CATALYST SYSTEM FOR MULTI-BLOCK COPOLYMER FORMATION

    公开(公告)号:SG11201908307XA

    公开(公告)日:2019-10-30

    申请号:SG11201908307X

    申请日:2018-03-15

    Abstract: FIG23 chain growth 10 A chain growth 20 chain growth 13 14 chain shuttling ,-24 23 chain chain . growth shuttling 12 13 13 ,-28 (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 20 September 2018 (20.09.2018) WIP0 I Iiiimmomiolollmonolomolomoiloimmomovom (10) International Publication Number WO 2018/170208 Al PCT (51) International Patent Classification: C08F 4/64 (2006.01) C08F 210/16 (2006.01) (21) International Application Number: PCT/US2018/022554 (22) International Filing Date: 15 March 2018 (15.03.2018) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 62/471,518 15 March 2017 (15.03.2017) US (71) Applicant: DOW GLOBAL TECHNOLOGIES LLC [US/US]; 2040 Dow Center, Midland, MI 48674 (US). (72) Inventors: DEVORE, David D.; 1776 Building, Midland, MI 48674 (US). ARRIOLA, Daniel J.; 1776 Building, Midland, MI 48674 (US). KRASOVSIUY, Arkady L.; 230 Abner Jackson Parkway, Lake Jackson, TX 77566 (US). CARNAHAN, Edmund M.; 230 Abner Jackson Parkway, Lake Jackson, TX 77566 (US). THERIAULT, Curt N.; 901 Loveridge Road, Pittsburgh, PA 94565 (US). ROOF, Gordon R.; 1710 Building, Midland, MI 48674 (US). WENZEL, Timothy T.; 6909 North Jefferson Road, Midland, MI 48642 (US). KLOSIN, Jerzy; 1776 Building, Midland, MI 48674 (US). FIGUEROA, Ruth; 1776 Build- ing, Midland, MI 48674 (US). (74) Agent: HUANG, Cheney; The Dow Chemical Company, Intellectual Property, P. 0. Box 1967, Midland, Michigan 48641-1967 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, = (54) Title: CATALYST SYSTEM FOR MULTI-BLOCK COPOLYMER FORMATION cc O N 00 O C (57) : The present disclosure relates to a catalyst system for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first olefin polymerization procatalyst, (B) a second olefm polymerization procatalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by procatalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent. [Continued on next page] WO 2018/170208 Al MIDEDIMOMMIDIREEM301011101010MODEVOIS UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: — with international search report (Art. 21(3))

    CATALYST SYSTEM FOR MULTI-BLOCK COPOLYMER FORMATION

    公开(公告)号:SG11201908518VA

    公开(公告)日:2019-10-30

    申请号:SG11201908518V

    申请日:2018-03-14

    Abstract: 13 2 chain 13 growth 23 chain growth in growth chain growth chain shuttling 1-1 kr) O O N 1-1 00 1-1 O O (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 20 September 2018 (20.09.2018) WIP0 I PCT o °nolo olo mons iflo oimIE (10) International Publication Number WO 2018/170056 Al (51) International Patent Classification: C08F 210/16 (2006.01) C08F 4/64 (2006.01) (21) International Application Number: PCT/US2018/022331 (22) International Filing Date: 14 March 2018 (14.03.2018) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 62/471,565 15 March 2017 (15.03.2017) US (71) Applicant: DOW GLOBAL TECHNOLOGIES LLC [US/US]; 2040 Dow Center, Midland, MI 48674 (US). (72) Inventors: DEVORE, David D.; 1776 Building, Midland, MI 48674 (US). ARRIOLA, Daniel J.; 1776 Building, Midland, MI 48674 (US). ROOF, Gordon R.; 1710 Build- ing, Midland, MI 48674 (US). MUNRO, Jeffrey C.; 230 Abner Jackson Parkway, Lake Jackson, TX 77566 (US). YOUNG, Andrew J.; 230 Abner Jackson Parkway, Lake Jackson, TX 77566 (US). CARNAHAN, Edmund M.; 230 Abner Jackson Parkway, Lake Jackson, TX 77566 (US). (74) Agent: HUANG, Cheney; The Dow Chemical Company, Intellectual Property, P. 0. Box 1967, Midland, Michigan 48641-1967 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: with international search report (Art. 21(3)) (54) Title: CATALYST SYSTEM FOR MULTI-BLOCK COPOLYMER FORMATION (57) : The present disclosure relates to a catalyst system for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first olefin polymerization procatalyst, (B) a second olefm polymerization procatalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by procatalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

    HYPERBRANCHED ETHYLENE-BASED OLIGOMERS

    公开(公告)号:CA2915067C

    公开(公告)日:2021-08-03

    申请号:CA2915067

    申请日:2014-06-24

    Abstract: A process to prepare a relatively inexpensive utility fluid comprises contacting together ethylene and a coordination-insertion catalyst and, optionally, an alpha-olefin, in a continuously-fed backmixed reactor zone under conditions such that a mixture of a hyperbranched oligomer and a branched oligomer is formed. The hyperbranched oligomer has an average of at least 1.5 methine carbons per oligomer molecule, and at least 40 methine carbons per one-thousand total carbons, and at least 40 percent of the methine carbons is derived from the ethylene, and the average number of carbons per molecule is from 25 to 100, and at least 25 percent of the hyperbranched oligomer molecules has a vinyl group and can be separated from the branched oligomer, which has an average number of carbons per molecule of up to 20. The coordination-insertion catalyst is characterized as having an ethylene/octene reactivity ratio up to 20 and a kinetic chain length up to 20 monomer units.

    PROCESS OF POLYMERIZING TETRA-FUNCTIONAL LONG-CHAIN BRANCHED POLYOLEFIN RESINS

    公开(公告)号:SG11202102949TA

    公开(公告)日:2021-04-29

    申请号:SG11202102949T

    申请日:2019-09-27

    Abstract: The present process embodiments for synthesizing long-chain branched copolymers include contacting together one or more C2-C14 alkene monomers, at least one diene or polyene, optionally a solvent, and a multi-chain catalyst. The multi-chain catalyst includes a plurality of polymerization sites and produces at least two polymer chains of the C2-C14 alkene monomers, each polymer chain polymerizing at one of the polymerization sites. The process synthesizes the long-chain branched polymers by connecting the two polymer chains with the diene or polyene, the joining of the two polymer chains being performed in a concerted manner during the polymerization.

Patent Agency Ranking