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    PROCEDIMIENTO PARA LA PREPARACION DE 2-OXO-1,3-DIOXOLANOS
    21.
    发明专利
    PROCEDIMIENTO PARA LA PREPARACION DE 2-OXO-1,3-DIOXOLANOS 未知

    公开(公告)号：ES2000286A6

    公开(公告)日：1988-02-01

    申请号：ES8601130

    申请日：1986-08-14

    Applicant: HOECHST AG

    Inventor： BRINDOPKE GERHARD ,  MARTEN MANFRED

    IPC: C07D317/36 ,  C07D317/38 ,  C08G59/00 ,  C08G71/04

    Abstract: PROCEDIMIENTO PARA LA PREPARACION DE 2-OXO-1,3-DIOXOLANOS POR REACCION DE EPOXIDOS CON DIOXIDO DE CARBONO EN PRESENCIA DE UN CATALIZADOR, EN EL CUAL SE MEZCLA POR LO MENOS UN COMPUESTO EPOXIDICO EN PRESENCIA O AUSENCIA DE UN DISOLVENTE INERTE, CON POR LO MENOS UN CATALIZADOR, Y SE HACE REACCIONAR A TEMPERATURAS DE 40 A 180JC CON INTRODUCCION DE DIOXIDO DE CARBONO A PRESION NORMAL O A PRESION LIGERAMENTE ELEVADA, PARA FORMAR LOS CORRESPONDIENTES CARBONATOS ORGANICOS. LOS 2-OXO-1,3-DIOXOLANOS OBTENIDOS SE UTILIZAN PARA LA PREPARACION DE RESINAS SINTETICAS CON CONTENIDO DE GRUPOS URETANO, EN FORMA DE REVESTIMIENTOS Y CUERPOS MOLDEADOS.

    24.
    发明专利
    未知

    公开(公告)号：MX173127B

    公开(公告)日：1994-02-02

    申请号：MX522587

    申请日：1987-02-13

    Applicant: HOECHST AG

    Inventor： SPRENGER WALTER ,  FINKE MANFRED ,  LENZ RUDIGER ,  WALZ GERD ,  HONEL MICHAEL ,  BRINDOPKE GERHARD

    IPC: C07C67/00 ,  C07D317/36 ,  C07C239/00 ,  C07C269/00 ,  C07C271/20 ,  C07D303/28 ,  C08G18/06 ,  C08G18/32 ,  C08G18/64 ,  C08G18/70 ,  C08G18/80 ,  C08G18/83 ,  C08G59/02 ,  C08G59/40 ,  C08G71/04 ,  C09D5/44 ,  C09D175/04 ,  C09D175/12

    Abstract: Amino-urethanes (I) claimed are of formula R3-N(Re)-A-R1-NH-C(O)-O-CH2-CH(OH)-CH2- R-CH2-CH(OH)-CH2-O-C(O)-NH- R1-A-N(R2)R3 R is residue of a diglycidyl ether or ester, or 2-18 alkylene gp.; R1 is opt. branched 2-18C alkylene; R2 is H, 1-8Calkyl, or 1-8C hydroxyalkyl; R3 is R2, or R3 with R2 can form cyclic ring, or, if R2 is H then R3 can be at least one gp. of formula (a) -C(O)-O-CH2-CH(R4)-CH2- (R-CH2-CH(R4)-CH2-OmB-(R4)n R4 is OH or -CONH-PI-NHCO R6; B is residue of a polyol; m is 1-3; n is 1-6; and PI is residue of a polyisocyanate and R6 is residue of (cylco)aliphatic, or alkylaromatic alcohol, an aminoalcohol, ketoxime, or a CH- or NH- acidic cpd.: b) R3 is gp. of formula (I) R5 is H or R4; R7 is 1-8Calkyl; and s is 1-6; c) -C(O)-NH-PI-NH-C(O)-O-B-d)R8-CHOH-CH2-O-CO-; e) R8-CHOH-CH2-; R8 is H, 1-18C alkyl, or residue of a glycidyl ester or ether; or f) PI'NHCO- PI' is residue of a partly capped polyisocyanate; and A 75 chemical bond or -R1NH)r-R1NH- r is 0-6. Prodn. of a (I) by heating an at least bifunctional 2-oxo-1,3-dioxolan (II) and a prim polyamine at 20-150 deg.C is claimed. Structural formulae are given for pref. R, viz. residues of a bisphenol diglycidyl ether opt. linked by residues of a diamine, diol, dicarboxylic acid, di-isocyanate, etc. Pref. (II) is bicyclic carbonate of specified formuls esp. derived from polyglycidyl ether of a polyphenol, or a epoxide-cyclic carbonate.

