公开(公告)号：ZA945923B

公开(公告)日：1996-02-08

申请号：ZA945923

申请日：1994-08-08

Applicant: HOECHST AG

Inventor： EPPLE ULRICH ,  KUBILLUS UWE ,  SCHMIDT HOLGER

IPC: C08F20060101 ,  C09D20060101 ,  C08F ,  C09D

公开(公告)号：ZA9405405B

公开(公告)日：1996-01-22

申请号：ZA9405405

申请日：1994-07-22

Applicant: HOECHST AG

Inventor： EPPLE ULRICH ,  KUBILLUS UWE ,  BRINDOEPKE GERHARD ,  DOESSEL KARL-FRIEDRICH

IPC: C08F4/28 ,  C08F4/34 ,  C08F20/10 ,  C08F20/26 ,  C08F212/08 ,  C08F220/04 ,  C08F220/12 ,  C08F220/18 ,  C08F220/26 ,  C08F220/28 ,  C08F220/32 ,  C09D5/00 ,  C09D5/03 ,  C09D133/00 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/14 ,  C09D175/04 ,  C08F ,  C09D

CPC classification number: C08F220/12 ,  C08F220/04

公开(公告)号：CZ192994A3

公开(公告)日：1995-03-15

申请号：CZ192994

申请日：1994-08-09

Applicant: HOECHST AG

Inventor： EPPLE ULRICH ,  KUBILLUS UWE ,  SCHMIDT HOLGER

IPC: C08F220/32 ,  C08F2/02 ,  C08F220/04 ,  C08F220/06 ,  C08F220/10 ,  C08F222/02 ,  C08G18/62 ,  C09D133/02 ,  C09D133/06 ,  C09D133/14 ,  C09D135/00 ,  C09D175/04

Abstract: Copolymers of particularly low viscosity which can be prepared by bulk polymerisation in which component (A) is introduced at the beginning of the polymerisation and at least two olefinically unsaturated, copolymerisable monomers (B), of which at least one contains at least one COOH group and at least one is sterically hindered, are added during the further course of the polymerisation.

公开(公告)号：BR9401384A

公开(公告)日：1994-12-13

申请号：BR9401384

申请日：1994-04-04

Applicant: HOECHST AG

Inventor： SCHMIDT HOLGER ,  BRUECK TANJA REGINA ,  KUBILLUS UWE ,  OSWALD HARALD ,  SCHAUB PETRA ,  HEMMER ANDREA TRAVERS

IPC: B05D3/02 ,  C08F8/44 ,  C08F12/00 ,  C08F20/10 ,  C08F212/06 ,  C08F220/04 ,  C08F220/06 ,  C08F220/18 ,  C08F220/28 ,  C08F220/32 ,  C08G59/02 ,  C08G59/32 ,  C08J3/07 ,  C08L61/28 ,  C09D5/00 ,  C09D125/00 ,  C09D125/02 ,  C09D125/14 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/10 ,  C09D133/14 ,  C09D161/20 ,  C09D161/28 ,  C09D163/00 ,  C08F220/10

Abstract: Water-dilutable dispersions of acrylate copolymers having a hydroxyl number of from 40 to 200 mg of KOH/g and an acid number of from 15 to 50 mg of KOH/g, obtained by free-radical copolymerization of a) from 5 to 40 parts by weight of at least one glycidyl ester of an aliphatic, saturated monocarboxylic acid which is branched in the alpha -position, b) from 0 to 30 parts by weight of at least one diester of an alpha , beta -olefinically unsaturated dicarboxylic acid, c) from 0 to 70 parts by weight of at least one vinyl aromatic hydrocarbon, where the molar amount of component c) is always greater than or equal to the molar amount of component b), d) from 0 to 60 parts by weight of an alkyl ester of an alpha , beta -olefinically unsaturated carboxylic acid, e) from 2 to 40 parts by weight of at least one alpha , beta -olefinically unsaturated carboxylic acid, where the molar amount of component e) is always greater than the molar amount of component a), f) from 5 to 40 parts by weight of at least one hydroxyalkyl ester of an alpha , beta -olefinically unsaturated carboxylic acid, where the polymerisation is carried out in the presence or absence of solvents, optionally with addition of a water-dilutable solvent, neutralisation and dilution with water. These dispersions are suitable as water-dilutable binders for stoving (baking) varnishes or stoving solid-colour top coats.

