公开(公告)号：DE3169806D1

公开(公告)日：1985-05-15

申请号：DE3169806

申请日：1981-06-25

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  PAPARIZOS CHRISTOS ,  KUCH PHILIP LAWRENCE

IPC: C07C57/055 ,  B01J23/76 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/235 ,  C07C51/25 ,  C07C67/00 ,  B01J27/18 ,  B01J23/88 ,  C07C57/04

Abstract: Compositions of the empirical formula: Mo12P0.1-3M0.1-3Cu0.1-2V0.1-2X0.01-2YaOb (I) where M is at least one of K, Rb and Cs; X is at least one of Ba, La, Ga, Al, Ag, Cd, Ti, Tl, Hg, Pb and Zn; Y is at least one of Fe, Co, Ni, Sr, Mn, In, Ta, Ge, S and Be when a>0; a is a number of 0 to about 2; and b is a number that satisfies the valence requirements of the other elements present, are excellent catalysts for the oxidation of methacrolein to methacrylic acid.

公开(公告)号：DK146583C

公开(公告)日：1984-04-30

申请号：DK465074

申请日：1974-09-03

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT KARL ,  MILLER ARTHUR FRANCIS ,  SHAW WILFRID GARSIDE

IPC: C07C27/14 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/192 ,  B01J27/198 ,  B01J27/199 ,  C07B35/04 ,  C07B61/00 ,  C07C5/333 ,  C07C5/48 ,  C07C27/00 ,  C07C27/12 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C47/20 ,  C07C47/22 ,  C07C51/25 ,  C07C57/05 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J23/76 ,  C07C121/32

Abstract: Catalysts containing at least nickel or cobalt, chromium, bismuth and molybdenum have been found to be especially useful for the ammoxidation of olefins, the oxidation of olefins and the oxidative dehydrogenation of olefins.

公开(公告)号：DK146583B

公开(公告)日：1983-11-14

申请号：DK465074

申请日：1974-09-03

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT KARL ,  MILLER ARTHUR FRANCIS ,  SHAW WILFRID GARSIDE

IPC: C07C27/14 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/192 ,  B01J27/198 ,  B01J27/199 ,  C07B35/04 ,  C07B61/00 ,  C07C5/333 ,  C07C5/48 ,  C07C27/00 ,  C07C27/12 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C47/20 ,  C07C47/22 ,  C07C51/25 ,  C07C57/05 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J23/76 ,  C07C121/32

Abstract: Catalysts containing at least nickel or cobalt, chromium, bismuth and molybdenum have been found to be especially useful for the ammoxidation of olefins, the oxidation of olefins and the oxidative dehydrogenation of olefins.

公开(公告)号：FI63217C

公开(公告)日：1983-05-10

申请号：FI751394

申请日：1975-05-13

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT KARL ,  MILLER ARTHUR FRANCIS ,  SHAW WILFRID GARSIDE

IPC: C07C20060101 ,  C07C121/32 ,  C07C120/14

公开(公告)号：MX146730A

公开(公告)日：1982-08-04

申请号：MX16707474

申请日：1974-08-30

Applicant: STANDARD OIL CO

Inventor： GRASSELLI ROBERT KARL ,  MILLER ARTHUR FRANCIS ,  SHAW WILFRID GARSIDE

IPC: C07C3/00

公开(公告)号：AT363914B

公开(公告)日：1981-09-10

申请号：AT388379

申请日：1979-05-28

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  TERRILL DAVID BYERLY ,  MILBERGER ERNEST CARL ,  WOODBURY DAVID ROY ,  DOLHYJ SERGE ROMAN

IPC: C07D307/60 ,  B01J23/28 ,  B01J23/30 ,  B01J23/31 ,  B01J23/32 ,  B01J23/34 ,  B01J23/36 ,  B01J23/68 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00

公开(公告)号：AT363912B

公开(公告)日：1981-09-10

申请号：AT388179

申请日：1979-05-28

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  TERRILL DAVID BYERLY ,  MILBERGER ERNEST CARL ,  WOODBURY DAVID ROY ,  DOLHYJ SERGE ROMAN

IPC: B01J23/28

公开(公告)号：ATA388379A

公开(公告)日：1981-02-15

申请号：AT388379

申请日：1979-05-28

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  TERRILL DAVID BYERLY ,  MILBERGER ERNEST CARL ,  WOODBURY DAVID ROY ,  DOLHYJ SERGE ROMAN

IPC: C07D307/60 ,  B01J23/28 ,  B01J23/30 ,  B01J23/31 ,  B01J23/32 ,  B01J23/34 ,  B01J23/36 ,  B01J23/68 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00

公开(公告)号：AT359045B

公开(公告)日：1980-10-10

申请号：AT709477

申请日：1977-10-05

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES FERGUSON ,  SHAW WILFRID GARSIDE

IPC: C07C57/04 ,  B01J27/00 ,  B01J27/19 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  B01J27/18

Abstract: Coated catalysts having an inert support material with an outer surface and a coating of active catalyst containing molybdenum, phosphorus, arsenic, copper and oxygen have been found to be especially effective catalysts for the production of unsaturated acids from the corresponding unsaturated aldehydes, for example, methacrolein is oxidized to methacrylic acid using these catalysts. The catalysts give a very low exotherm, very high single pass yields of the desired acid and reduce the undesirable byproducts.

公开(公告)号：AT358533B

公开(公告)日：1980-09-10

申请号：AT320877

申请日：1977-05-05

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  TERRILL DAVID BYERLY ,  MILBERGER ERNEST CARL ,  WOODBURY DAVID ROY ,  DOLHYJ SERGE ROMAN

IPC: C07D307/60 ,  B01J23/28 ,  B01J23/30 ,  B01J23/31 ,  B01J23/32 ,  B01J23/34 ,  B01J23/36 ,  B01J23/68 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  B01J23/16