公开(公告)号：DE19711714A1

公开(公告)日：1998-10-01

申请号：DE19711714

申请日：1997-03-20

Applicant: HOECHST AG

Inventor： SALBECK JOSEF DR ,  LUPO DONALD DR

IPC: C07D241/46 ,  C07C13/72 ,  C07C211/54 ,  C07C217/84 ,  C07C217/92 ,  C07C217/94 ,  C07D209/86 ,  C07D209/88 ,  C07D219/02 ,  C07D413/10 ,  C07D417/10 ,  C09K11/06 ,  H01L51/00 ,  H01L51/05 ,  H01L51/30 ,  H01L51/42 ,  H01L51/50 ,  H05B33/14 ,  C07C211/50 ,  C07D295/04 ,  H01L31/0256

Abstract: The invention relates to spiro compounds of the formula (I) wherein at least one of the radicals K , L, M, N , R , R , R , R is one of the groups (a), (b), (c), (d), (e), (f), (g), (h), (i), (j) and (k). Said spiro compounds are suitable for use as charge transfer materials, especially for photovoltaic cells, and as electroluminescence materials.

公开(公告)号：DE4442050A1

公开(公告)日：1996-05-30

申请号：DE4442050

申请日：1994-11-25

Applicant: HOECHST AG

Inventor： KREUDER WILLI DR ,  LUPO DONALD DR ,  SALBECK JOSEF DR ,  SCHENK HERMANN DR ,  STEHLIN THOMAS DR

IPC: H01L51/50 ,  C07C13/72 ,  C07F7/08 ,  C07F7/30 ,  C08G61/00 ,  C08G79/00 ,  C09K11/06 ,  H01L51/00 ,  H01L51/30 ,  H05B33/14 ,  C07F7/00 ,  C07D413/14 ,  C07F1/02 ,  C07F7/12 ,  C07F7/22 ,  C07F9/547 ,  C07F9/6561

Abstract: The invention concerns the use in electroluminescent devices of heterospiro-compounds of formula (I), in which PSI means an element of the fourth main group of the periodic system of elements, with the exception of carbon, and is preferably Sn, Ge or Si, particularly preferably Ge or Si, and K and K , independently of each other, mean conjugated systems. The compounds of formula (I) are distinguished by good solubility in common organic solvents, improved film-forming properties and a considerably reduced tendency towards crystallization.

公开(公告)号：DE19744792A1

公开(公告)日：1999-04-15

申请号：DE19744792

申请日：1997-10-10

Applicant: HOECHST AG

Inventor： SALBECK JOSEF DR ,  BECKER HEINRICH DR ,  KREUDER WILLI DR ,  WEINFURTNER KARL HEINZ DIPL CH

IPC: H01L51/50 ,  C07C13/64 ,  C07C35/44 ,  C07F9/6568 ,  C09K11/06 ,  H05B33/14 ,  C07C50/22 ,  C07C22/04 ,  C07C39/17 ,  C07C63/49 ,  C07C47/546 ,  C07C33/34 ,  C07D269/02 ,  C07C211/61 ,  G01N21/66

Abstract: Triptycene derivatives are useful in electroluminescent devices. The use of triptycene derivatives of formula (I) in electroluminescent devices is claimed: K -K = optionally substituted mono- or polycyclic systems which may also contain hetero atoms; X, Y = CR , N, P, As or SiR ; R = H, halogen, pseudohalogen or 1-30 C hydrocarbyl (optionally containing hetero atoms); R = 1-30 C hydrocarbyl (optionally containing hetero atoms). Independent claims are also included for: (a) compounds (I) as such in which at least one of the groups K -K is a fluorophore; (b) electroluminescent devices containing one or more active layers, at least one of which contains one or more triptycene derivatives (I).

公开(公告)号：DE4431039A1

公开(公告)日：1996-03-07

申请号：DE4431039

申请日：1994-09-01

Applicant: HOECHST AG

Inventor： STERN ROLAND DR ,  LUPO DONALD DR ,  SALBECK JOSEF DR ,  SCHENK HERMANN DR ,  STEHLIN THOMAS DR ,  MUELLEN KLAUS PROF ,  KREYENSCHMIDT MARTIN DR ,  SCHERF ULLRICH DR

IPC: C07C25/22 ,  C07B61/00 ,  C07C17/12 ,  C08G61/00 ,  C08G61/10 ,  C09K11/06 ,  H01L51/30 ,  H01L51/50 ,  H05B33/12 ,  H05B33/14

