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公开(公告)号：US3325504A
公开(公告)日：1967-06-13
申请号：US45053765
申请日：1965-04-23
Applicant: STANDARD OIL CO
Inventor： GRASSELLI ROBERT K
IPC: A22C29/02 , B01J23/18 , C07C45/36 , C07C255/34
CPC classification number: C07C253/28 , B01J23/18 , C07C45/36 , C07C255/50 , C07C255/34
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公开(公告)号：US3911039A
公开(公告)日：1975-10-07
申请号：US43584174
申请日：1974-01-23
Applicant: STANDARD OIL CO OHIO
Inventor： GRASSELLI ROBERT K , HARDMAN HARLEY F
IPC: B01J23/887 , C07C5/48 , C07C5/18
CPC classification number: B01J23/8876 , C07C5/48 , C07C11/167
Abstract: Catalysts containing molybdenum, bismuth, iron and nickel, cobalt, magnesium, zinc, cadmium, manganese calcium or mixture thereof and an alkali metal or T1 are promoted by an element selected from antimony and tin to give highly desirable catalysts for the oxidative dehydrogenation of olefins of 4 to about 10 carbon atoms.
Abstract translation: 含有钼，铋，铁和镍，钴，镁，锌，镉，锰钙或其混合物和碱金属或T1的催化剂由选自锑和锡的元素促进，以产生用于烯烃氧化脱氢的非常理想的催化剂 4至约10个碳原子。
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公开(公告)号：US3893951A
公开(公告)日：1975-07-08
申请号：US40046873
申请日：1973-09-25
Applicant: STANDARD OIL CO
Inventor： GRASSELLI ROBERT K , SURESH DEV D
IPC: B01J23/30 , B01J23/34 , B01J23/88 , B01J23/888 , C07C51/25 , C07C51/265 , C07C67/39 , B01J11/06 , B01J11/22
CPC classification number: C07C51/265 , B01J23/30 , B01J23/34 , B01J23/8885 , C07C51/25 , C07C51/252 , C07C67/39 , C07C57/145 , C07C57/04 , C07C63/16 , C07C69/54
Abstract: The present invention is catalysts that contain oxides or oxide complexes of at least tin, tungsten, vanadium and molybdenum. Optionally, the catalysts may also contain the oxides of iron, nickel, cobalt, zinc, manganese, magnesium or copper. These catalysts are very useful for the oxidation of acrolein to acrylic acid, the oxidation of butadiene to maleic anhydride and other oxidation reactions.
Abstract translation: 本发明是含有至少锡，钨，钒和钼的氧化物或氧化物络合物的催化剂。 任选地，催化剂还可以含有铁，镍，钴，锌，锰，镁或铜的氧化物。 这些催化剂对于将丙烯醛氧化成丙烯酸，将丁二烯氧化成马来酸酐和其它氧化反应非常有用。
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24.发明授权
公开(公告)号：US3892794A
公开(公告)日：1975-07-01
申请号：US22496772
申请日：1972-02-09
Applicant: STANDARD OIL CO
Inventor： GRASSELLI ROBERT K , SURESH DEV D , MILBERGER ERNEST C
IPC: C07C27/14 , B01J21/00 , B01J23/00 , B01J23/28 , B01J23/30 , B01J23/31 , B01J23/32 , B01J23/88 , B01J23/887 , B01J27/00 , B01J27/057 , C07B61/00 , C07C27/00 , C07C45/00 , C07C45/34 , C07C45/35 , C07C47/20 , C07C47/22 , C07C51/25 , C07C57/055 , C07C67/00 , C07C253/00 , C07C255/08 , C07D307/79 , C07D307/80 , C07D307/82 , C07D307/83 , C07D307/92 , C07D333/60 , C07D333/68 , D06L3/12 , C07C121/02
CPC classification number: B01J23/8875 , B01J23/28 , B01J23/30 , B01J23/31 , B01J23/32 , B01J23/8876 , B01J23/8878 , B01J27/00 , B01J27/0576 , B01J2523/00 , C07C45/34 , C07C45/35 , C07C51/252 , C07C253/26 , C07D307/79 , C07D307/80 , C07D307/82 , C07D307/83 , C07D307/92 , C07D333/60 , C07D333/68 , D06L4/636 , Y02P20/52 , C07C47/22 , C07C57/04 , B01J2523/53 , B01J2523/68 , C07C255/08
Abstract: A process for the catalytic oxidation of olefins to unsaturated aldehydes and acids and the ammoxidation of olefins to unsaturated nitriles in which the catalyst comprises a promoted, reduced, antimony oxide-molybdenum oxide-containing catalyst.
