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    21.
    发明专利
    未知

    公开(公告)号：DK0593458T3

    公开(公告)日：1996-07-08

    申请号：DK91908530

    申请日：1991-04-08

    Applicant: ISP INVESTMENTS INC

    Inventor： TAYLOR PAUL D ,  BUCHANAN DONALD W JR ,  DE THOMAS WALDO

    IPC: B01J23/80 ,  B01J35/10 ,  B01J37/18 ,  C07B61/00 ,  C07D307/33 ,  C07D315/00 ,  B01J23/06 ,  B01J23/72

    Abstract: Vapor phase catalytic hydrogenation of maleic anhydride to gamma-butyrolactone is achieved in a conversion of 95% or more and a selectivity of 80% or more during a prolonged period of production. The process uses an activated catalyst prepared by reducing a catalyst composition comprising 30-65% by weight of CuO, 18-50% by weight of ZnO and 8-22% by weight of Al2O3, and activating the reduced catalyst composition in hydrogen at an activation temperature of at least 400 DEG C., preferably 400 DEG to 525 DEG C., and optimally about 425 DEG C. The process suitably is carried out under predetermined and advantageous process conditions, including a defined molar ratio of hydrogen to maleic anhydride in the vapor reactant stream, a selected pressure during hydrogenation, a defined feed rate space velocity, a predetermined contact time, and a suitable reaction temperature.

    ALKENYL ETHERS AND RADIATION CURABLE COMPOSITIONS
    22.
    发明专利
    ALKENYL ETHERS AND RADIATION CURABLE COMPOSITIONS 未知

    公开(公告)号：AU6893691A

    公开(公告)日：1991-08-21

    申请号：AU6893691

    申请日：1990-11-23

    Applicant: ISP INVESTMENTS INC

    Inventor： VARA FULVIO J ,  DOUGHERTY JAMES A ,  PLOTKIN JEFFREY S ,  NARAYANAN KOLAZI S ,  TAYLOR PAUL D

    IPC: C07F7/04 ,  C08F2/46 ,  C08F8/42 ,  C08G59/40 ,  C08G65/336 ,  C09D4/00 ,  C08G77/14 ,  C08J3/28

    Abstract: The invention relates to alk-1-enyl ether silicates having the formula (I): [X]4-nSi[OR1OCH=CH-R2]n, and a process for making same, wherein X is halogen or -OR wherein R is lower alkyl or a mixture of halogen and OR, a mixture of OR and hydrogen or a mixture of halogen and hydrogen; R1 contains from 1 to 8 carbon atoms and is alkylene, alkenylene, alkynylene, optionally alkoxylated with up to 20 units of alpha , wherein Y is hydrogen or methyl and R2 is each hydrogen or lower alkyl and n has a value of from 1 to 4; and polyfunctional alkenyl ether having the formula (II): A[(CH2O)m(Z)rCH=CHR]n, wherein A is a carbon atom, -OCH=CHR or [C1 to C10 alkyl]4-n; R is C1 to C6 alkyl; Z is C2 to C8 alkyleneoxy; r has a value of from 0 to 6; m has a value of from 0 to 1 and at least one of r and m has a positive value; n has a value of from 1 to 4, with the proviso that m is 0 and n is one when A is -OCH=CHR, n has a value of 2 or 3 when A is [C1 to C10 alkyl]4-n and n has a value of 4 when A is carbon. This invention also relates to a radiation curable cross linkable compositions containing (a) from about 0.1 to about 5 wt. % of an initiator containing at least 25 % cationic intiator, (b) from about 0 to about 60 wt. % of a polymerizable vinyl ether, epoxide, vinyloxy alkyl urethane or acrylate and (c) from about 35 to about 99.9 wt. % of an ether of formula (II).

    24.
    发明专利
    未知

    公开(公告)号：ES2085992T3

    公开(公告)日：1996-06-16

    申请号：ES91908530

    申请日：1991-04-08

    Applicant: ISP INVESTMENTS INC

    Inventor： TAYLOR PAUL D ,  DE THOMAS WALDO ,  BUCHANAN DONALD W JR

    IPC: B01J23/80 ,  B01J35/10 ,  B01J37/18 ,  C07B61/00 ,  C07D307/33 ,  C07D315/00 ,  B01J23/06 ,  B01J23/72

    Abstract: Vapor phase catalytic hydrogenation of maleic anhydride to gamma-butyrolactone is achieved in a conversion of 95% or more and a selectivity of 80% or more during a prolonged period of production. The process uses an activated catalyst prepared by reducing a catalyst composition comprising 30-65% by weight of CuO, 18-50% by weight of ZnO and 8-22% by weight of Al2O3, and activating the reduced catalyst composition in hydrogen at an activation temperature of at least 400 DEG C., preferably 400 DEG to 525 DEG C., and optimally about 425 DEG C. The process suitably is carried out under predetermined and advantageous process conditions, including a defined molar ratio of hydrogen to maleic anhydride in the vapor reactant stream, a selected pressure during hydrogenation, a defined feed rate space velocity, a predetermined contact time, and a suitable reaction temperature.

