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公开(公告)号：JPH10273554A
公开(公告)日：1998-10-13
申请号：JP1592398
申请日：1998-01-28
Applicant: TORAY INDUSTRIES
Inventor： MAKABE YOSHIKI , KITAJIMA NORIO , INOUE SHUNEI
Abstract: PROBLEM TO BE SOLVED: To obtain a resin compsn. which gives a molded article excellent in thin-wall flowability and mechanical properties and having a high vibration- damping capability, a smooth surface, and small variations in physical properties by compounding a liq.-crystalline resin with aluminum borate whisker having a particle size and a relative particle amt. satisfying a specific relation. SOLUTION: The liq.-crystalline resin (A) is a liq.-crystalline polyester, a liq.-crystalline polyesteramide, etc., capable of forming anisotropy when melted. A liq.-crystalline polyester is a polyester which have ethylenedioxy units as the essential units and comprises structural units represented by formulas I to IV (wherein R1 is at least one kind of a group selected from among groups represented by formula V; R2 is at least one kind of a group selected from among groups represented by formula VII; and X is H or Cl). The aluminum borate whisker (B) used has a particle size distribution (obtd. by laser diffraction) satisfying the relation: 7.5
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公开(公告)号：JPH09204951A
公开(公告)日：1997-08-05
申请号：JP1214796
申请日：1996-01-26
Applicant: TORAY INDUSTRIES
Inventor： NAKAMURA SEIICHI , KITAJIMA NORIO , INOUE SHUNEI
Abstract: PROBLEM TO BE SOLVED: To provide a connector excellent in dimensional precision and weld strength with little burr by molding a liquid crystalline resin composition obtained by blending a filler blended to a specified liquid crystalline resin which has a melt viscosity of a specified range by injection molding. SOLUTION: A liquid crystalline resin composition contains 0-400 parts by weight of a filler blended to 100 parts by weight of one or more liquid crystalline resins selected from liquid crystalline polyester and liquid crystalline polyester amide forming an anisotropic melting phase. This composition having a melt viscosity within the following condition range is injection molded, whereby a fine pitch connector molded product having a pitch space between terminals of 0.8mm or less. Temperature: melting point of liquid crystalline resin (Tm)+10 deg.C, nozzle size: nozzle diameter 1.0mmϕ, nozzle length: 10mm, (melt viscosity) the melt viscosity at a shear rate of 1200s is 200Pa.s or less, and the melt viscosity at a shear rate of 12s is 300-2500Pa.s.
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公开(公告)号：JPH04189863A
公开(公告)日：1992-07-08
申请号：JP31877390
申请日：1990-11-22
Applicant: TORAY INDUSTRIES
Inventor： OKAMOTO MASARU , KITAJIMA NORIO , INOUE SHUNEI
IPC: C08K5/5465 , C08K5/54 , C08K5/541 , C08K7/14 , C08L67/00
Abstract: PURPOSE:To obtain the title composition suitable for electrical and electronic parts, etc., having slight mechanical anisotropy and high weld strength by blending a thermotropic liquid crystal polyester with specific amounts of a filler and a specific isocyanate-based silane-containing compound. CONSTITUTION:(A) 100 pts.wt. thermotropic liquid crystal polyester shown by formula I to formula III or formula I to formula IV (Y is group shown by formula V, etc.; Z is group shown by formula VI, etc.) is blended with (B) 0-200 pts.wt., preferably 10-150 pts. wt. filler (e.g. glass fibers) and (C) 0.01-20 pts. wt., preferably 0.1-10 pts.wt. isocyanate-based silane-containing compound shown by formula VII (R is CH3 and/or C2H5; R is CH3; x is 2 and/ or 3).
