公开(公告)号：DE19615128A1

公开(公告)日：1997-10-30

申请号：DE19615128

申请日：1996-04-17

Applicant: HOECHST AG

Inventor： KREUDER WILLI DR ,  LUPO DONALD DR ,  SALBECK JOSEF DR ,  SCHENK HERMANN DR ,  STEHLIN THOMAS DR

IPC: C08G61/00 ,  C08G61/12 ,  C08G73/06 ,  C09K11/06 ,  H01L51/50 ,  H05B33/10 ,  C08G73/08 ,  H05B33/14 ,  C08L101/12

Abstract: A conjugated polymer containing recurrent unit of the formula (I) in which PSI is an element of the 4th main group of the periodic system except for carbon; D, E, F , G are the same or different, and mean -CR R -, -O-, -S-, -NR - or a chemical bond; U is -CR =CR - or a chemical bond; V means U or is -CR R -, -O-, -S-, -NR -, -SiR R -, -SO2-, -SO-, -CO-; A is the same or different and means H, a C1-C20 hydrocarbon radical which may also contain a heteroatom; T is -O-, -S-, -NR -, -CR R -, -CH=N-, -CA=CA-, -CH=CA-, -CH=CF- or -CF=CF-; K, Q are the same or different and are hydrocarbon radicals which may contain heteroatoms and are characterised by conjugated electron systems; M, L are H or a straight or branched-chain alkyl group with 1 to 22 C atoms, Br, Cl, F, CN, NO2 or CF3; m, n are the same or different and are 0, 1, 2, 3 or 4; said polymers are suitable as electroluminescent materials.

公开(公告)号：DE4442052A1

公开(公告)日：1996-05-30

申请号：DE4442052

申请日：1994-11-25

Applicant: HOECHST AG

Inventor： KREUDER WILLI DR ,  LUPO DONALD DR ,  SALBECK JOSEF DR ,  SCHENK HERMANN DR ,  STEHLIN THOMAS DR

IPC: H01L51/50 ,  C07F7/08 ,  C07F7/22 ,  C07F7/30 ,  C08G61/00 ,  C09K11/06 ,  H01L51/00 ,  H01L51/30 ,  C09D165/00 ,  H05B33/14 ,  C07F7/00 ,  C07F9/547 ,  C07F9/653 ,  C07F9/6561 ,  C07D413/14

Abstract: The proposed conjugated polymers contain repeating units of formula I, in which the symbols and indices have the following meanings: psi is a group IV element other than carbon; D, E, F and G are identical or different, for example -O- or a chemical bond; U represents (for example) a chemical bond; V can have the same meaning as U or can represent -O-; the groups A are identical or different, and are (for example) H or a C1-C20 hydrocarbon group; T represents (for example) -O- or -CA=CA-, A having the meaning indicated above; K, L, M and Q are identical or different and represent hydrocarbon groups which can contain heteroatoms and are characterized by conjugated electron systems; m and n are identical or different integers 0, 1, 2, 3 or 4. The proposed polymers can be used as electroluminescent materials.

公开(公告)号：DE4436773A1

公开(公告)日：1996-04-18

申请号：DE4436773

申请日：1994-10-14

Applicant: HOECHST AG

Inventor： KREUDER WILLI DR ,  LUPO DONALD DR ,  SALBECK JOSEF DR ,  SCHENK HERMANN DR ,  STEHLIN THOMAS DR

IPC: C07C17/35 ,  C07C25/22 ,  C07C69/00 ,  C07C69/76 ,  C08G61/00 ,  C08G61/02 ,  C09K11/06 ,  H01L51/30 ,  H01L51/50 ,  H05B33/14 ,  C09D165/00 ,  C08L65/00

Abstract: Conjugated polymers (I) contg. recurring units, having a 9,9'-spiro-bifluorene ring system, of formula (II) are new: A, B, C, D = 1-15 arylene, heteroarylene and/or vinylene gps. and these and the spiro-bifluorene ring system may be substd.; S = H or a substit., m, n = 0 or 1. Also claimed are: (a) the use of (I) as electroluminescent material; (b) electroluminescent material contg. (I); (c) prodn. of the material by applying a (I) film to a substrate; and (d) electroluminescent device with active layer(s), at least one or which contains (I).