公开(公告)号：ZA918200B

公开(公告)日：1992-07-29

申请号：ZA918200

申请日：1991-10-15

Applicant: HOECHST AG

Inventor： BRINDOEPKE GERHARD ,  GERHARD BRINDOEPKE ,  KUBILLUS UWE ,  UWE KUBILLUS ,  PLUM HELMUT ,  HELMUT PLUM

IPC: A47K3/28 ,  A47K3/30 ,  C08G59/14 ,  C08G59/16 ,  C08G59/40 ,  C08G59/50 ,  C08G59/62 ,  C09D163/00 ,  C09D

Abstract: A liquid coating composition is based on an acetoacetate group-containing polymer and a polyamine in the form of the corresponding aldimine or ketimine, where the acetoacetate group-containing polymer is obtained by reacting a polyepoxide with water, an amine, a hydroxycarboxylic acid and subsequently esterifying or transesterifying the final product using acetoacetic acid. This liquid coating composition is particularly suitable as a binder in two-component automobile repair fillers or as a two-component primer.

公开(公告)号：AU8581491A

公开(公告)日：1992-04-30

申请号：AU8581491

申请日：1991-10-15

Applicant: HOECHST AG

Inventor： BRINDOEPKE GERHARD ,  KUBILLUS UWE ,  PLUM HELMUT

IPC: A47K3/28 ,  A47K3/30 ,  C08G59/14 ,  C08G59/16 ,  C08G59/40 ,  C08G59/50 ,  C08G59/62 ,  C09D163/00 ,  C09D179/02 ,  C09D171/02

Abstract: A liquid coating composition is based on an acetoacetate group-containing polymer and a polyamine in the form of the corresponding aldimine or ketimine, where the acetoacetate group-containing polymer is obtained by reacting a polyepoxide with water, an amine, a hydroxycarboxylic acid and subsequently esterifying or transesterifying the final product using acetoacetic acid. This liquid coating composition is particularly suitable as a binder in two-component automobile repair fillers or as a two-component primer.

公开(公告)号：BR9002723A

公开(公告)日：1991-08-20

申请号：BR9002723

申请日：1990-06-08

Applicant: HOECHST AG

Inventor： ESSER KLAUS ,  DUERR HELMUT ,  PLATH DIETER ,  SCHOEN MANFRED ,  KUBILLUS UWE

IPC: C09D7/12 ,  C09D7/80 ,  C09D201/00 ,  C09D201/06 ,  C09D5/04

Abstract: Coating compsn. contains (A) a film-forming resin, (B) a cellulose ester, (C) solvent, (D) metal pigment and opt. (E) crosslinkers and (F) further lacquer additives and of the type esp. to give a multi-layer coating with a base layer and opt. a clear topcoat. (i) the cellulose ester (B) has an acetyl content of 2-30 (pref. 2-5) wt.%, a butyryl content of 17-53 (pref. 47-53) wt.% and an average mol.wt. of at least 25000, pref. 30000-60000; and (ii) this cellulose ester is introduced into the coating compsn. in the form of a pasty, thixotropic pre-mix (e.g. with the crosslinkers). The solids content of the compsn. is pref. 15-30 wt.%. The cellulose ester pre-mix pref. contains a diluent which swells the cellulose ester, esp. an aromatic or aliphatic hydrocarbon or a higher alcohol. alcohol.