    25.
    发明专利
    未知

    公开(公告)号：MX170907B

    公开(公告)日：1993-09-22

    申请号：MX345286

    申请日：1986-08-15

    Applicant: HOECHST AG

    Inventor： BRINDOPKE GERHARD ,  MARTEN MANFRED

    IPC: C07D317/36 ,  C07D317/38 ,  C08G59/00 ,  C08G59/14

    Abstract: 1. A process for the preparation of 2-oxo-1,3-dioxolanes by reaction of epoxides with carbon dioxide in the presence of a catalyst and, if necessary, an inert solvent, wherein the reaction is effected at temperatures from 40 to 180 degrees C and at normal pressure or slightly increased pressure in the presence of at least one catalyst from the group comprising triphenylphosphane, tritolylphosphane, diazabicyclo[2.2.2]octane, 4-dimethylaminopyridine, 4-(1-pyrrolidinyl)pyridine, amidines, imidazole and the alkyl, aryl, or aralkyl substitution products thereof.

    AMINOURETHANES
    28.
    发明专利
    AMINOURETHANES 未知

    公开(公告)号：AU6872787A

    公开(公告)日：1987-08-20

    申请号：AU6872787

    申请日：1987-02-12

    Applicant: HOECHST AG

    Inventor： WALZ GERD ,  HONEL MICHAEL ,  BRINDOPKE GERHARD ,  SPRENGER WALTER ,  FINKE MANFRED ,  LENZ RUDIGER

    IPC: C07D317/36 ,  C07C67/00 ,  C07C239/00 ,  C07C269/00 ,  C07C271/20 ,  C07D303/28 ,  C08G18/06 ,  C08G18/32 ,  C08G18/64 ,  C08G18/70 ,  C08G18/80 ,  C08G18/83 ,  C08G59/02 ,  C08G59/40 ,  C08G71/04 ,  C09D5/44 ,  C09D175/04 ,  C09D175/12 ,  C07C91/12 ,  C09D3/72 ,  C08L75/12 ,  C08L75/04 ,  C07C87/14 ,  C07C1/24

    Abstract: Amino-urethanes (I) claimed are of formula R3-N(Re)-A-R1-NH-C(O)-O-CH2-CH(OH)-CH2- R-CH2-CH(OH)-CH2-O-C(O)-NH- R1-A-N(R2)R3 R is residue of a diglycidyl ether or ester, or 2-18 alkylene gp.; R1 is opt. branched 2-18C alkylene; R2 is H, 1-8Calkyl, or 1-8C hydroxyalkyl; R3 is R2, or R3 with R2 can form cyclic ring, or, if R2 is H then R3 can be at least one gp. of formula (a) -C(O)-O-CH2-CH(R4)-CH2- (R-CH2-CH(R4)-CH2-OmB-(R4)n R4 is OH or -CONH-PI-NHCO R6; B is residue of a polyol; m is 1-3; n is 1-6; and PI is residue of a polyisocyanate and R6 is residue of (cylco)aliphatic, or alkylaromatic alcohol, an aminoalcohol, ketoxime, or a CH- or NH- acidic cpd.: b) R3 is gp. of formula (I) R5 is H or R4; R7 is 1-8Calkyl; and s is 1-6; c) -C(O)-NH-PI-NH-C(O)-O-B-d)R8-CHOH-CH2-O-CO-; e) R8-CHOH-CH2-; R8 is H, 1-18C alkyl, or residue of a glycidyl ester or ether; or f) PI'NHCO- PI' is residue of a partly capped polyisocyanate; and A 75 chemical bond or -R1NH)r-R1NH- r is 0-6. Prodn. of a (I) by heating an at least bifunctional 2-oxo-1,3-dioxolan (II) and a prim polyamine at 20-150 deg.C is claimed. Structural formulae are given for pref. R, viz. residues of a bisphenol diglycidyl ether opt. linked by residues of a diamine, diol, dicarboxylic acid, di-isocyanate, etc. Pref. (II) is bicyclic carbonate of specified formuls esp. derived from polyglycidyl ether of a polyphenol, or a epoxide-cyclic carbonate.

    29.
    发明专利
    未知

    公开(公告)号：BR8603901A

    公开(公告)日：1987-03-24

    申请号：BR8603901

    申请日：1986-08-15

    Applicant: HOECHST AG

    Inventor： BRINDOPKE GERHARD ,  MARTEN MANFRED

    IPC: C07D317/36 ,  C07D317/38 ,  C08G59/00 ,  C08J5/22

    Abstract: 1. A process for the preparation of 2-oxo-1,3-dioxolanes by reaction of epoxides with carbon dioxide in the presence of a catalyst and, if necessary, an inert solvent, wherein the reaction is effected at temperatures from 40 to 180 degrees C and at normal pressure or slightly increased pressure in the presence of at least one catalyst from the group comprising triphenylphosphane, tritolylphosphane, diazabicyclo[2.2.2]octane, 4-dimethylaminopyridine, 4-(1-pyrrolidinyl)pyridine, amidines, imidazole and the alkyl, aryl, or aralkyl substitution products thereof.

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