公开(公告)号：ES2056186T3

公开(公告)日：1994-10-01

申请号：ES89123522

申请日：1989-12-20

Applicant: HOECHST AG

Inventor： LUPO DONALD DR ,  PRASS WERNER DR ,  SCHEUNEMANN UDE DR

IPC: B05D1/20 ,  B32B27/30 ,  C07C233/05 ,  C07C233/80 ,  C08F20/34 ,  C08F20/36 ,  C08F20/52 ,  C08F20/60 ,  C08J5/18

Abstract: Amphiphilic monomers with mixed-chain structures of the formula in which Y denotes -O- or -NH- X denotes a group of the formula -(CH2)n- or -(CH2-O-CH2)n- l denotes an integer from 0 to 10, n denotes an integer from 1 to 10, R1 denotes hydrogen, methyl, chlorine, cyano, fluorine or bromine, R2 denotes C1-C24-alkyl or C1-C24-fluoroalkyl and R3 denotes C8-C24-alkyl or C8-C24-fluoralkyl, with the proviso that the groups R2 and R3 contain a different number of carbon atoms. The monomers are polymerized on their own or together with other comonomers. The polymers obtained are suitable for the preparation of ultra-thin layers on a suitable layer support.

公开(公告)号：DE3870071D1

公开(公告)日：1992-05-21

申请号：DE3870071

申请日：1988-07-21

Applicant: HOECHST AG

Inventor： LASCHEWSKY ANDRE DR ,  RINGSDORF HELMUT PROF DR ,  INTERTHAL WERNER DR ,  LUPO DONALD DR ,  PRASS WERNER DR ,  SCHEUNEMANN UDE DR

IPC: C08J5/18 ,  C07C67/00 ,  C07C241/00 ,  C07C251/86 ,  C09B26/00 ,  C09B26/02 ,  C09B67/02 ,  G02B1/04 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361

Abstract: Film consists of monolayer(s) of or contg. an amphiphilic cpd., which is a 4-alkoxy-, 4-acyloxy-, 4-aminoalkyl-, 4-alkylaminoalkyl-, 4-acylamino- or 4-N-alkyl-N-acyl-amino -benzaldehyde 4'-nitrophenylhydrazone of formula (I) (where R1 = a CH3-(CH2)m-O-, CH3-(CH2)n-CO-O-, CH(CH2)nN(CH2)lH or CH3(CH2)n(CO)N(CH2)lH gp.; m = 10-25; n = 8-22; l = 0-25; in which the mols. are oriented in the same direction, parallel to one another and not centro-symmetrically).

公开(公告)号：DE3912824A1

公开(公告)日：1990-10-25

申请号：DE3912824

申请日：1989-04-19

Applicant: HOECHST AG

Inventor： LUPO DONALD DR ,  PRASS WERNER DR ,  SCHEUNEMANN UDE DR

IPC: B05D1/20 ,  C08G69/26

Abstract: New polyamide (I) contg. medium to long-chain alkyl gps. is of the formula: -(N(A) X N(B) CO Y CO)n (I); (where Y = a divalent gp.; X = a divalent gp. with at least 2C atoms in the chain; A and B independently = H or 1-26C alkyl; n = over 4). (I) contains at least o ne 6-26, esp. 14-20C alkyl gp./recurring unit. The novelty is that X and/or Y contain at least one CH2 gp. in the chain.

公开(公告)号：DE19619227A1

公开(公告)日：1997-11-20

申请号：DE19619227

申请日：1996-05-13

Applicant: HOECHST AG

Inventor： LUPO DONALD DR ,  APPEL GUNTHER DIPL ING ,  CABRERA IVAN DR ,  SCHEUNEMANN UDE DR ,  SCHOENFELD AXEL DR

IPC: G01N1/22 ,  G01N31/22 ,  G01N33/00 ,  G01N21/77

Abstract: An ozone collector for determining integral ozone pollution is characterised in that it contains a dye with conjugated double bonds contained in a polymer layer with at least one polymer. Also disclosed is a process for determining integral ozone contamination.

