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公开(公告)号:JPH0912901A
公开(公告)日:1997-01-14
申请号:JP10660596
申请日:1996-04-26
Applicant: TORAY INDUSTRIES
Inventor: TAMURA SHINICHI , CHIBA KAZUMASA
Abstract: PROBLEM TO BE SOLVED: To obtain a thermoplastic resin composition excellent in chemical resistance and resistance to stress cracking without causing deformation of a molding by swelling, especially when brought into contact with a chemical. SOLUTION: In this thermoplastic resin composition comprising (A) a matrix resin component and (B) a disperse phase resin component, (i) the component A contains an amorphous resin component (a) and (ii) the component B contains a polymer (b) having =3.5 times by weight based on chemical absorbing amount of component A alone.
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公开(公告)号:JP2556119B2
公开(公告)日:1996-11-20
申请号:JP29489588
申请日:1988-11-22
Applicant: TORAY INDUSTRIES
Inventor: TANAKA SEIJI , IWAMOTO MASAAKI , CHIBA KAZUMASA
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公开(公告)号:JPH0853618A
公开(公告)日:1996-02-27
申请号:JP7520695
申请日:1995-03-31
Applicant: TORAY INDUSTRIES
Inventor: KOBAYASHI KAZUHIKO , KATAOKA SHIRO , CHIBA KAZUMASA
Abstract: PURPOSE:To suppress the formation of decomposition gases due to a flame retardant during molding by adding a specified total amount of a hydrotalcite and/or an inorganic compound containing Mg and Al to a flame-retardant polyamide resin composition of a specified composition. CONSTITUTION:This composition is obtained by adding 0.01-10 pts.wt., in total, hydrotalcite of formula I (wherein 0
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公开(公告)号:JPH07304914A
公开(公告)日:1995-11-21
申请号:JP9846794
申请日:1994-05-12
Applicant: TORAY INDUSTRIES
Inventor: TAMURA SHINICHI , TANAKA SEIJI , CHIBA KAZUMASA
Abstract: PURPOSE:To obtain a thermoplastic resin compsn. having excellent rigidity and impact resistance with improvements in the tensile toughness and chemical resistance of a thermoplastic styrene resin by blending the thermoplastic styrene resin with a modified polyolefin resin and a specific modified graft copolymer. CONSTITUTION:A thermoplastic resin compsn. comprises the following components [A] to [C]. The component [A] is a thermoplastic styrene resin. The component [B] is a modified polyolefin resin prepd. by grafting a polyolefin resin with an alpha,beta-unsatd. carboxylic acid or a deriv. thereof, the amt. of which is 0.1 to 15wt.%, based on the polyolefin resin. The component [C] is either a modified graft copolymer prepd. by graft copolymn. of a diene rubber with a monomer mixture of an oxazolyl group-contg. vinyl monomer and other copolymerizable monomer, or a modified graft copolymer compsn. comprising the above-mentioned modified graft copolymer and a copolymer of the remaining monomers. The blending ratio is such that [A]/[B]=-5/95 to 95/5 (wt. ratio) and the amt. of the component [C] is l-100 pts.wt. per 100 pts.wt. in total of the components [A] and [B].
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公开(公告)号:JPH07228738A
公开(公告)日:1995-08-29
申请号:JP1873994
申请日:1994-02-15
Applicant: TORAY INDUSTRIES
Inventor: TAMURA SHINICHI , TANAKA SEIJI , CHIBA KAZUMASA
Abstract: PURPOSE:To obtain a thermoplastic resin composition having good compatibility among components and excellent in impact resistance, tensile toughness, and rigidity by mixing a thermoplastic styrene resin with a modified polyolefin resin and a modified vinyl polymer having oxazolyl groups. CONSTITUTION:This composition comprises a thermoplastic styrene resin (A) (e.g. a rubber-reinforced styrene-resin), a modified polyolefin resin (B) obtained by grafting an alpha,beta-unsaturated carboxylic acid or a derivative thereof onto a polyolefin resin (b) (e.g. an ethylene/alpha-olefin copolymer rubber) in an amount of 0.1-15wt.% based on the resin (b), and a modified vinyl polymer (C) having oxazolyl groups, wherein the (A) to (B) ratio is 5/95 to 95/5 by weight and the amount of (C) is 1-100 pts.wt. per 100 pts.wt. the sum of (A) and (B). The component (C) is a copolymer of a vinyl monomer having an oxazolyl group (e.g. 2-propenyl-2-oxazoline with a copolymerizable vinyl monomer (e.g., acrylonitrile).
