公开(公告)号：JP2007176887A

公开(公告)日：2007-07-12

申请号：JP2005379633

申请日：2005-12-28

Applicant: Kao Corp ,  花王株式会社

Inventor： NOJIRI MASAYOSHI ,  TSUCHIYA MASARU ,  FUJII YASUYUKI ,  TAKEUCHI HIROKI

IPC: A61K8/41 ,  A61K8/22 ,  A61Q5/10

Abstract: PROBLEM TO BE SOLVED: To provide a hair dye effective for restoring the springy or wavy hair generated at the tip of excessively damaged hair to the natural state, suppressing the generation of the springy or wavy hair, reducing the degradation of the feeling of the hair and uniformly dyeing the hair from the root to the tip. SOLUTION: The hair dye composition contains the components (A) to (C) and has a pH of 8-12. (A) A quaternary ammonium salt expressed by general formula (1) (R 1 is a 6-12C saturated or unsaturated hydrocarbon group; R 2 and R 3 are each independently a 1-3C alkyl; n is an integer of 0-2; m is 1 or 2; and X - is halide ion, alkylsulfate ion or alkyl- or arylsulfonic acid ion), (B) an oxidizing agent and (C) toluene-2,5-diamine, p-aminophenol or their acid addition salts. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：为了提供有效地将在过度损坏的头发的尖端产生的弹性或波浪状毛发恢复到自然状态的染发剂，抑制弹性或波浪状头发的产生，减少感觉的退化 的头发，并将毛发从根部均匀地染色到尖端。 毛发染料组合物含有成分（A）〜（C），pH为8〜12。 （A）由通式（1）表示的季铵盐（R 1 是6-12C饱和或不饱和烃基; R 2 和R 3 各自独立地为1-3C烷基; n为0-2的整数; m为1或2; X为 - 卤素离子，烷基硫酸根离子或烷基 - 或芳基磺酸 离子），（B）氧化剂和（C）甲苯-2,5-二胺，对氨基苯酚或其酸加成盐。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2003327550A

公开(公告)日：2003-11-19

申请号：JP2003058210

申请日：2003-03-05

Applicant: Kao Corp ,  花王株式会社

Inventor： YANAGI NICHIKEI ,  MATSUBARA HIROSHI ,  YASUDA SHINJI ,  SUGIYAMA HIROYUKI ,  FUJII YASUYUKI ,  KITA KATSUMI

IPC: C07C5/00 ,  C07C5/02 ,  C07C5/03 ,  C07C9/15 ,  C07C13/48 ,  C07C13/615 ,  C07C17/354 ,  C07C25/02 ,  C07C29/147 ,  C07C29/58 ,  C07C33/05 ,  C07C33/22 ,  C07C41/30 ,  C07C43/20 ,  C07C45/68 ,  C07C47/52 ,  C07C67/347 ,  C07C69/76 ,  C07C209/78 ,  C07C211/45

Abstract: PROBLEM TO BE SOLVED: To carry out an organic reaction at high temperatures and to provide a method for separation with which a reaction product can be separated from a fluorine/organic amphiphilic ether compound that is a reusable solvent after completing the reaction.
SOLUTION: The organic reaction using the fluorine/organic amphiphilic ether compound represented by general formula (1): Rf-(CH
2 )
n -O-R (wherein, Rf denotes a fluoroalkyl group in which at least one hydrogen atom in a linear or a branched 1-20C alkyl group is substituted with a fluorine atom; R denotes a linear or branched 1-36C alkyl group or a 3-9C cycloalkyl group; and n denotes a number of 0-8) is carried out in the homogeneous phase using the fluorine/ organic amphiphilic ether as a reaction solvent. A fluorous solvent that is an organic compound in which at least a part is substituted with fluorine is then added to the resultant reaction mixture to separate the reaction product form the fluorous solvent and the fluorine/organic amphiphilic ether compound. The method for separation is provided.
COPYRIGHT: (C)2004,JPO

Abstract translation: 要解决的问题：在高温下进行有机反应，并提供一种分离方法，通过该方法可以使反应产物在完成反应后与作为可重复使用的溶剂的氟/有机两亲醚化合物分离。 解决方案：使用由通式（1）表示的氟/有机两亲醚化合物的有机反应：Rf-（CH 2 ） -OR（其中， Rf表示直链或支链1-20C烷基中的至少一个氢原子被氟原子取代的氟代烷基; R表示直链或支链的1-36C烷基或3-9C环烷基;以及 使用氟/有机两亲性醚作为反应溶剂，在均相中n表示0-8的数。 然后将至少部分被氟取代的有机化合物的氟溶剂加入到所得反应混合物中，以从氟溶剂和氟/有机两亲醚化合物中分离反应产物。 提供了分离方法。 版权所有（C）2004，JPO