公开(公告)号：DE19537969A1

公开(公告)日：1997-04-17

申请号：DE19537969

申请日：1995-10-12

Applicant: HOECHST AG

Inventor： LUPO DONALD DR

IPC: G02F1/35 ,  C08F12/00 ,  C08F28/00 ,  C08F30/04 ,  C08F112/32 ,  C08F124/00 ,  C08F126/06 ,  C08F128/06 ,  C08F130/00 ,  G02F1/355 ,  G02F1/361 ,  C08G61/10 ,  C08G61/12

Abstract: The use of spiro cpds. of formula (I) or of conjugated polymers (II) contg. recurring units of formula (IIA) in non-linear optical applications is claimed; psi = C, Si, Ge or Sn, pref. (I) psi = Ge, esp. Si or more esp. C; K , K = conjugated systems; D, E, F, G = -CR R -, -O-, -S-, -NR - or a chemical bond; R , R , R = 1-20 C alkyl or H; or R + R form an opt. substd. cycloalkyl ring; U = -CR =CR - or a chemical bond; V = U, -CR R -, -O-, -S-, -NR -, -SiR R -, -SO2-, -SO- or -CO-; R , R = as R or F or CF3; A = H or 1-20 C hydrocarbyl, opt. contg. hetero-atom(s); R , R = H, 1-20 C aliphatic, alicyclic or aromatic hydrocarbyl or R + R form a ring; T = -O-, -S-, -NR -, -CR R -, -CH=N-, -CA=CA-, -CH=CA-, -CH=CF- or -CF=CF-; K, L, M, Q = hydrocarbyl gps., opt. contg. hetero-atom(s), with conjugated electron systems, which may form a satd. or partly or max. unsatd. ring with the A gp. in the ortho-position, esp. an annelated aromatic ring system; L, M may also = H, unconjugated hydrocarbyl (pref. with 1-20 C atoms and opt. hetero-atom(s)), halogen, CN, NO2, NH2 or (di)alkylamino; m, n = 0, 1, 2 or 3.

公开(公告)号：DE19509450A1

公开(公告)日：1996-09-26

申请号：DE19509450

申请日：1995-03-20

Applicant: HOECHST AG

Inventor： LUPO DONALD DR ,  REMMERS MARCUS ,  NEHER DIETER DR

IPC: H05B33/10 ,  C08G61/02 ,  C09K11/06 ,  H01L51/00 ,  H01L51/30 ,  H01L51/50 ,  H01L51/52 ,  H05B33/12 ,  H05B33/14 ,  C08G81/00

Abstract: The invention concerns an electroluminescence device with at least one light-emitting layer containing conjugated, stiff-chain polymers which are soluble in organic solvents. The device is characterised by the fact that the emitted electroluminescence is polarised, the intensity of the light polarised parallel to the longitudinal axis of the substrate being at least three times greater than the light polarised perpendicularly to that axis.

公开(公告)号：DE4431039A1

公开(公告)日：1996-03-07

申请号：DE4431039

申请日：1994-09-01

Applicant: HOECHST AG

Inventor： STERN ROLAND DR ,  LUPO DONALD DR ,  SALBECK JOSEF DR ,  SCHENK HERMANN DR ,  STEHLIN THOMAS DR ,  MUELLEN KLAUS PROF ,  KREYENSCHMIDT MARTIN DR ,  SCHERF ULLRICH DR

IPC: C07C25/22 ,  C07B61/00 ,  C07C17/12 ,  C08G61/00 ,  C08G61/10 ,  C09K11/06 ,  H01L51/30 ,  H01L51/50 ,  H05B33/12 ,  H05B33/14

Abstract: Poly (4,5,9,10-tetrahydropyrene-2,7-diyl) derivs. of formula (I) are new (where, R1-R4 = H, 1-22C alkyl (opt. contg. one or more non-adjacent CH2 gps. substd. by O, -COO-, -OOC- and/or phenylene), aryl(oxy) (opt. a substd on the aryl ring with one or more of 1-22C alkyl, 1-22C alkoxy Br, Cl, F, CN and/or NO2)., Br, Cl, F, CN, NO2 or 2-23C carboalkoxy; and n = 10-150). Also claimed are: (i) prepn. of (I) by reacting one or more cpds. of formula (II) with bis(1,5-cyclooctadiene) nickel (O) and a 2,2'-bipyridine in an inert organic solvent (mixt); (ii) electroluminescent materials contg. (I); (iii) electroluminescent devices contg. at least one layer of the material; and (iv) prepn. of (II) by reacting a 4,5,9,10-tetrahydropyrene deriv. with bromine in an inert organic solvent in the presence of a gp. VIII transition metal on an active carbon carrier.