Abstract: Poly (4,5,9,10-tetrahydropyrene-2,7-diyl) derivs. of formula (I) are new (where, R1-R4 = H, 1-22C alkyl (opt. contg. one or more non-adjacent CH2 gps. substd. by O, -COO-, -OOC- and/or phenylene), aryl(oxy) (opt. a substd on the aryl ring with one or more of 1-22C alkyl, 1-22C alkoxy Br, Cl, F, CN and/or NO2)., Br, Cl, F, CN, NO2 or 2-23C carboalkoxy; and n = 10-150). Also claimed are: (i) prepn. of (I) by reacting one or more cpds. of formula (II) with bis(1,5-cyclooctadiene) nickel (O) and a 2,2'-bipyridine in an inert organic solvent (mixt); (ii) electroluminescent materials contg. (I); (iii) electroluminescent devices contg. at least one layer of the material; and (iv) prepn. of (II) by reacting a 4,5,9,10-tetrahydropyrene deriv. with bromine in an inert organic solvent in the presence of a gp. VIII transition metal on an active carbon carrier.

公开(公告)号：DE4411969A1

公开(公告)日：1995-10-19

申请号：DE4411969

申请日：1994-04-07

Applicant: HOECHST AG

Inventor： LUPO DONALD DR ,  SALBECK JOSEF DR ,  SCHENK HERMANN DR ,  STEHLIN THOMAS DR ,  STERN ROLAND DR ,  WOLF ARNO DR ,  KREUDER WILLI DR

IPC: C07C13/72 ,  C07D271/10 ,  C07D271/107 ,  C07D307/80 ,  C09K11/06 ,  H01L51/30 ,  H05B33/14 ,  C07D307/78 ,  C07C211/60 ,  C07D405/04 ,  C07D413/14 ,  C07D417/14 ,  G02F1/15 ,  G09F9/33

Abstract: The use of spiro cpds. of formula (I) in electroluminescent devices is claimed. In (I), K1, K2 = conjugated systems. Also claimed are spiro cpds. of formula (IA); electroluminescent devices contg. cpd(s). (I); and organic electroluminescent material. In (IA), A, B, K, L, M, N = R-Q-(T)m-(CH=CH)n-, R1-(T)m-(CH=CH)n-, R-Q-(CH=CH)n-(T)m-, R1-(CH=CH)n-(T)m-, R1-(T)p-(CH=CH)n-(T)m- or R2R3N-; and A, B may also = a 1-22 C alkyl, alkoxy or ester gp., CN, NO2; Ar or -O-Ar; Q = (a (het)arylene gp. of formula (II); and T = a (het)arylene gp. of formula (III): Ar = phenyl, biphenyl, 1- or 2-naphthyl, 2-thienyl or 2-furanyl, opt. mono- or di-substd. by R; m, n, p 0, 1, 2 or 3; X, Y = CR or N; X = -O-, -S-, -CR1R4, -CH=CH- or -CH=N-; R, R1, R4 = H, a 1-22 C alkyl, alkoxy or ester gp., CN, NO2, -NR2R3, Ar or -O-Ar; R2, R3 = H, 1-22 C alkyl, Ar or 3-methylphenyl.

公开(公告)号：DE19646411A1

公开(公告)日：1998-05-14

申请号：DE19646411

申请日：1996-11-11

Applicant: HOECHST AG

Inventor： SALBECK JOSEF DR ,  GRAETZEL MICHAEL PROF DR

IPC: H01L27/14 ,  G01J1/42 ,  H01L31/09 ,  H01L51/00 ,  H01L51/30 ,  H01L51/42 ,  H01L31/101 ,  H01L31/0256

Abstract: An optoelectric radiation detector detecting short wave electromagnetic radiation, characterized by a charge transfer layer containing a hole conduction material.

公开(公告)号：DE4446818A1

公开(公告)日：1996-07-04

申请号：DE4446818

申请日：1994-12-27

Applicant: HOECHST AG

Inventor： LUPO DONALD DR ,  SALBECK JOSEF DR ,  SCHENK HERMANN DR ,  STEHLIN THOMAS DR ,  STERN ROLAND DR ,  WOLF ARNO DR ,  KREUDER WILLI DR

IPC: C07C13/72 ,  C07D271/10 ,  C07D271/107 ,  C07D307/80 ,  C09K11/06 ,  H01L51/30 ,  H05B33/14 ,  C07C13/567 ,  C07C211/57 ,  C07D263/32 ,  C07D263/56 ,  C07D307/79 ,  G09F9/33

