0 até 85 partes em peso de um polímero escolhido de fluorpolímeros e poliolefinas, sendo que a soma das partes em peso de a), b) e c) perfaz 100 e sendo que adicionalmente na soma dos componentes a) e b) consistem pelo menos em 20 partes em peso de unidades monômeras, que derivam de caprolactama e/ou da combinação de hexametilenodiamina/ácido adípico, hexametilenodiamina/ácido subérico, hexametilenodiamina/ácido sebácico, hexametilenodiamino/d iácido dodecanóico, hexametilenod iamina/ isoftálico ou hexametilenodiamina/ácido tereftálico; d) no máximo 50 partes em peso de aditivos, escolhido de borracha amortecedora de impacto e/ou adjuvantes ou substâncias aditivas usuais; iii, uma camada (iii) a partir de massa de moldagem evoh; apresentando uma aperfeiçoada aderência de camadas.
-
公开(公告)号:CY1106891T1
公开(公告)日:2012-09-26
申请号:CY071101239
申请日:2007-09-26
Applicant: DEGUSSA
Inventor: SCHMITZ GUIDO DR , HAEGER HARALD DR , RIES HANS DR
Abstract: Πολυστοιβαδικήένωση, πουπεριέχειτιςπαρακάτωστοιβάδες:
-
公开(公告)号:DE50113219D1
公开(公告)日:2007-12-20
申请号:DE50113219
申请日:2001-05-02
Applicant: EVONIK DEGUSSA GMBH
Inventor: HAEGER HARALD DR , SCHMITZ GUIDO DR , BAUMANN FRANZ-ERICH DR , BARTZ WILFRIED DR , OENBRINK GEORG DR
IPC: B60S5/02 , C08L77/00 , B60K15/01 , B60K15/03 , C08J5/00 , C08L23/08 , C08L53/02 , C08L77/02 , C08L77/06 , F16K27/00
Abstract: Polyamide molding composition containing an impact modifier and a functionalized olefin-acrylic polymer comprises a polyamide having an excess of terminal amino groups over terminal carboxy groups. Molding composition comprises: (A) 60-96.5 wt.% of a polyamide having an excess of terminal amino groups over terminal carboxy groups; (B) 3-39.5 wt.% of an anhydride-functional impact modifier selected from ethylene/ alpha -olefin copolymers and styrene-ethylenebutylene-styrene block copolymers; and (C) 0.5-20 wt.% of a copolymer comprising: (a) 20-94.5 wt.% 2-12C alpha -olefin units; (b) 5-79.5 wt.% (meth)acrylic acid, (meth)acrylate salt, 1-12C alcohol (meth)acrylate, (meth)acrylonitrile and/or (meth)acrylamide units; and (c) 0.5-50 wt.% olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline or oxazinone units.
-
公开(公告)号:BRPI0517546A
公开(公告)日:2008-10-14
申请号:BRPI0517546
申请日:2005-08-10
Applicant: DEGUSSA
Inventor: SCHMITZ GUIDO DR , HOGER HARALD , RIES HANS DR
Abstract: A multilayer composite which comprises the following layers: I. an interior layer I selected from among a fluoropolymer molding composition and a polyolefin molding composition; II. a bonding agent layer II which has the following composition: a) from 0 to 80 parts by weight of a polyamine-polyamide graft copolymer, b) from 0 to 85 parts by weight of polyamide, c) from 0 to 85 parts by weight of a polymer selected from among fluoropolymers and polyolefins; with the sum of the parts by weight of a), b) and c) being 100; and, in addition, the sum of the components a) and b) comprising at least 20 parts by weight of monomer units derived from caprolactam and/or the combination hexamethylenediamine/adipic acid, hexamethylenediamine/suberic acid, hexamethylenediamine/sebacic acid, hexamethylenediamine/dodecanedioic acid, hexamethylenediamine/isophthalic acid or hexamethylenediamine/terephthalic acid and d) not more than 50 parts by weight of additives selected from among impact-modifying rubber and customary auxiliaries and additives; III. a layer III comprising an EVOH molding composition, has improved adhesion of the layers.