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公开(公告)号:JPH06248159A
公开(公告)日:1994-09-06
申请号:JP4012593
申请日:1993-03-01
Applicant: TORAY INDUSTRIES
Inventor: TAMURA SHINICHI , KAWAMURA TSUKASA , CHIBA KAZUMASA
Abstract: PURPOSE:To obtain the subject composition which has improved chemical resistance and excellent compatibility and can give a nondelaminating molding by mixing a specified graft copolymer with an aromatic polyester resin and a specified amount of a diene rubber. CONSTITUTION:This thermoplastic resin composition comprises 100 pts.wt. total of 50-95 pts.wt. graft copolymer prepared by polymerizing 90-15 pts.wt. monomer mixture comprising 10-50wt.% vinyl cyanide, 50-90wt.% aromatic vinyl and 0-20wt.% other copolymerizable vinyl monomers in the presence of 10-85 pts.wt. diene rubber or graft copolymer composition comprising this graft copolymer and a copolymer formed from the copolymerization of the residual monomer and 5-50 pts.wt. aromatic polyester resin consisting of a dicarboxylic acid component based on an aromatic dicarboxylic acid and a glycol component 10-90mol% of which comprises cyclohexanedimethanol, wherein the amount of the diene rubber is 1-50 pts.wt. based on the total composition.
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公开(公告)号:JPH066668B2
公开(公告)日:1994-01-26
申请号:JP24438984
申请日:1984-11-21
Applicant: TORAY INDUSTRIES
Inventor: CHIBA KAZUMASA
IPC: C08L77/00 , C08K5/54 , C08K5/5425 , C08K5/5435 , C08K5/544 , C08L77/06 , C08L81/04 , C08L83/04
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公开(公告)号:JPH05230301A
公开(公告)日:1993-09-07
申请号:JP3220592
申请日:1992-02-19
Applicant: TORAY INDUSTRIES
Inventor: TANAKA SEIJI , CHIBA KAZUMASA
Abstract: PURPOSE:To provide the subject olefin-based thermoplastic resin composition composed of a polyolefin, a polyether ester amide, an ethylene-based ionomer resin and a styrenesulfonic acid compound and exhibiting permanent antistatic properties. CONSTITUTION:The objective thermoplastic resin composition is composed of (A) a polyolefin, preferably polypropylene or polyethylene, (B) a polyether ester amide, preferably, e.g. one synthesized from caprolactam, polyethylene glycol and terephthalic acid, (C) an ethylene-based ionomer resin, preferably, e.g. one in which the metal ion is a 2n ion or Na ion and (D) a compound containing >=50wt.%, especially 100wt.% styrenesulfonic acid unit of the formula [R is H, an alkyl or an aryl; X is H, an alkaline(earth) metal or ammonium; n is an integer of 1 to 20000]. The weight ratio of (A/B) is (10 to 99)/(90 to 1) and (C) and (D) are contained each in an amount of 1 to 200 pts.wt. and 0.01 to 50 pts.wt. based on 100 pts.wt. total weight of (A) and (B).
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公开(公告)号:JPH05202239A
公开(公告)日:1993-08-10
申请号:JP1246692
申请日:1992-01-28
Applicant: TORAY INDUSTRIES
Inventor: TANAKA SEIJI , FUKUMOTO TADAO , CHIBA KAZUMASA
Abstract: PURPOSE:To obtain the title composition having permanent antistatic properties, not causing the exudation of the constituent polyether ester amide and excellent in mechanical properties. CONSTITUTION:The title composition comprises a polyolefin (A), a polyether ester amide (B) and a polyamide (C), wherein the weight ratio (A) to (B) is (10-99)/(90-1), and the amount of (C) added is 1-50 pts.wt. per 100 pts.wt. total of (A) and (B).
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公开(公告)号:JPH0522728B2
公开(公告)日:1993-03-30
申请号:JP13085484
申请日:1984-06-27
Applicant: TORAY INDUSTRIES
Inventor: KOBAYASHI KAZUHIKO , CHIBA KAZUMASA
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