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公开(公告)号:JPH07247380A
公开(公告)日:1995-09-26
申请号:JP4245294
申请日:1994-03-14
Applicant: TORAY INDUSTRIES
Inventor: HARADA YUTAKA , KIDA KENJI , TSUNASHIMA KENJI
Abstract: PURPOSE:To obtain a film having extremely high gas-barrier properties and excellent transparency. CONSTITUTION:The gas-barrier film has a layer comprising a polyalkyleneimine and a polymer having a styrenesulfonic acid unit represented by the formula (wherein R0, R1, R2, R3, and R4 each is hydrogen or methyl and M is a monovalent cation).
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公开(公告)号:JPH07207042A
公开(公告)日:1995-08-08
申请号:JP530194
申请日:1994-01-21
Applicant: TORAY INDUSTRIES
Inventor: KIDA KENJI , HARADA YUTAKA , TSUNASHIMA KENJI
Abstract: PURPOSE:To obtain a highly transparent oxygen barrier film which can be desirably used as especially a packaging material for foods and drugs which need to be stored for a long time. CONSTITUTION:This film is one having a barrier layer made of a polyester in which sulfonate-containing aromatic dicarboxylic acids account for at least 50mol% of the total dicarboxylic acid component, and aliphatic or alicyclic glycols account for at least 80 mol % of the total glycol component.
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公开(公告)号:JP2002166459A
公开(公告)日:2002-06-11
申请号:JP2000367246
申请日:2000-12-01
Applicant: TORAY INDUSTRIES
Inventor: HARADA YUTAKA , OKAZAKI IWAO , TSUNASHIMA KENJI
IPC: G02F1/1333 , B29C47/04 , C08J5/18 , C08K5/098 , C08K5/42 , C08L45/00 , C08L83/04 , C08L101/00 , C08L101/04
Abstract: PROBLEM TO BE SOLVED: To provide a method for manufacturing a thermoplastic resin film capable of being used as a liquid crystal element substrate having excellent optical characteristics. SOLUTION: In the method for manufacturing the thermoplastic resin film by laminating a thermoplastic resin B on both surfaces of a thermoplastic resin A with a glass transition temperature of >=150 deg.C in a peelable state by melt coextrusion and peeling the laminated thermoplastic resin B, at least one compound selected from polysiloxane, a metal salt of a fatty acid, alkyl sulfate and a fluorine modified polymer is added in an amount of 5-5,000 ppm to perform melt extrusion.
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公开(公告)号:JP2002069210A
公开(公告)日:2002-03-08
申请号:JP2000260461
申请日:2000-08-30
Applicant: TORAY INDUSTRIES
Inventor: TSUNASHIMA KENJI , HARADA YUTAKA , KONDO ATSUSHI
IPC: G02B5/30 , B29C43/20 , B29C47/04 , B29C47/88 , C08J5/18 , C08L67/00 , C08L69/00 , G02B1/04 , G02F1/1333
Abstract: PROBLEM TO BE SOLVED: To provide a low-cost isotropic sheet for optical use having no surface defect, optical isotropy, advanced gas barrier performance, high wear resistance, excellent conductivity, uniform in a quality and a method for manufacturing the same. SOLUTION: The isotropic sheet for optical use is 5 nm or less in retardation(Rd), 160 deg.C or higher in glass transition temperature, and 200 μ or more in thickness, and is manufactured by the melt extrusion of a laminated sheet BAB, wherein a polymer layer B is attached to both sides of an optical isotropic sheet-constituting polymeric resin layer A with the layers B peelable from the layer A, with the laminated sheet BAB to be closely attached to a cooling drum upon melt extrusion. In this method, the glass transition temperature Tgb of the layer B should be not lower than the glass transition temperature of the layer A (Tga-70) deg.C in the laminated sheet and the laminated sheet should be attached closely to the drum with its temperature kept at between (Tgb-50) deg.C or higher and (Tgb+30) deg.C or lower.
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公开(公告)号:JP2001180854A
公开(公告)日:2001-07-03
申请号:JP36665699
申请日:1999-12-24
Applicant: TORAY INDUSTRIES
Inventor: TSUNASHIMA KENJI , HARADA YUTAKA
Abstract: PROBLEM TO BE SOLVED: To provide a clip travel device capable of successively orienting a thermoplastic resin in the lengthwise direction and the width direction in a noncontact state for the purpose of manufacturing an oriented thermoplastic resin sheet with zero surface defect, excellent easy surface slidableness and easy surface adhesive property as well as to provide a heat treatment device using the clip device, an orientation and heat treatment method of the thermoplastic resin sheet or a manufacturing method of the thermoplastic resin sheet. SOLUTION: This clip traveling, heat treatment device using this device, orientation and heat treatment device of a thermoplastic resin sheet or a manufacturing method of the thermoplastic resin sheet are featured by being constituted so that clips having a structure allowing free traveling on a rail are detachably constituted in clip driving devices arranged at least in two places, and the clips are forcedly made to travel on the rail by being installed in the clip driving devices.
