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公开(公告)号:SG11201908307XA
公开(公告)日:2019-10-30
申请号:SG11201908307X
申请日:2018-03-15
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: DEVORE DAVID D , ARRIOLA DANIEL J , KRASOVSKIY ARKADY L , CARNAHAN EDMUND M , THERIAULT CURT N , ROOF GORDON R , WENZEL TIMOTHY T , KLOSIN JERZY , FIGUEROA RUTH
IPC: C08F4/64 , C08F210/16
Abstract: FIG23 chain growth 10 A chain growth 20 chain growth 13 14 chain shuttling ,-24 23 chain chain . growth shuttling 12 13 13 ,-28 (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 20 September 2018 (20.09.2018) WIP0 I Iiiimmomiolollmonolomolomoiloimmomovom (10) International Publication Number WO 2018/170208 Al PCT (51) International Patent Classification: C08F 4/64 (2006.01) C08F 210/16 (2006.01) (21) International Application Number: PCT/US2018/022554 (22) International Filing Date: 15 March 2018 (15.03.2018) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 62/471,518 15 March 2017 (15.03.2017) US (71) Applicant: DOW GLOBAL TECHNOLOGIES LLC [US/US]; 2040 Dow Center, Midland, MI 48674 (US). (72) Inventors: DEVORE, David D.; 1776 Building, Midland, MI 48674 (US). ARRIOLA, Daniel J.; 1776 Building, Midland, MI 48674 (US). KRASOVSIUY, Arkady L.; 230 Abner Jackson Parkway, Lake Jackson, TX 77566 (US). CARNAHAN, Edmund M.; 230 Abner Jackson Parkway, Lake Jackson, TX 77566 (US). THERIAULT, Curt N.; 901 Loveridge Road, Pittsburgh, PA 94565 (US). ROOF, Gordon R.; 1710 Building, Midland, MI 48674 (US). WENZEL, Timothy T.; 6909 North Jefferson Road, Midland, MI 48642 (US). KLOSIN, Jerzy; 1776 Building, Midland, MI 48674 (US). FIGUEROA, Ruth; 1776 Build- ing, Midland, MI 48674 (US). (74) Agent: HUANG, Cheney; The Dow Chemical Company, Intellectual Property, P. 0. Box 1967, Midland, Michigan 48641-1967 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, = (54) Title: CATALYST SYSTEM FOR MULTI-BLOCK COPOLYMER FORMATION cc O N 00 O C (57) : The present disclosure relates to a catalyst system for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first olefin polymerization procatalyst, (B) a second olefm polymerization procatalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by procatalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent. [Continued on next page] WO 2018/170208 Al MIDEDIMOMMIDIREEM301011101010MODEVOIS UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: — with international search report (Art. 21(3))
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22.
公开(公告)号:CA3075083A1
公开(公告)日:2019-03-28
申请号:CA3075083
申请日:2018-09-12
Inventor: HERRON JEFFREY , ARRIOLA DANIEL J , BLAYLOCK D WAYNE , LEE WEN-SHENG , SUSSMAN VICTOR J , HICKMAN DANIEL A , LIMBACH KIRK W
Abstract: A method for preparing methyl methacrylate from methacrolein and methanol. The method comprises contacting a mixture comprising methacrolein, methanol and oxygen with a heterogeneous catalyst comprising a support and a noble metal, wherein oxygen concentration at a reactor outlet is from 1 to 7.5 mol% and wherein pH at a reactor outlet is no greater than 7.5.