公开(公告)号：JP2001199845A

公开(公告)日：2001-07-24

申请号：JP2000013795

申请日：2000-01-24

Applicant: KAO CORP

Inventor： FUJII YASUYUKI ,  YANO SHINJI

IPC: A61K8/00 ,  A61Q5/00 ,  A61Q5/12 ,  C07C43/13 ,  A61K7/06 ,  A61K7/08

Abstract: PROBLEM TO BE SOLVED: To provide a hair cosmetic good in slipperiness when applied, giving no hair squeakiness after dried, and excellent in slipperiness with refreshingness. SOLUTION: This hair cosmetic contains a fluorine-contg. compound of the general formula (I) (wherein, Rf is a fluoroalkyl group where a fluorine atom is substituted for at least one of the hydrogen atoms of a 1-20C straight-chain or branched chain alkyl group; A is an oxygen atom; n is 0 or 1; m is 1-3; and R is H or 1-6C alkyl group having 1-3 hydroxyl group(s)).

公开(公告)号：JP2000273067A

公开(公告)日：2000-10-03

申请号：JP8102199

申请日：1999-03-25

Applicant: KAO CORP

Inventor： FUJII YASUYUKI ,  YANO SHINJI

IPC: A61K8/30 ,  C07C69/63 ,  C10M105/54 ,  C11D3/43 ,  C11D7/50 ,  A61K7/00

Abstract: PROBLEM TO BE SOLVED: To obtain the novel subject compound having a specific branched alkyl chain and functions which fluorine has, stable under various conditions, excellent in compatibility with other solvents, etc., and useful as solvents, cosmetics, detergents, emulsifiers, surface treating agents, lubricants, etc. SOLUTION: This fluorine-containing ester compound is expressed by formula I [Rf is a 1-12C fluoroalkyl; R1 is a 6-35C branched chain alkyl; (n) is 1-8], e.g. 2-(perfluorooctyl)ethyl 2-ethylhexanoate. The compound of formula I is obtained by reacting a fluorine-containing compound expressed by the formula Rf-(CH2)n-O-H [preferably, an 8-10C alcohol such as 2-(perfluorooctyl)ethanol, 2-(perfluorohexyl)ethanol or the like] with a carboxylic acid expressed by formula II (a branched chain carboxylic acid having 7-36C, preferably 7-18C and liquid at the normal temperature, e.g. 2-ethylhexanoic acid and the like) or its halogenated compound (an acid chloride), its lower alkyl ester, its acid anhydride or the like.

公开(公告)号：JPH11322652A

公开(公告)日：1999-11-24

申请号：JP13212898

申请日：1998-05-14

Applicant: KAO CORP

Inventor： FUJII YASUYUKI ,  YANO SHINJI

IPC: B01J23/44 ,  C07B61/00 ,  C07C41/05 ,  C07C43/12 ,  C07C43/192

Abstract: PROBLEM TO BE SOLVED: To provide a method for simply and inexpensively producing a fluorinated ether compound which can be used, for example, in solvents, cosmetics, cleaning compositions, emulsifiers, and surface-treating agents. SOLUTION: This method comprises producing an ether compound by reacting a hydroxyl compound with a carbonyl compound, or solely a carbonyl compound, in the presence of a catalyst under the atmosphere of hydrogen, wherein the hydroxyl compound and/or the carbonyl compound are/is fluorinated compound(s), wherein the reaction is carried out continuously in a fixed-bed type reactor.

公开(公告)号：JPH11147817A

公开(公告)日：1999-06-02

申请号：JP31703997

申请日：1997-11-18

Applicant: KAO CORP

Inventor： NISHISAKA TAKAHIRO ,  YAMAZAKI SEIJI ,  FUJII YASUYUKI ,  YANO SHINJI

IPC: A61K8/30 ,  A61K8/00 ,  A61K8/06 ,  A61Q19/00 ,  A61K7/48 ,  A61K7/00

Abstract: PROBLEM TO BE SOLVED: To obtain a skin cosmetic which is excellent in water and oil repellent properties and useful as an oil agent remaining on skin for a long time, particularly a skin care cosmetic, by blending a specified fluorine compound thereto. SOLUTION: This skin cosmetic is obtained by blending a fluoric compound (e.g. perfluorooctylethyl octanoate or the like) of the formula (R is a hydrocarbon; X is a group connecting R to CH2 ; (n) is an integer; Rf is carbon fluoride or the like) preferably in an amount of 0.01-10 wt.% based on the whole composition. When necessary, e.g. purified water, a surfactant (e.g. a polyoxyethylene castor oil, a polyoxyethylene-curing castor oil or the like), an oil component (e.g. isotridecyl isononanoate, neopentylglycol dicaprate or the like), a moisturizer (e.g. glycerin, sorbitol or the like) and a viscosity-increasing agent (e.g. montmorillonite, a polyethyleneglycol or the like) can be blended with this cosmetic.