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公开(公告)号:JP2001048994A
公开(公告)日:2001-02-20
申请号:JP22739099
申请日:1999-08-11
Applicant: TORAY INDUSTRIES
Inventor: HARADA YUTAKA , TANAKA SHIGERU , NAGAI ITSUO
Abstract: PROBLEM TO BE SOLVED: To obtain a gas barrier film having gas barrier properties and transparency at a low humidity and a high humidity. SOLUTION: This gas barrier film is a film obtained by forming a coating film comprising inorganic laminar particles and a water-soluble polymer as main constituent components and having d (μm) coating film thickness on at least one side of a thermoplastic resin base. The number of surface projections of the thermoplastic resin base having height Hc (μm) in a range satisfying the formula Hc>=d-0.1 is
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公开(公告)号:JPH10323929A
公开(公告)日:1998-12-08
申请号:JP7632698
申请日:1998-03-24
Applicant: TORAY INDUSTRIES
Inventor: HARADA YUTAKA , KIMURA MASAHIRO , HASHIMOTO KOKICHI
Abstract: PROBLEM TO BE SOLVED: To provide gas barrier properties, extension barrier properties and adhesion with a base material even under high humidity by forming more than a plurality of layers comprising a cating layer which contains an inorganic tabular particle and a water-soluble polymer as constituent components and a layer comprising a metal oxide, on one of the faces of a thermoplastic resin base material. SOLUTION: A coating comprising a particle which forms a tabular particle of an extremely thin units crystal layer and a copolymer polyvinyl alcohol made up of polyvinyl alcohol with a degree of saponifiecation of 80 mol.% or more and a vinyl alcohol unit of 60% or more, is formed on one of the faces of a biaxially orientated thermoplastic base material. In addition, the moisture content of the coating is 3 mg/cm or less. Further, the formation of the coating on the surface of the layer comprising a metal and/or a metal oxide on one of the faces, is preferable from the viewpoint of gas barrier properties, adhesion, especially extension barrier properties and printability. The metal and the metal oxide to be preferably used are aluminum, silicon, zinc and magnesium.
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公开(公告)号:JPH10237188A
公开(公告)日:1998-09-08
申请号:JP3929297
申请日:1997-02-24
Applicant: TORAY INDUSTRIES
Inventor: HASHIMOTO KOKICHI , KIMURA MASAHIRO , HARADA YUTAKA
Abstract: PROBLEM TO BE SOLVED: To obtain the subject film capable of giving a film excellent in a gas barrier performance and secondary processability, by suppressing deformation due to heat and tensions on various kinds of processing treatments and smoothing the surface to which the vacuum-deposition is applied. SOLUTION: This non-oriented polyolefin film has an absolute dimensional change rate of =100nm in the number of observed with an interatomic microscope on the surface to be subjected to a vacuum deposition. An inorganic thin film, especially an aluminum thin film, is preferably vacuum-deposited to the film surface to be vacuum-deposited, and the obtained vacuum-deposited non-oriented film preferably has a steam permeability of and an oxygen permeability of
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公开(公告)号:JPH0939166A
公开(公告)日:1997-02-10
申请号:JP21660395
申请日:1995-08-02
Applicant: TORAY INDUSTRIES
Inventor: HARADA YUTAKA , KIMURA MASAHIRO , OSHIMA KATSUNORI
Abstract: PROBLEM TO BE SOLVED: To provide a gas barrier film having high gas barrier property even under high humidities. SOLUTION: In a film, a coat which contains a water soluble high polymer and a metallic fine particle is formed on at least one face of a thermoplastic resin base material. The coat is dried or treated with heat at a temperature ranging from 140 deg.C to a melting point of the thermoplastic resin base material in its forming process.
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公开(公告)号:JP2002338705A
公开(公告)日:2002-11-27
申请号:JP2001147469
申请日:2001-05-17
Applicant: TORAY INDUSTRIES
Inventor: HARADA YUTAKA , TSUNASHIMA KENJI
Abstract: PROBLEM TO BE SOLVED: To provide a thermoplastic resin film suitably used for a liquid crystal indication element. SOLUTION: The thermoplastic resin film comprises a thermoplastic resin A of which a melt resistivity is 1×10 Ω.cm or higher and a light ray transmittance ratio is 85% or higher. A film thickness of the film is 30 μm or higher and an electric charge is 0.001 C/m or higher.
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