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公开(公告)号:ES2946762T3
公开(公告)日:2023-07-25
申请号:ES18716046
申请日:2018-03-15
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: PATTON JASSON T , SENECAL TODD D , ARRIOLA DANIEL J , CHRISTIANSON MATTHEW D , ROOF GORDON R , KLOSIN JERZY , DEVORE DAVID D , DAVIS ANNA V
IPC: C08F210/16 , C08F4/52 , C08F4/64
Abstract: La presente descripción se refiere a un sistema catalizador de polimerización de olefinas para su uso en la formación de un copolímero multibloque, dicho copolímero que contiene dos o más segmentos o bloques que difieren en propiedades químicas o físicas, un proceso de polimerización que lo utiliza y los polímeros resultantes, en el que la composición comprende la mezcla o el producto de reacción que resulta de combinar: (A) un primer procatalizador de polimerización de olefinas, (B) un segundo procatalizador de polimerización de olefinas capaz de preparar polímeros que difieren en propiedades químicas o físicas del polímero preparado por procatalizador (A) en condiciones de polimerización equivalentes, y (C) un agente de transporte de cadena. (Traducción automática con Google Translate, sin valor legal)
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公开(公告)号:SG11202102966RA
公开(公告)日:2021-04-29
申请号:SG11202102966R
申请日:2019-09-27
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: ARRIOLA DANIEL J , FROESE ROBERT D J , KASHYAP TERESITA
IPC: C08F210/16
Abstract: Ethylene-based polymers of this disclosure include an average g′ less than 0.86, where the average g′ is an intrinsic viscosity ratio determined by gel permeation chromatography using a triple detector; and a molecular weight tail quantified by an MWD area metric, ATAIL, and ATAIL is less than or equal to 0.04 as determined by gel permeation chromatography using a triple detector.
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公开(公告)号:SG11201908518VA
公开(公告)日:2019-10-30
申请号:SG11201908518V
申请日:2018-03-14
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: DEVORE DAVID D , ARRIOLA DANIEL J , ROOF GORDON R , MUNRO JEFFREY C , YOUNG ANDREW J , CARNAHAN EDMUND M
IPC: C08F210/16 , C08F4/64
Abstract: 13 2 chain 13 growth 23 chain growth in growth chain growth chain shuttling 1-1 kr) O O N 1-1 00 1-1 O O (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 20 September 2018 (20.09.2018) WIP0 I PCT o °nolo olo mons iflo oimIE (10) International Publication Number WO 2018/170056 Al (51) International Patent Classification: C08F 210/16 (2006.01) C08F 4/64 (2006.01) (21) International Application Number: PCT/US2018/022331 (22) International Filing Date: 14 March 2018 (14.03.2018) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 62/471,565 15 March 2017 (15.03.2017) US (71) Applicant: DOW GLOBAL TECHNOLOGIES LLC [US/US]; 2040 Dow Center, Midland, MI 48674 (US). (72) Inventors: DEVORE, David D.; 1776 Building, Midland, MI 48674 (US). ARRIOLA, Daniel J.; 1776 Building, Midland, MI 48674 (US). ROOF, Gordon R.; 1710 Build- ing, Midland, MI 48674 (US). MUNRO, Jeffrey C.; 230 Abner Jackson Parkway, Lake Jackson, TX 77566 (US). YOUNG, Andrew J.; 230 Abner Jackson Parkway, Lake Jackson, TX 77566 (US). CARNAHAN, Edmund M.; 230 Abner Jackson Parkway, Lake Jackson, TX 77566 (US). (74) Agent: HUANG, Cheney; The Dow Chemical Company, Intellectual Property, P. 0. Box 1967, Midland, Michigan 48641-1967 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: with international search report (Art. 21(3)) (54) Title: CATALYST SYSTEM FOR MULTI-BLOCK COPOLYMER FORMATION (57) : The present disclosure relates to a catalyst system for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first olefin polymerization procatalyst, (B) a second olefm polymerization procatalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by procatalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.
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公开(公告)号:CA3071185A1
公开(公告)日:2019-01-31
申请号:CA3071185
申请日:2018-06-25
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: SUSSMAN VICTOR J , LEE WEN-SHENG , HERRON JEFFREY , BLAYLOCK D WAYNE , ARRIOLA DANIEL J , HEITSCH ANDREW , KIRILIN ALEXEY , CLEMENTS HEIDI , SCHMUCKER ABRIN L , HICKMAN DANIEL A
Abstract: A method for preparing a heterogeneous catalyst. The method comprises steps of: (a) combining (i) a support, (ii) an aqueous solution of a noble metal compound and (iii) a C2-C18 thiol comprising at least one hydroxyl or carboxylic acid substituent; to form a wet particle and (b) removing water from the wet particle by drying followed by calcination to produce the catalyst.