公开(公告)号：JPH11147808A

公开(公告)日：1999-06-02

申请号：JP31704097

申请日：1997-11-18

Applicant: KAO CORP

Inventor： NISHISAKA TAKAHIRO ,  YAMAZAKI SEIJI ,  FUJII YASUYUKI ,  YANO SHINJI

IPC: A61K8/30 ,  A61K8/00 ,  A61K8/06 ,  A61K8/72 ,  A61K8/81 ,  A61Q19/00 ,  A61K7/00 ,  A61K7/48

Abstract: PROBLEM TO BE SOLVED: To obtain a skin cosmetic excellent in water repellency and oil repellency and useful as a oil solution left for a long time in skin, especially as a skin care cosmetic by formulating a perfluoro polymer compound or the like having a specific molecular weight with a specified fluorine-based compound. SOLUTION: This skin cosmetic is obtained by formulating (A) a perfluoropolmer compound and/or a fluorinated polymer compound (e.g. fluorinated acrylic acid-based polymer or fluorinated alkylene oxide polymer) having 5,000 to 1,000,000 molecular weight with (B) a fluorine-based compound represented by the formula [R is a hydrocarbon; X is a group connecting R to CH2 ; (n) is an integer; Rf is a fluorinated carbon or the like] and not corresponding to the fluorinated polymer compound of the component A (e.g. perfluorooctylethyloctanoate or perfluorooctylethylstearate). The formulating amount of the component A to the component B is preferably

公开(公告)号：JPH11140008A

公开(公告)日：1999-05-25

申请号：JP30683697

申请日：1997-11-10

Applicant: KAO CORP

Inventor： TAMURA HIDEKO ,  FUJII YASUYUKI ,  YANO SHINJI

IPC: B01J23/44 ,  C07B61/00 ,  C07C41/09 ,  C07C43/12 ,  C07C43/192

Abstract: PROBLEM TO BE SOLVED: To provide a method for simply and inexpensively producing a fluorine-containing ether compound usable for a solvent, a cosmetic, a detergent composition, an emulsifying agent, a surface treating agent, etc. SOLUTION: In the method for producing an ether compound by reacting a hydroxy compound and a carbonyl compound or only the carbonyl compound by using a catalyst in a hydrogen atmosphere, a fluorine substituent group- containing fluorine compound is used as at least one of the hydroxy compound and the carbonyl compound and the reaction is carried out in the presence of a Lewis acid to give the objective fluorine-containing ether compound.

公开(公告)号：JPH09316017A

公开(公告)日：1997-12-09

申请号：JP12814196

申请日：1996-05-23

Applicant: KAO CORP

Inventor： FUJII YASUYUKI ,  UNO MITSURU ,  TAMURA HIDEKO ,  KITA KATSUMI

IPC: B01J23/44 ,  C07B61/00 ,  C07C41/01 ,  C07C41/09 ,  C07C43/04

Abstract: PROBLEM TO BE SOLVED: To simply and easily produce an ether compound useful as a solvent, etc., in high yield. SOLUTION: This ether compound is produced by proceeding a reaction of a hydroxy compound with a carbonyl compound in a hydrogen atmosphere under a catalyst while removing a formed water as a by-product with the proviso that at least one kind of hydroxy and carbonyl compounds is a polyfunctional compound. A polyfunctional alcohol used in the reaction has 2-10 hydroxy groups and polyfunctional carbonyl compound is a 2-20C compound having 2-10 carbonyl groups. The catalyst is a palladium catalyst, etc., supported on a carbon, etc. The water formed as a by-product is preferably distilled off with an unreacted raw material and the unreacted raw material is preferably separated from the water and returned to the reaction system.

公开(公告)号：JPH09263631A

公开(公告)日：1997-10-07

申请号：JP13320596

申请日：1996-05-28

Applicant: KAO CORP

Inventor： FUJII YASUYUKI ,  UNO MITSURU ,  KITA KATSUMI

IPC: C08G65/26

Abstract: PROBLEM TO BE SOLVED: To obtain a colorless and odorless new ether compound subject to no discoloration or odor emission with the lapse of time, moderately low in viscosity, low in hygroscopicity, excellent in stability, and useful as e.g. a surfactant such as deinking agent. SOLUTION: This new ether compound is expressed by formula I [R is a 1-36C alkyl; R is a (1-3C alkyl-substituted) 3-8C cyclic alkyl or 3-36C branched alkyl; A is a (hydroxyl-substituted) 2-6C alkylene; (n) is such a number as to satisfy the relationship: 30 and R are each H or a 1-35C alkyl; R is a 2-7C alkylene) in the presence of a palladium catalyst in a hydrogen atmosphere.