公开(公告)号：SG11202102950WA

公开(公告)日：2021-04-29

申请号：SG11202102950W

申请日：2019-09-27

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： FROESE ROBERT D J ,  ARRIOLA DANIEL J ,  KASHYAP TERESITA ,  STUBBERT BRYAN D

IPC: C08F210/16

Abstract: Ethylene-based polymers comprise reaction products of polymerizing ethylene monomer, at least one diene or polyene comonomer, and optionally at least one C3 to C14 comonomer under defined polymerization reaction conditions, the ethylene-based polymer having: an Mw/Mw0 greater than 1.20. The Mw0 is the initial weight-average molecular weight of a comparative ethylene-based polymer by gel permeation chromatography. The comparative ethylene-based polymer being a reaction product of polymerizing ethylene monomer and all C3 to C14 comonomers present in the ethylene-based polymer, if any, without the at least one polyene comonomer, under the defined polymerization reaction conditions; and a molecular weight tail quantified by an MWD area metric, ATAIL, and ATAIL is less than or equal to 0.04 as determined by gel permeation chromatography using a triple detector.

公开(公告)号：SG11202102966RA

公开(公告)日：2021-04-29

申请号：SG11202102966R

申请日：2019-09-27

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： ARRIOLA DANIEL J ,  FROESE ROBERT D J ,  KASHYAP TERESITA

IPC: C08F210/16

Abstract: Ethylene-based polymers of this disclosure include an average g′ less than 0.86, where the average g′ is an intrinsic viscosity ratio determined by gel permeation chromatography using a triple detector; and a molecular weight tail quantified by an MWD area metric, ATAIL, and ATAIL is less than or equal to 0.04 as determined by gel permeation chromatography using a triple detector.

公开(公告)号：SG11202109338WA

公开(公告)日：2021-09-29

申请号：SG11202109338W

申请日：2020-03-27

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： FROESE ROBERT D J ,  KASHYAP TERESITA ,  REDWINE OSCAR D ,  ARRIOLA DANIEL J ,  SAMMLER ROBERT L ,  DEN DOELDER CORNELIS F J

IPC: C08F210/18 ,  C08F4/64

Abstract: Embodiments of this disclosure include polymers comprising the polymerized product of ethylene, at least one diene comonomer, and optionally at least one C3 to C14 comonomer. The polymer comprises tri -functional long-chain branches resulting from the diene that occur at a frequency of at least 0.03 per 1000 carbon atoms of the polymer. The diene has a structure according to formula (I):

公开(公告)号：SG11202102963UA

公开(公告)日：2021-04-29

申请号：SG11202102963U

申请日：2019-09-27

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： KASHYAP TERESITA ,  FROESE ROBERT D J ,  ARRIOLA DANIEL J

IPC: C08F210/18 ,  C08F210/16

Abstract: Ethylene-based polymers of this disclosure include a melt viscosity ratio (V0.1/V100) at 190° C. of at least 10, where V0.1 is the viscosity of the ethylene-based polymer at 190° C. at a shear rate of 0.1 radians/second, and V100 is the viscosity of the ethylene-based polymer at 190° C. at a shear rate of 100 radians/second; and a molecular weight tail quantified by an MWD area metric, ATAIL, and ATAIL is less than or equal to 0.04 as determined by gel permeation chromatography using a triple detector.