21.
    发明专利
    未知

    公开(公告)号:DE69214424D1

    公开(公告)日:1996-11-14

    申请号:DE69214424

    申请日:1992-11-26

    Abstract: Thermal decomposition of cycloalkanone oximes is inhibited by allowing nitrogen-containing compounds represented by the following formula (1) to coexist with the cycloalkanone oximes: NR1R2R3 (1> (wherein R1, R2 and R3 each represents a hydrogen atom or a lower alkyl group).

    26.
    发明专利
    未知

    公开(公告)号:DE69230820D1

    公开(公告)日:2000-04-27

    申请号:DE69230820

    申请日:1992-11-26

    Abstract: epsilon -Caprolactam is prepared by subjecting cyclohexanone oxime in a gas phase to a catalytic reaction using zeolite catalysts in the presence of water and at least one compound selected from alcohols and ether compounds.

    27.
    发明专利
    未知

    公开(公告)号:DE69214424T2

    公开(公告)日:1997-03-20

    申请号:DE69214424

    申请日:1992-11-26

    Abstract: Thermal decomposition of cycloalkanone oximes is inhibited by allowing nitrogen-containing compounds represented by the following formula (1) to coexist with the cycloalkanone oximes: NR1R2R3 (1> (wherein R1, R2 and R3 each represents a hydrogen atom or a lower alkyl group).

    28.
    发明专利
    未知

    公开(公告)号:DE69020172T2

    公开(公告)日:1995-12-07

    申请号:DE69020172

    申请日:1990-01-26

    Abstract: epsilon -caprolactam is produced by gas phase reaction of cyclohexanone oxime using a solid acid as a catalyst in the presence of a compound represented by the formula (I): R -O-R (wherein R represents a lower alkyl group which may be substituted with fluorine and R represents a hydrogen atom, a lower alkyl group or a phenyl group) such as a lower alcohol or an ether compound. The solid acid includes a crystalline metallosilicate or a crystalline silicate.

    Method for producing oxime
    30.
    发明专利
    Method for producing oxime 有权
    生产氧化物的方法

    公开(公告)号:JP2010024144A

    公开(公告)日:2010-02-04

    申请号:JP2008183467

    申请日:2008-07-15

    CPC classification number: C07C249/04 C07C2601/14 C07C251/44

    Abstract: PROBLEM TO BE SOLVED: To produce an oxime in a good selectivity and a good yield by performing the ammoximation reaction of a ketone with an organic peroxide and ammonia. SOLUTION: The method for producing the oxime by performing the ammoximation reaction of the ketone with the organic peroxide and ammonia in a reaction vessel, in a solvent and in the presence of a titanosilicate is characterized by supplying the ketone and ammonia into the reaction vessel in which the solvent, titanosilicate and organic peroxide are placed in advance, and performing the above reaction. As the ketone, a cycloalkanone is preferable. COPYRIGHT: (C)2010,JPO&INPIT

    Abstract translation: 待解决的问题:通过进行酮与有机过氧化物和氨的氨肟化反应,以良好的选择性和良好的产率制备肟。 解决方案:通过在反应容器中,在溶剂中和在钛硅酸盐存在下,通过进行酮与有机过氧化物和氨的氨肟化反应来制备肟的方法的特征在于将酮和氨供给到 反应容器,其中溶剂,钛硅酸盐和有机过氧化物预先放置,并进行上述反应。 作为酮,优选环烷酮。 版权所有(C)2010,JPO&INPIT

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