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公开(公告)号：JPH04103656A
公开(公告)日：1992-04-06
申请号：JP22182890
申请日：1990-08-22
Applicant: TORAY INDUSTRIES
Inventor： KITAJIMA NORIO , OKAMOTO MASARU , ICHIKAWA YASUNORI
Abstract: PURPOSE:To obtain a composition having excellent heat resistance, moldability, fluidity, high mechanical strength, especially weld strength and excellent mechanical anisotropic by blending a liquid crystal polyester comprising specific structural units with a specific amount of glass fibers of different diameter structure. CONSTITUTION:(A) 99-20wt.%, preferably 95-30wt.% anisotropic melt phase- forming liquid crystal polyester comprising structural units shown by formula I, formula II and formula IV or formula I, formula II, formula III and formula IV (R1 is group shown by formula V, etc.; R2 is group shown by formula VI, etc.; X is chlorine or H; group shown by formula IV is in an equimolar amount with groups shown by formula II and formula III, having
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公开(公告)号：JPH0476050A
公开(公告)日：1992-03-10
申请号：JP18951590
申请日：1990-07-19
Applicant: TORAY INDUSTRIES
Inventor： OKAMOTO MASARU , KITAJIMA NORIO , ICHIKAWA YASUNORI
Abstract: PURPOSE:To prepare a resin molding having excellent specific strength, specific modulus, and impact strength and a low mechanical anisotropy by compounding a liq. crystalline polyester consisting of specific structural units with a high- molecular complex and a filler. CONSTITUTION:100 pts.wt. liq. crystalline polyester consisting of structural units of formulas I, II, and V and structural unit of formula III and/or structural unit of formula IV is compounded with 1-200 pts. wt. at least one high-molecular complex consisting of at least one arom. dicarboxylic acid constituting structural unit V and a divalent metal atom, and 0-150 pts.wt. filler are compounded. In formulas III and V, X represents at least one group selected from the group consisting of a group of formula VI, etc.; and Y, at least one group selected from the group consisting of a group of formula V, etc. The sum of molar amts. of structural units II, III, and IV is substantially the same as the molar amt. of structural unit V.
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Patent Agency Ranking
公开(公告)号：JPH0395259A
公开(公告)日：1991-04-19
申请号：JP23261389
申请日：1989-09-07
Applicant: TORAY INDUSTRIES
Inventor： ICHIKAWA YASUNORI , OKAMOTO MASARU , KITAJIMA NORIO
Abstract: PURPOSE:To obtain a resin composition which is excellent in heat resistance, flowability and sliding properties, gives a less anisotropic molded product, and is useful as a sliding material by mixing a specific thermotropic liquid crystal polyester with a fluororesin, a lubricant, etc. CONSTITUTION:The title resin composition is obtained by blending 100 pts.wt. thermotropic liquid crystal polyester comprising structural units of I-III [wherein X is phenylene, biphenylene, a dihydric diphenyl ether group, tetramentylbiphenylene, t-butylphenylene, tolylene, naphthylene, or ethylene; Y is phenylene, naphthylene, a divalent 2,2'-substituted diphenoxyethane residue (the substituent is H or Cl); and the amounts of the structural units II and III are equimolar] (deflection temperature under load: 190-280 deg.C), 0.5-50 pts. fluororesin and/or lubricant, and 5-100 pts. filler.
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公开(公告)号：JPS646239A
公开(公告)日：1989-01-10
申请号：JP8054888
申请日：1988-03-31
Applicant: TORAY INDUSTRIES
Inventor： MIYATA AKIRA , SAKURAI YUZO , KITAJIMA NORIO
Abstract: NEW MATERIAL:An optically active ether compound expressed by formula I (R1 is 4-18C alkyl or alkoxy; R2 is 2-10C alkyl; X is formula II or formula III; * is asymmetric carbon; m and n are 1 or 2) wherein one or two of ether one or both H of two kinds of aromatics different in position may be substituted by Cl or F. EXAMPLE:4'-n-Octyloxybiphenyl-4-carboxylic acid 4-[(R)-1-methyl-2-butoxyetho xy]phenylester. USE:A display element material. The aimed compound is chiral smectic C liquid crystal, especially exhibiting ferroelectricity, stable to water content and light, having excellent weather resistance as well as high speed responsibility. PREPARATION:A compound expressed by formula VII is reacted with a com pound expressed by formula VIII to afford a compound expressed by formula IX, which is subjected to catalytic hydrogenation to give a compound expressed by formula X. Then the compound expressed by formula X is reacted with a compound expressed by formula XII obtained by reacting a compound expressed by formula XI with SOCl to provide the compound expressed by formula I wherein X is formula II and n is 1.
