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公开(公告)号:SG11202102949TA
公开(公告)日:2021-04-29
申请号:SG11202102949T
申请日:2019-09-27
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: FROESE ROBERT D J , ARRIOLA DANIEL J , STUBBERT BRYAN D
IPC: C08F210/18
Abstract: The present process embodiments for synthesizing long-chain branched copolymers include contacting together one or more C2-C14 alkene monomers, at least one diene or polyene, optionally a solvent, and a multi-chain catalyst. The multi-chain catalyst includes a plurality of polymerization sites and produces at least two polymer chains of the C2-C14 alkene monomers, each polymer chain polymerizing at one of the polymerization sites. The process synthesizes the long-chain branched polymers by connecting the two polymer chains with the diene or polyene, the joining of the two polymer chains being performed in a concerted manner during the polymerization.
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公开(公告)号:ES2911503T3
公开(公告)日:2022-05-19
申请号:ES18789525
申请日:2018-09-20
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: STUBBERT BRYAN D , KRASOVSKIY ARKADY L , VAIDYA TULAZA , KLOSIN JERZY , CARNAHAN EDMUND M , FONTAINE PHILIP P , ROSEN MARI S , WILSON DAVID R
IPC: C08F210/16 , C08F4/64 , C08F4/659
Abstract: Un sistema catalítico que comprende un complejo metal-ligando según la fórmula (I): **(Ver fórmula)** donde: M es un metal elegido entre titanio, zirconio o hafnio, estando el metal en un estado de oxidación formal de +2, +3 o +4; X se selecciona del grupo que consiste en -(CH2)SiRX3, donde cada RX es independientemente un hidrocarbilo(C1- C30) o un heterohidrocarbilo(C1-C30) y al menos uno de RX es un (C2-C30)hidrocarbilo, donde dos RX cualesquiera o los tres RX están opcionalmente enlazados covalentemente; cada Z se elige independientemente de -O-, -S-, -N(RN)-, o -P(RP)-; cada uno de R1 y R16 se selecciona independientemente del grupo que consiste en -H, hidrocarbilo(C1-C40), heterohidrocarbilo(C1-C40), -Si(RC)3, -Ge(RC)3, -P(RP)2, -N(RN)2, -ORC, -SRC, -NO2, -CN, -CF3, RCS(O)-, RCS(O)2-, (RC)2C=N-, RCC(O)O-, RCOC(O)-, RCC(O)N(R)-, (RC)2NC(O)-, halógeno, radicales de fórmula (II), radicales de fórmula (III) y radicales de fórmula (IV): **(Ver fórmula)** donde cada uno de R31-35, R41-48 y R51-59 se elige independientemente de -H, hidrocarbilo(C1-C40), heterohidrocarbilo(C1-C40), -Si(RC)3, -Ge(RC)3, -P(RP)2, -N(RN)2, -ORC, -SRC, -NO2, -CN, -CF3, RCS(O)-, RCS(O)2-, (RC)2C=N-, RCC(O)O-, RCOC(O)-, RCC(O)N(RN)-, (RC)2NC(O)-, o halógeno, siempre que al menos uno de R1 o R16 sea un radical de fórmula (II), un radical de fórmula (III) o un radical de fórmula (IV); cada uno de R2-4, R5-8, R9-12 y R13-15 se selecciona independientemente de -H, hidrocarbilo(C1-C40), heterohidrocarbilo(C1-C40), -Si(RC)3, -Ge(RC)3, -P(RP)2, -N(RN)2, -ORC, -SRC, -NO2, -CN, -CF3, RCS(O)-, RCS(O)2-, (RC)2C=N-, RCC(O)O-, RCOC(O)-, RCC(O)N(R)-, (RC)2NC(O)-, y halógeno; L es (C2-C40)hidrocarbileno o (C2-C40)heterohidrocarbileno; y cada RC, RP y RN en la fórmula (I) es independientemente un (C1-C30)hidrocarbilo, (C1-C30)heterohidrocarbilo, o -H.
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公开(公告)号:SG11202002719VA
公开(公告)日:2020-04-29
申请号:SG11202002719V
申请日:2018-09-20
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: STUBBERT BRYAN D , KRASOVSKIY ARKADY L , VAIDYA TULAZA , KLOSIN JERZY , CARNAHAN EDMUND M , FONTAINE PHILIP P , ROSEN MARI S , WILSON DAVID R
IPC: C08F210/16 , C08F4/64
Abstract: Embodiments are directed to a catalyst system comprising metal-ligand complexes and processes for polyolefin polymerization using the metal-ligand complex having the following structure, Formula (I), where X is selected from the group consisting of —(CH2)SiRX3.
