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    22.
    发明专利
    未知

    公开(公告)号：AT187439T

    公开(公告)日：1999-12-15

    申请号：AT96303754

    申请日：1996-05-24

    Applicant: STANDARD OIL CO OHIO

    Inventor： BRAZDIL JAMES F ,  CAVALCANTI FERNANDO A P

    IPC: B01J23/18 ,  B01J23/22 ,  B01J23/847 ,  B01J27/057 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

    Abstract: The process for the ammoxidation of a C3 to C5 paraffinic hydrocarbon to its corresponding alpha , beta -unsaturated hydrocarbon comprising reacting the C3 to C5 paraffinic hydrocarbon with ammonia and oxygen in a fluid bed reactor at a temperature of between 250 DEG C to 600 DEG C in the presence of a catalyst having the empirical formula as follows: VvSbmAaDdOx wherein A when present is Sn and/or Ti D when present is one or more of Li, Mg, Na, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al, P and Mn; and wherein v is 1, m is 0.5-75, a is 0 to 25, d is 0 to 25, and x is determined by the oxidation state of the cations present, and a minor quantity of an halogen-containing component, preferably characterized by the following formula: R-X or X2 where R=Hydrogen, C1-C20 alkyl and X=F, Cl, Br, I or mixtures thereof.arbo

    METHOD FOR AMMOXIDATION OF PARAFFINS
    27.
    发明专利
    METHOD FOR AMMOXIDATION OF PARAFFINS 未知

    公开(公告)号：CA2055739A1

    公开(公告)日：1992-06-04

    申请号：CA2055739

    申请日：1991-11-18

    Applicant: STANDARD OIL CO OHIO

    Inventor： BRAZDIL JAMES F ,  GLAESER LINDA C ,  TOFT MARK A

    IPC: B01J23/84 ,  B01J23/847 ,  B01J23/85 ,  B01J23/89 ,  B01J27/057 ,  B01J27/198 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/07 ,  C07C255/08

    Abstract: CSL-P-3645 Disclosed is a process for making an a , .beta.-unsaturated mononitrile by the catalytic reaction of a paraffin containing 3-5 carbon atoms with molecular oxygen and ammonia by catalytic contact of the foregoing reactants in a reaction zone with a metal oxide catalyst containing the elements indicated by the empirical formula, Vv Aa DdSnm Sbn CUc0x (formula 1) in the relative atomic proportions indicated by the subscripts, where A is selected from Te and Bi D is one or more optional elements selected from Mo, W, Ti, Ge, Ce, La, Cr, Mn, Mg, Ca, Co, Ni, Fe, Nb, Ta, Ag, Zn, Cd, B, P, Na, K and Cs, and a is 0.001 to 30 d is zero to 30 c is 0.001 to 30 m is 0.1 to 60 n is 0.1 to 60 n/v is > 12 and v + a + c + d, and x is determined by the valence requirements of the elements present, and wherein the reactants fed to the reaction zone contain a mole ratio of said paraffin:NH3 in the range from 2 to 16 and a mole ratio of said paraffin:02 in the range from 1 to 10. Applns.AZ5

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