1.
    发明专利
    未知

    公开(公告)号:DE19681695T1

    公开(公告)日:1998-11-05

    申请号:DE19681695

    申请日:1996-12-12

    Abstract: A polymerizable composition consisting essentially of about 50 to about 90% by weight of vinylpyrrolidone monomer, about 10 to about 50% by weight of vinyl caprolactam monomer, and about 0.5 to about 7% by weight of a crosslinker, which is capable of proliferous polymerization in the absence of base at about 80 DEG -120 DEG C.

    3.
    发明专利
    未知

    公开(公告)号:DE19681695B4

    公开(公告)日:2007-01-25

    申请号:DE19681695

    申请日:1996-12-12

    Abstract: A polymerizable composition consisting essentially of about 50 to about 90% by weight of vinylpyrrolidone monomer, about 10 to about 50% by weight of vinyl caprolactam monomer, and about 0.5 to about 7% by weight of a crosslinker, which is capable of proliferous polymerization in the absence of base at about 80 DEG -120 DEG C.

    PROCESS FOR MAKING HIGHLY CROSSLINKED POLYVINYLPYRROLIDONE

    公开(公告)号:CA2154767A1

    公开(公告)日:1994-09-15

    申请号:CA2154767

    申请日:1994-02-25

    Inventor: TSENG SUSAN Y

    Abstract: A process is described for making highly crosslinked polyvinylpyrrolidone (PVP) polymer by popcorn polymerization having a swell volume of less than about 65 ml/10 g, preferably 40-65 ml/10 g, in the absence of added crosslinking agent, and with substantially no induction period. The process comprises (a) providing a reaction mixture of vinylpyrrolidine (VP) monomer at a concentration of about 75-85 % in an aqueous basic solution, containing about 0.4-0.8 % base, under agitation, in an inert gas atmosphere, and at an initial gas pressure of at least 2 bars, (b) heating said mixture at a predetermined temperature and time sufficient to generate an active crosslinker in situ, and (c) reducing the temperature of the mixture to a temperature whereupon popcorn polymerization of said VP monomer commences substantially immediately to form the desired crosslinked PVP.

    PROCESS FOR MAKING HIGHLY CROSSLINKED POLYVINYLPYRROLIDONE
    7.
    发明公开
    PROCESS FOR MAKING HIGHLY CROSSLINKED POLYVINYLPYRROLIDONE 失效
    工艺生产高交联聚乙烯吡咯烷酮

    公开(公告)号:EP0738289A4

    公开(公告)日:1996-07-01

    申请号:EP94909726

    申请日:1994-02-25

    Inventor: TSENG SUSAN Y

    CPC classification number: C08F26/10

    Abstract: A process is described for making highly crosslinked polyvinylpyrrolidone (PVP) polymer by popcorn polymerization having a swell volume of less than about 65 ml/10 g, preferably 40-65 ml/10 g, in the absence of added crosslinking agent, and with substantially no induction period. The process comprises (a) providing a reaction mixture of vinylpyrrolidone (VP) monomer at a concentration of about 75-85 % in an aqueous basic solution, containing about 0.4-0.8 % base, under agitation, in an inert gas atmosphere, and at an initial gas pressure of at least 2 bars, (b) heating said mixture at a predetermined temperature and time sufficient to generate an active crosslinker in situ, and (c) reducing the temperature of the mixture to a temperature whereupon popcorn polymerization of said VP monomer commences substantially immediately to form the desired crosslinked PVP.

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