Abstract: The use of spiro cpds. of formula (I) in electroluminescent devices is claimed. In (I), K1, K2 = conjugated systems. Also claimed are spiro cpds. of formula (IA); electroluminescent devices contg. cpd(s). (I); and organic electroluminescent material. In (IA), A, B, K, L, M, N = R-Q-(T)m-(CH=CH)n-, R1-(T)m-(CH=CH)n-, R-Q-(CH=CH)n-(T)m-, R1-(CH=CH)n-(T)m-, R1-(T)p-(CH=CH)n-(T)m- or R2R3N-; and A, B may also = a 1-22 C alkyl, alkoxy or ester gp., CN, NO2; Ar or -O-Ar; Q = (a (het)arylene gp. of formula (II); and T = a (het)arylene gp. of formula (III): Ar = phenyl, biphenyl, 1- or 2-naphthyl, 2-thienyl or 2-furanyl, opt. mono- or di-substd. by R; m, n, p - 0, 1, 2 or 3; X, Y = CR or N; X = -O-, -S-, -CR1R4, -CH=CH- or -CH=N-; R, R1, R4 = H, a 1-22 C alkyl, alkoxy or ester gp., CN, NO2, -NR2R3, Ar or -O-Ar; R2, R3 = H, 1-22 C alkyl, Ar or 3-methylphenyl.

公开(公告)号：DE4435047A1

公开(公告)日：1996-04-04

申请号：DE4435047

申请日：1994-09-30

Applicant: HOECHST AG

Inventor： KREUDER WILLI DR ,  LUPO DONALD DR ,  SALBECK JOSEF DR ,  SCHENK HERMANN DR ,  STEHLIN THOMAS DR ,  HOERHOLD HANS-HEINRICH PROF ,  LUX ANDREA DIPL ING ,  TEUSCHEL ANNETT DIPL ING ,  WIEDUWILT MARTINA DIPL ING

IPC: C07C43/215 ,  C07C43/285 ,  C07D495/22 ,  C08G61/00 ,  C08G73/06 ,  C09K11/00 ,  C09K11/06 ,  H01L51/30 ,  H05B33/14 ,  C07D407/08 ,  C07D409/06 ,  C07D417/14

Abstract: The use of polymers contg. repeating units of formula (I) as electroluminescent materials is claimed: A , A = arylene or heteroarylene gps. with one or more rings, opt. bridged and/or condensed and opt. substd.; A = monovalent aryl or heteroaryl gps. opt. modified as above. Also claimed are: (i) electroluminescent material contg. one or more polymers of formula (I); (ii) a process for the prodn. of such material by: (a) polycondensation of an organophosphorus cpd. of formula Z2P(O)-CH2A -CH2P(O)Z2 (III) with a diketone of formula A -CO-A -CO-A (II) in the presence of a base to give polymer (I); and (b) casting the polymer as a film on a substrate, and (iii) an electroluminescent system with one or more active layers, at least one of which contains polymer (I).

公开(公告)号：DE4422670A1

公开(公告)日：1996-01-04

申请号：DE4422670

申请日：1994-06-30

Applicant: HOECHST AG

Inventor： STERN ROLAND DR ,  LUPO DONALD DR ,  SALBECK JOSEF DR ,  SCHENK HERMANN DR ,  STEHLIN THOMAS DR ,  MUELLEN KLAUS PROF DR ,  SCHERF ULLRICH DR ,  HUBER JOACHIM DR

IPC: C08G61/00 ,  C08G61/02 ,  C09K11/06 ,  H01L51/50 ,  H05B33/14 ,  C07D321/00 ,  C07D339/00 ,  C07D327/00 ,  C07D245/06 ,  C07C49/747 ,  C07C49/723 ,  C07C49/623 ,  C07C25/18 ,  C07C13/32

Abstract: Conjugated polymers with ansa structural sections (I) contain aromatic gps. combined in such a way that a ring atom in one such gp. is directly linked with a ring atom in another adjacent gp., and any other linkages of these two aromatic gps. can only be via a bridge contg. at least one tetravalent C atom and/or hetero atom. Also claimed are electroluminescent devices contg. (I).

公开(公告)号：DE19711713A1

公开(公告)日：1998-10-01

申请号：DE19711713

申请日：1997-03-20

Applicant: HOECHST AG

Inventor： BACH UDO ,  GRAETZEL MICHAEL PROF DR ,  SALBECK JOSEF DR ,  WEISOERTEL FRANK ,  LUPO DONALD DR

IPC: H01G9/00 ,  H01G9/20 ,  H01L31/04 ,  H01L31/06 ,  H01L51/00 ,  H01L51/30 ,  H01M14/00

Abstract: The invention relates to a photovoltaic cell with an electrolyte which has a redox system in the form of a hole conductor compound.