23.
    发明专利
    未知

    公开(公告)号:DE4117935A1

    公开(公告)日:1992-12-03

    申请号:DE4117935

    申请日:1991-05-31

    Applicant: HOECHST AG

    Abstract: In the process described for the preparation of alkoxylates having a narrow distribution of homologs by reaction of compounds containing at least one hydroxyl group with alkylene oxide, complex compounds of antimony pentahalide with a special Lewis base are used as the catalysts. Alkoxylates having a narrow distribution of homologs and good color quality are obtained at a high conversion.

    25.
    发明专利
    未知

    公开(公告)号:BR9101578A

    公开(公告)日:1991-12-10

    申请号:BR9101578

    申请日:1991-04-19

    Applicant: HOECHST AG

    Inventor: WIMMER IGNAZ

    Abstract: In the process described, alkoxylation of compounds containing active hydrogen atoms using antimony pentahalides as catalyst is carried out such that first a catalyst premix is prepared by dissolving antimony pentahalide in a portion of the amount of the compound to be alkoxylated while maintaining a maximum temperature of 60 DEG C and a maximum antimony pentahalide concentration of 30 mol%, the catalyst premix prepared or a portion thereof is combined as the catalyst component with the remaining amount of the compound to be alkoxylated, and the starting mixture thus obtained is reacted with the alkylene oxide.

    26.
    发明专利
    未知

    公开(公告)号:DE4012725A1

    公开(公告)日:1991-10-24

    申请号:DE4012725

    申请日:1990-04-21

    Applicant: HOECHST AG

    Inventor: WIMMER IGNAZ

    Abstract: In the process described, alkoxylation of compounds containing active hydrogen atoms using antimony pentahalides as catalyst is carried out such that first a catalyst premix is prepared by dissolving antimony pentahalide in a portion of the amount of the compound to be alkoxylated while maintaining a maximum temperature of 60 DEG C and a maximum antimony pentahalide concentration of 30 mol%, the catalyst premix prepared or a portion thereof is combined as the catalyst component with the remaining amount of the compound to be alkoxylated, and the starting mixture thus obtained is reacted with the alkylene oxide.

    27.
    发明专利
    未知

    公开(公告)号:BR9001939A

    公开(公告)日:1991-07-30

    申请号:BR9001939

    申请日:1990-04-26

    Applicant: HOECHST AG

    Abstract: In the novel process for the purification of an alkylene oxide adduct which has been prepared using halogen-containing metal catalysts and contains halogen-containing compounds and metals as impurities, the alkylene oxide adduct to be purified is treated with an excess of the alkali metal compound, and the alkaline mixture obtained is brought to a pH of not more than 7 using an acid, with the proviso that the amount of water present in the resulting product mixture is at least 0.1% by weight, relative to the weight of the product. This product mixture is freed from water and other solvents, as a result of which the salts insoluble in the alkylene oxide adduct precipitate in the form of coarse crystals and can be easily separated off to give the desired pure alkylene oxide adduct.

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