Abstract translation: 一种将烯烃催化氧化成不饱和醛和酸的方法，以及烯烃对不饱和腈的氨氧化反应，其中催化剂包含促进的，还原的氧化锑 - 氧化钼的催化剂。
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公开(公告)号：US3546174A
公开(公告)日：1970-12-08
申请号：US3546174D
申请日：1969-07-22
Applicant: STANDARD OIL CO
Inventor： GRASSELLI ROBERT K , CALLAHAN JAMES L
CPC classification number: C08G12/30 , C08G12/266
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Patent Agency Ranking
公开(公告)号：US3546138A
公开(公告)日：1970-12-08
申请号：US3546138D
申请日：1968-06-05
Applicant: STANDARD OIL CO
Inventor： CALLAHAN JAMES L , GRASSELLI ROBERT K , KNIPPLE WARREN R
CPC classification number: C07C253/26 , B01J23/84 , B01J23/8973 , C07C45/35 , Y02P20/52 , C07C47/22 , C07C255/08
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公开(公告)号：US3514488A
公开(公告)日：1970-05-26
申请号：US3514488D
申请日：1968-02-05
Applicant: STANDARD OIL CO
Inventor： UEBELE CURTIS E , GRASSELLI ROBERT K , NIXON WILLIAM C JR
IPC: C07C7/156 , C07C107/00 , C10G5/02
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公开(公告)号：US3435061A
公开(公告)日：1969-03-25
申请号：US42381865
申请日：1965-01-06
Applicant: STANDARD OIL CO
Inventor： GRASSELLI ROBERT K , CALLAHAN JAMES L
IPC: B01J23/16 , B01J23/18 , B01J23/644 , B01J23/68 , B01J23/84 , B01J23/843 , B01J27/19 , C07C45/36 , C07C47/20 , C07C255/34 , C07C121/02
CPC classification number: C07C253/28 , B01J23/16 , B01J23/6445 , B01J23/681 , B01J23/84 , B01J23/8435 , B01J27/19 , C07C45/36 , C07C255/34
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公开(公告)号：US3328315A
公开(公告)日：1967-06-27
申请号：US31165763
申请日：1963-09-26
Applicant: STANDARD OIL CO
Inventor： CALLAHAN JAMES L , GRASSELLI ROBERT K , KNIPPLE WARREN R
IPC: B01J21/00 , B01J23/16 , B01J23/18 , B01J23/644 , B01J23/68 , B01J23/843 , B01J27/18 , B01J37/00 , C07C5/48 , C07C45/35
CPC classification number: B01J21/00 , B01J23/16 , B01J23/18 , B01J23/6445 , B01J23/681 , B01J23/8435 , B01J27/1815 , B01J37/0009 , C07C5/48 , C07C45/35 , C07C253/26 , Y02P20/52 , Y10S502/503 , Y10S502/504 , Y10S585/906 , C07C11/167 , C07C47/22 , C07C255/08
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公开(公告)号：US3907859A
公开(公告)日：1975-09-23
申请号：US30065072
申请日：1972-10-25
Applicant: STANDARD OIL CO OHIO
Inventor： GRASSELLI ROBERT K , SURESH DEV D , MILLER ARTHUR F
IPC: B01J23/24 , B01J23/32 , B01J23/68 , B01J23/887 , B01J27/192 , C07C51/25 , C07C57/055 , C07C120/14 , C07C51/32 , C07C57/04
CPC classification number: C07C253/26 , B01J23/24 , B01J23/32 , B01J23/687 , B01J23/8876 , B01J27/192 , C07C51/252 , Y02P20/52 , C07C57/04 , C07C255/08
Abstract: High per pass conversions to acrylonitrile and acrylic acid or methacrylonitrile and methacrylic acid and desirable commercial flexibility are realized by reacting propylene or isobutylene with molecular oxygen and about 0.1 to about 0.9 moles of ammonia per mole of olefin in the presence of two catalysts. The first catalyst is an ammoxidation catalyst, and the second catalyst is an oxidation catalyst.
Abstract translation: 丙烯腈和丙烯酸或甲基丙烯腈和甲基丙烯酸的高通过转化率和所需的商业柔性通过在两种催化剂存在下使丙烯或异丁烯与分子氧和约0.1至约0.9摩尔氨/摩尔烯烃反应来实现。 第一催化剂是氨氧化催化剂，第二催化剂是氧化催化剂。
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