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28.发明专利
公开(公告)号：JPS6345258A
公开(公告)日：1988-02-26
申请号：JP10041887
申请日：1987-04-23
Applicant: TORAY INDUSTRIES
Inventor： SAKURAI YUZO , KITAJIMA NORIO , HASEGAWA SAKIE
IPC: C07D213/80 , C09K19/34 , C09K19/42
Abstract: NEW MATERIAL:The optically active 6-substituted-pyridine-3-carboxylic acid ester compound of formula I (R is 2-14C alkyl; R2 is optically active alkyl). EXAMPLE:6-n-Octyloxypyridine-3-carboxylic acid 4'-[(S)-2-methylbutyloxycarbo nyl]4-biphenyl ester. USE:A liquid crystal substance stable against moisture and light, having excellent weather resistance and exhibiting chiral smectic C liquid crystal over a wide temperature range. PREPARATION:The objective compound of formula I can be produced by (1) heating and refluxing the compound of formula II and excess thionyl chloride for several hr, (2) distilling out unreacted thionyl chloride under reduced pressure and (3) reacting the resultant compound of formula III with the compound of formula IV in an aromatic hydrocarbon solvent such as benzene, toluene, etc., in the presence of an organic basic compound such as pyridine, triethylamine, etc., at room temperature or under heating for several hr.
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公开(公告)号：JPS62114935A
公开(公告)日：1987-05-26
申请号：JP25492085
申请日：1985-11-15
Applicant: TORAY INDUSTRIES
Inventor： ONISHI KOJI , SAKURAI YUZO , KITAJIMA NORIO
IPC: C07C69/88
Abstract: PURPOSE:To economically obtain the titled compound useful as a germicide, antifugal agent, etc., in high yield, by reacting 4-hydroxybenzoic acid with chlorine in methanol as a solvent and carrying out nuclear chlorination and esterification reaction in the same system. CONSTITUTION:1mol 4-hydroxybenzoic acid is dissolved in methanol in a molar amount of 5-40 times, preferably 10-20 times based on the 4-hydroxybenzoic acid and chlorinated with preferably 0.9-1.1mol, based on 1mol above-mentioned 4-hydrobenzoic acid, chlorine, preferably under ordinary pressure, preferably at 0-30 deg.C and subsequently esterified at 30-60 deg.C to carry out the nuclear chlorination and esterification reaction in the same system is one stage and afford the aimed compound. EFFECT:Since the methanol as a solvent acts also as a methyl esterifying agent and the reaction, isolation and purification can be carried out in one stage to simplify the isolation and purification stage, this method is industrially advantageous. USE:A raw material for high-performance polyester films having improved mechanical strength, etc.
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公开(公告)号：JPS61160054A
公开(公告)日：1986-07-19
申请号：JP16985
申请日：1985-01-07
Applicant: TORAY INDUSTRIES
Inventor： SAKURAI YUZO , HASEGAWA SAKIE , KITAJIMA NORIO
IPC: C08F220/00 , B01J20/283 , B01J20/291 , B01J20/32 , C07B31/00 , C07B57/00 , C07C67/00 , C08F30/00 , C08F30/08 , C08F220/10 , C08F220/56 , C08F230/08 , G01N30/88
Abstract: PURPOSE:To obtain a packing agent having not only good separation efficiency but also sufficient mechanical strength and easily adaptable to high performance chromatography and having excellent separation capacity even to a roughened plane compound, by fixing a copolymer consisting of a specific optically active monomer and a vinyl silane compound to a silica gel. CONSTITUTION:A copolymer, which consists of an optically active monomer represented by formula I (wherein R1 is phenyl, 1-naphthyl, 2-naphthyl or lower alkyl and phenyl and 1- or 2-naphthyl may have a substituent. R2 is lower alkyl, R3 is H or CH3 and * is asymmetric carbon) and a compound represented by formula II (wherein R4, R5 and R6 are alkyl, alkoxy, OH or halogen and one or more of R4, R5, R6 is alkoxy and halogen), is obtained so that the mol ratio of the compound represented by the formula I and the compound represented by the formula II is 0.5-80. This copolymer is fixed to a silica gel particle pref. having a uniform particle size and an average fine pore size of 100Angstrom or more. By this method, a packing agent excellent in the optical separation capacity of a wide range of a racemic mixture.
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