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公开(公告)号:ES2391209T3
公开(公告)日:2012-11-22
申请号:ES07837242
申请日:2007-08-23
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: ARRIOLA DANIEL J , JAZDZEWSKI BRIAN A , TIMMERS FRANCIS J , VOSEJPKA PAUL C , WAGNER NICOLE L , LANDES BRIAN G , JUEPTNER GUENTER , BANK DAVID H , WENZEL TIMOTHY T
IPC: C08G61/04 , C08F299/00
Abstract: Un procedimiento para preparar una mezcla de productos de metátesis cruzada, que comprende poner encontacto un catalizador de metátesis bajo condiciones de metátesis con una composición que comprende dos o máspolímeros etilénicamente insaturados distinguibles químicamente, comprendiendo el primero de dichos polímerosetilénicamente insaturados insaturación interna y teniendo un peso molecular mayor que 1.000 y teniendo de 0,001 a50 por ciento en moles de insaturación y teniendo el segundo de dichos polímeros etilénicamente insaturados de0,001 por ciento en moles a menos de 10 por ciento en moles de contenido etilénico y que comprende insaturacióninterna y segmentos duros y que tiene un peso molecular mayor de 1.000 y un valor esperado de Tg o medido deTm mayor que 100ºC, para formar de este modo el producto de reacción de metátesis cruzada, donde el producto dereacción de metátesis cruzada comprende una distribución aleatoria de bloques poliméricos y longitudes de bloquesy posee segmentos duros.
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公开(公告)号:CA2915067C
公开(公告)日:2021-08-03
申请号:CA2915067
申请日:2014-06-24
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: ARRIOLA DANIEL J , BAILEY BRAD C , KLOSIN JERZY , LYSENKO ZENON , ROOF GORDON R , SMITH AUSTIN J
Abstract: A process to prepare a relatively inexpensive utility fluid comprises contacting together ethylene and a coordination-insertion catalyst and, optionally, an alpha-olefin, in a continuously-fed backmixed reactor zone under conditions such that a mixture of a hyperbranched oligomer and a branched oligomer is formed. The hyperbranched oligomer has an average of at least 1.5 methine carbons per oligomer molecule, and at least 40 methine carbons per one-thousand total carbons, and at least 40 percent of the methine carbons is derived from the ethylene, and the average number of carbons per molecule is from 25 to 100, and at least 25 percent of the hyperbranched oligomer molecules has a vinyl group and can be separated from the branched oligomer, which has an average number of carbons per molecule of up to 20. The coordination-insertion catalyst is characterized as having an ethylene/octene reactivity ratio up to 20 and a kinetic chain length up to 20 monomer units.
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公开(公告)号:SG11202102949TA
公开(公告)日:2021-04-29
申请号:SG11202102949T
申请日:2019-09-27
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: FROESE ROBERT D J , ARRIOLA DANIEL J , STUBBERT BRYAN D
IPC: C08F210/18
Abstract: The present process embodiments for synthesizing long-chain branched copolymers include contacting together one or more C2-C14 alkene monomers, at least one diene or polyene, optionally a solvent, and a multi-chain catalyst. The multi-chain catalyst includes a plurality of polymerization sites and produces at least two polymer chains of the C2-C14 alkene monomers, each polymer chain polymerizing at one of the polymerization sites. The process synthesizes the long-chain branched polymers by connecting the two polymer chains with the diene or polyene, the joining of the two polymer chains being performed in a concerted manner during the polymerization.
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30.
公开(公告)号:SG11202002227SA
公开(公告)日:2020-04-29
申请号:SG11202002227S
申请日:2018-09-12
Applicant: DOW GLOBAL TECHNOLOGIES LLC , ROHM & HAAS
Inventor: HERRON JEFFREY , ARRIOLA DANIEL J , BLAYLOCK D WAYNE , LEE WEN-SHENG , SUSSMAN VICTOR J , HICKMAN DANIEL A , LIMBACH KIRK W
Abstract: A method for preparing methyl methacrylate from methacrolein and methanol. The method comprises contacting a mixture comprising methacrolein, methanol and oxygen with a heterogeneous catalyst comprising a support and a noble metal, wherein oxygen concentration at a reactor outlet is from 1 to 7.5 mol % and wherein pH at a reactor outlet is no greater than 7.5.
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