公开(公告)号：CA2026454A1

公开(公告)日：1991-03-31

申请号：CA2026454

申请日：1990-09-28

Applicant: HOECHST AG

Inventor： HONEL MICHAEL ,  WALZ GERD ,  ZIEGLER PETER ,  KUBILLUS UWE

IPC: C09D7/12 ,  C08G59/50 ,  C08L63/00 ,  C08L101/00 ,  C09D5/02 ,  C09D5/44 ,  C09D163/00 ,  C09D201/00

Abstract: - ? - HOE 89/F 322 Use of crosslinked polymer microparticles in paints as filler substitute and/or as crosslinking filler The invention relates to the use of crosslinked polymer microparticles having an average particle size of at most 5 .mu.m and a glass transition temperature (Tg) of at least +30.degree.C in aqueous paint preparations as filler and/or as partial substitute of white pigments, in particular of titanium dioxide. Among other things, the corresponding paints show increased spreading power, less tendency for sedimentation and reduced crater formation.

公开(公告)号：DE59602420D1

公开(公告)日：1999-08-19

申请号：DE59602420

申请日：1996-04-25

Applicant: HOECHST AG

Inventor： EPPLE ULRICH ,  KUBILLUS UWE ,  OSWALD HARALD

IPC: C08F220/32 ,  C08F20/32 ,  C08F220/04 ,  C08F222/02 ,  C08F222/16 ,  C08G18/62 ,  C09D133/02 ,  C09D133/04 ,  C09D133/14 ,  C09D135/00 ,  C09J133/02 ,  C09J133/04 ,  C09J133/14 ,  C09J135/00 ,  C09K3/10

Abstract: Low-mol. wt. copolymers (I) with a wt.-average mol. wt. (Mw) of less than 3500 contain at least 20 wt.% of components with branched side chains, obtd. by the reaction of (aa) glycidyl ester(s) of satd. aliphatic monocarboxylic acids with a tert. or quat. alpha -C atom; and (ab) at least two unsatd. comonomers, at least one of which contains at least one COOH gp., under radical copolymerisation conditions. Also claimed are (i) prepn. of (I) by heating component (aa) to 210-260 degrees C and reacting with component (ab) (which contains at least 2.0 wt.% of a COOH gp.-contg. monomer) in the presence of radical initiator(s), to a degree of conversion of at least 95 (pref. at least 97.5) %; (ii) polymer mixts. contg. (I), obtd. by reaction of (aa) and (ab) as above in at least two time intervals with a constant temp. in each interval, using at least two different reaction temps., at least one of which is in the range 210-260 degrees C; (iii) polymer mixts. contg. (I) and other polymers etc.; (iv) binders for coating materials contg. (I) or the above polymer mixts.; (v) coating materials contg. binders as above and hardeners such as amino resins, capped or uncapped polyisocyanates or organic cpds. with acid and/or anhydride gps.

公开(公告)号：AT164600T

公开(公告)日：1998-04-15

申请号：AT95106087

申请日：1995-04-24

Applicant: HOECHST AG

Inventor： EPPLE ULRICH ,  KUBILLUS UWE ,  SCHMIDT HOLGER

IPC: C08F2/00 ,  C08F8/30 ,  C08F20/26 ,  C08F220/04 ,  C08F220/10 ,  C08F220/28 ,  C08F220/32 ,  C08F222/02 ,  C08F222/20 ,  C09D5/03 ,  C09D5/46 ,  C09D133/00 ,  C09D133/04 ,  C09D133/14 ,  C09D135/02 ,  C09D175/04

Abstract: Low-viscosity copolymers with OH and COOH gps. (I) are obtd. by reacting (A) 3 - 50 wt.% glycidyl ester(s) of satd. aliphatic carboxylic acids with a tert. or quat. alpha -C atom and (B) 97 - 50 wt.% of at least 2 unsatd. comonomers, at least one of which contains at least one COOH gp. and at least one of which is sterically hindered, in the presence of radical initiators, and with an excess of COOH gps. in (B) wrt. epoxide gps. in (A) such that the prod. has an acid no. of at least 15 mg KOH/g. Also claimed is the above process for the prodn. of (I). Also claimed are 1-component paints with (I) as binder and formaldehyde/amino-resin reaction prods. (opt. etherated with 1 - 8 C aliphatic alcohol) as hardeners, and 2-component paints with (I) as binder and polyisocyanates or urethane-forming polyisocyanate derivs. as hardeners.