-
公开(公告)号:AT272497T
公开(公告)日:2004-08-15
申请号:AT00109633
申请日:2000-05-05
Applicant: DEGUSSA
Inventor: HAEGER HARALD DR , BOEER MICHAEL , SCHMITZ GUIDO DR , OENBRINK GEORG DR , RICHTER RALF DR
IPC: F16L11/04 , B32B27/00 , B32B27/34 , B32B27/36 , C08G69/02 , C08G69/48 , C08K3/00 , C08K5/00 , C08L21/00 , C08L67/00 , C08L77/00 , C08L77/02 , C08L77/06 , F16L11/11 , B32B7/02 , C08G73/02 , F16L11/127
Abstract: The composite includes a coupling layer comprising a graft copolymer from: (a) a polyamine with at least 4 nitrogen atoms and a number-average molecular weight (Mn) of at least 146; and (b) polyamide-forming monomers (lactams, omega -amino-acids and/or equimol. combinations of diamines and dicarboxylic acids). A thermoplastic multilayer composite comprises layers (I) and (II) of different thermoplastic moulding materials and an interlayer (III) of a coupling agent. At least 5 wt% of (III) consists of a graft copolymer derived from: (a) 0.5-25 wt% (based on the copolymer) of a polyamine with at least 4 nitrogen atoms and a Mn of at least 146; and (b) polyamide-forming monomers selected from lactams, omega -aminocarboxylic acids or equimolar combinations of diamines and dicarboxylic acids. An Independent claim is also included for moulding materials containing: (A) 5-60 parts by weight (pts. wt.) of a graft copolymer as above; (B) 10-85 pts. wt. of a polyamide; (C) 10-85 pts. wt. of a polyester; and (D) not more than 40 wt% (based on A + B + C) of an impact-modifying rubber and/or conventional auxiliary substances or additives.
-
公开(公告)号:AT243116T
公开(公告)日:2003-07-15
申请号:AT01125585
申请日:2001-10-26
Applicant: DEGUSSA
Inventor: HAEGER HARALD DR , SCHMITZ GUIDO DR
Abstract: A multilayer composite comprising the following layers bound directly to one another:I. a layer I of a polyamide molding composition;II. a layer II of a bonding agent comprising at least 50% by weight of a mixture ofa) from 30 to 70 parts by volume of polyamide andb) from 70 to 30 parts by volume of polyolefin, where the sum of the parts by volume is 100 and in addition at least some of the polyamide is present either in the form of a polyamide-polyolefin graft copolymer or as a highly branched polyamine-polyamide copolymer;III. if desired a layer III of a polyolefin molding composition,displays good adhesion between layers which remains largely intact even on prolonged contact with alcohol-containing or aqueous media at elevated temperature.
-
公开(公告)号:CZ20002436A3
公开(公告)日:2001-02-14
申请号:CZ20002436
申请日:2000-06-28
Applicant: DEGUSSA
Inventor: SCHMITZ GUIDO DR , OENBRINK GEORG DR , BOEER MICHAEL , HAGER HARALD DR , RICHTER RALF DR
IPC: B32B27/34
-
公开(公告)号:CZ2000676A3
公开(公告)日:2001-01-17
申请号:CZ2000676
申请日:2000-02-24
Applicant: DEGUSSA
Inventor: HAGER HARALD DR , SCHMITZ GUIDO DR , BAUMANN FRANZ-ERICH DR , FRANZMANN GISELHER DR , OENBRINK GEORG DR
IPC: C08J5/12 , A61K31/44 , B32B27/32 , B32B27/34 , B32B27/36 , C04B35/46 , C07C275/24 , C08L67/02 , C08L77/00 , C08L77/06 , C09J167/02 , C09J177/00
Abstract: The thermoplastic composite material comprises a polyamide layer bonded to a polyester layer by means of an adhesive (I) comprising a blend of polyamide prepared from stoichiometric amounts of a diamine containing 6-12C atoms and dicarboxylic acids, and a polyester prepared from a diol containing a mixture of dicarboxylic acids. Thermoplastic composite material comprises a polyamide layer bonded to a polyester layer by means of an adhesive (I) comprising at least 50 wt.% of a blend of: (a) 20-80 wt.% of a polyamide prepared from stoichiometric amounts of a diamine containing 6-12C atoms and dicarboxylic acids, including at least 5 mol% of dicarboxylic acids (II) containing 10-36 C atoms; and (b) 20-80 wt.% of a polyester prepared from a diol containing 2-12 C atoms and a mixture of 30-95 mol% of an aromatic dicarboxylic acid containing 6-20 C atoms and 5-70 mol% (II). Independent claims are also included for the following: (1) production of the composite material by multicomponent injection molding, coextrusion or coextrusion/blow molding; (2) an adhesive as defined for (I).
-
-
-
-
-
-
-
-
-