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公开(公告)号:SG11202109433WA
公开(公告)日:2021-10-28
申请号:SG11202109433W
申请日:2020-03-27
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: FROESE ROBERT DJ , STUBBERT BRYAN D , ARRIOLA DANIEL J , BROONER RACHEL E M , REDWINE OSCAR D
IPC: C08F210/18 , C08F4/64
Abstract: Processes of synthesizing long-chain branched polymers. The processes include contacting together one or more C2-C14 alkene monomers, at least one diene, optionally a solvent, and a multi-chain catalyst optionally in the presence of hydrogen, wherein the multi-chain catalyst comprises a plurality of polymerization sites; producing at least two polymer chains of the C2-C14 alkene monomers, each polymer chain polymerizing at one of the polymerization sites; synthesizing the long-chain branched polymers by connecting the two polymer chains with the diene, the joining of the two polymer chains being performed in a concerted manner during the polymerization; and producing tri-functional long chain branches from the diene, wherein the tri-functional long chain branches occur at a frequency of at least 0.03 per 1000 carbon atoms. The diene has a structure according to formula (I):
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公开(公告)号:SG11202109432QA
公开(公告)日:2021-10-28
申请号:SG11202109432Q
申请日:2020-03-27
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: FROESE ROBERT DJ , BROONER RACHEL E M , ARRIOLA DANIEL J , STUBBERT BRYAN D , REDWINE OSCAR D
IPC: C08F210/18 , C08F4/64
Abstract: Processes of synthesizing long-chain branched polymers. The processes include contacting together one or more C2-C14 alkene monomers, at least one diene, optionally a solvent, and a multi-chain catalyst optionally in the presence of hydrogen, wherein the multi-chain catalyst comprises a plurality of polymerization sites; producing at least two polymer chains of the C2-C14 alkene monomers, each polymer chain polymerizing at one of the polymerization sites; synthesizing the long-chain branched polymers by connecting the two polymer chains with the diene, the joining of the two polymer chains being performed in a concerted manner during the polymerization; and producing tri-functional long chain branches and tetra-functional long chain branches from the diene, wherein the long-chain branched polymers have a ratio of tri-functional to tetra-functional long chain branches from 0.05:1 to 100:0; and adjusting the ratio of tri-functional and tetra-functional long chain branches. The diene has a structure according to formula (I):
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公开(公告)号:SG11202102950WA
公开(公告)日:2021-04-29
申请号:SG11202102950W
申请日:2019-09-27
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: FROESE ROBERT D J , ARRIOLA DANIEL J , KASHYAP TERESITA , STUBBERT BRYAN D
IPC: C08F210/16
Abstract: Ethylene-based polymers comprise reaction products of polymerizing ethylene monomer, at least one diene or polyene comonomer, and optionally at least one C3 to C14 comonomer under defined polymerization reaction conditions, the ethylene-based polymer having: an Mw/Mw0 greater than 1.20. The Mw0 is the initial weight-average molecular weight of a comparative ethylene-based polymer by gel permeation chromatography. The comparative ethylene-based polymer being a reaction product of polymerizing ethylene monomer and all C3 to C14 comonomers present in the ethylene-based polymer, if any, without the at least one polyene comonomer, under the defined polymerization reaction conditions; and a molecular weight tail quantified by an MWD area metric, ATAIL, and ATAIL is less than or equal to 0.04 as determined by gel permeation chromatography using a triple detector.
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公开(公告)号:SG11202100288UA
公开(公告)日:2021-03-30
申请号:SG11202100288U
申请日:2019-07-29
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: STUBBERT BRYAN D
IPC: C08F210/16 , C08F4/64 , C08F4/659
Abstract: Embodiments are directed to catalyst systems comprising at least one metal ligand complex and to processes for polyolefin polymerization incorporating the catalyst systems. The metal ligand complexes have the following structures: (I)
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公开(公告)号:SG11202002720WA
公开(公告)日:2020-04-29
申请号:SG11202002720W
申请日:2018-09-19
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: KRASOVSKIY ARKADY L , WILSON DAVID R , STUBBERT BRYAN D , VAIDYA TULAZA , KLOSIN JERZY , CARNAHAN EDMUND M , FONTAINE PHILIP P , ROSEN MARI S
IPC: C08F4/659 , C08F4/64 , C08F210/16
Abstract: Embodiments are directed to a catalyst system comprising metal ligand complexes and processes for polyolefin polymerization using the metal ligand complex having the following structure: where each X is selected from the group consisting of —(CH2)SiRX3.
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