    25.
    发明专利
    未知

    公开(公告)号：AT135938T

    公开(公告)日：1996-04-15

    申请号：AT91908530

    申请日：1991-04-08

    Applicant: ISP INVESTMENTS INC

    Inventor： TAYLOR PAUL D ,  DE THOMAS WALDO ,  BUCHANAN DONALD W JR

    IPC: B01J23/80 ,  B01J35/10 ,  B01J37/18 ,  C07B61/00 ,  C07D307/33 ,  C07D315/00 ,  B01J23/06 ,  B01J23/72

    Abstract: Vapor phase catalytic hydrogenation of maleic anhydride to gamma-butyrolactone is achieved in a conversion of 95% or more and a selectivity of 80% or more during a prolonged period of production. The process uses an activated catalyst prepared by reducing a catalyst composition comprising 30-65% by weight of CuO, 18-50% by weight of ZnO and 8-22% by weight of Al2O3, and activating the reduced catalyst composition in hydrogen at an activation temperature of at least 400 DEG C., preferably 400 DEG to 525 DEG C., and optimally about 425 DEG C. The process suitably is carried out under predetermined and advantageous process conditions, including a defined molar ratio of hydrogen to maleic anhydride in the vapor reactant stream, a selected pressure during hydrogenation, a defined feed rate space velocity, a predetermined contact time, and a suitable reaction temperature.

    VINYL ETHER COMPOUNDS
    27.
    发明专利
    VINYL ETHER COMPOUNDS 未知

    公开(公告)号：CA2075367A1

    公开(公告)日：1991-08-07

    申请号：CA2075367

    申请日：1991-01-30

    Applicant: ISP INVESTMENTS INC

    Inventor： LIU KOU-CHANG ,  VARA FULVIO J ,  DOUGHERTY JAMES A ,  NARAYANAN KOLAZI S ,  PLOTKIN JEFFREY S ,  TAYLOR PAUL D

    IPC: C07C43/23 ,  C07C69/96 ,  C07C323/12 ,  C08F8/00 ,  C08F36/04 ,  C08F36/06 ,  C08F290/00 ,  C08F299/00 ,  C08G18/67 ,  C08G63/00 ,  C08G63/12 ,  C08G64/00 ,  C08G64/04 ,  C08G65/32 ,  C07C205/49 ,  C07C255/00

    Abstract: 2075367 9113052 PCTABS00007 Alkenyl ether carbonates having formula (A) wherein A is RHC=CHO(B)n-, lower alkyl or a mixture thereof; B is (a) divalent radical having from 2 to 12 carbon atoms and is selected from the group of alkylene, mono or polyalkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, alkyl, cyano, nitro or alkoxy; R is hydrogen or lower alkyl and n is from 1 to 10. These are provided alkenyl ether polycarbonate, a polymerizable compound formed from reaction of a dialkenyl ether monocarbonate and a polyhydroxy alcohol having at least three hydroxy groups, a polymerizable compound formed from the reaction of a hydroxylated polymeric polyether, polyurethane, polycarbonate, polyester of an alkanedioic acid or polybutadiene and a dialkenyloxy carbonate co-reactant, and polyaryloxypolyvinyl ethers. The polymerized compounds are intermediates for hard abrasion resistant films and coatings. The monomers and oligomers are intermediates for hydrogels or photoresist materials.

    VINYLOXY HYDROXYALKYLCYCLOALKANE AND PREPARATION THEREFOR
    28.
    发明专利
    VINYLOXY HYDROXYALKYLCYCLOALKANE AND PREPARATION THEREFOR 未知

    公开(公告)号：CA2045645A1

    公开(公告)日：1990-08-09

    申请号：CA2045645

    申请日：1990-01-04

    Applicant: ISP INVESTMENTS INC

    Inventor： LIU KOU-CHANG ,  TAYLOR PAUL D

    IPC: C07C41/08 ,  C07C43/178

    Abstract: 2045645 9009364 PCTABS00001 The invention relates to a vinyloxy hydroxyalkyl cycloalkylene having the formula HO(CH2)x-A-(CH2)x'OCH=CH2, wherein x has a value of from 1 to 10; x' has a value of from 0 to 10 and A is a cycloalkylene group having from 3 to 8 carbon atoms in the ring and is optionally substituted with lower alkyl. The invention also relates to the method for synthesizing the above compounds.

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