Abstract:
A thermoplastic polymer containing glutaric anhydride units of the following general formula (1) and having an absorbance at awavelength of 280 nm of at most 0.5 (the absorbance is a value of the polymer film having a thickness of 100 mu m, measured with a UV-visible spectrophotometer) and a glass transition temperature of not lower than 130 DEG C has high-level colorless transparency and good heat resistance, moldability and dwell stability. wherein R and R are the same or different and each represents a hydrogen atom or an alkyl group having from 1 to 5 carbon atoms.
Abstract:
The present invention provides a thermoplastic resin composition, which is excellent in low-temperature toughness and high-temperature creep characteristics, by a method for producing a thermoplastic resin composition by melt-kneading: (a) a polyphenylene sulfide resin, with (b) a polyetherimide resin or a polyethersulfone resin, wherein the thermoplastic resin composition contains 99 to 1% by weight of the component (a) and 1 to 99% by weight of the component (b) based on 100% by weight of the total amount of the component (a) and the component (b); the melt-kneading step is the step of melt-kneading by an extruder provided with an elongational flow zone which is a zone in which melt-kneading is performed while being allowed to undergo elongational flow; and a flow effect pressure drop before and after the elongational flow zone is from 50 to 1,000 kg/cm 2 .
Abstract:
A flame-retardant resin composition comprising 100 parts by weight of a rubber reinforced polystyrene resin, 0.1 to 20 parts by weight of an epoxidized phenolic resin, and 1 to 30 parts by weight of an aromatic phosphate is not impaired in the mechanical characteristics inherent in thermoplastic resin and has excellent flame retardance and light resistance.
Abstract:
An object of the invention is to provide a PPS resin composition having excellent heat resistance and excellent electrical properties without damaging excellent physical properties including mechanical properties and low gas generation which PPS intrinsically has. There is provided a resin composition comprising (a) a polyphenylene sulfide resin and (b) one or more copolymers selected among a tetrafluoroethylene/ hexafluoropropylene copolymer, an ethylene/ tetrafluoroethylene copolymer and a tetrafluoroethylene/ perfluoro(alkyl vinyl ether) copolymer. In the resin composition, (a) the polyphenylene sulfide resin forms a continuous phase, (b) one copolymer selected among the above components forms primary dispersed phases, and the primary dispersed phase includes secondary dispersed phases formed by a component different from the component of the primary dispersed phase.
Abstract:
PROBLEM TO BE SOLVED: To obtain a flame retardant polybutylene terephthalate resin composition for connectors excellent in injection moldability, heat and heat cycle resistances and flame retardance and using a nonhalogen-based flame retardant. SOLUTION: This composition is obtained by compounding (A) 100 pts.wt. of a polybutylene terephthalate with (B) 1-200 pts.wt. of a polycarbonate and/or a polyethylene terephthalate, (C) 0.1-75 pts.wt. of a phenol resin and/or a phenoxy resin, (D) 0.1-50 pts.wt. of a red phosphorus having 0.1-1,000 μS/cm electroconductivity (with the proviso that the electroconductivity is obtained by adding 100 mL of pure water to 5 g of the red phosphorus, carrying out extraction treatment at 121 deg.C for 10 h, filtering the red phosphorus and measuring the electroconductivity of extracted water prepared by diluting the resultant filtrate to 250 mL), (E) 1-200 pts.wt. of a fibrous reinforcing material, (F) 0-100 pts.wt. of a polyolefin resin, (G) 0-30 pts.wt. of an inorganic layer compound, (H) 0-10 pts.wt. of a fluorine-based resin, (I) 0-10 pts.wt. of a silicone-based compound, (J) 0-30 pts.wt. of a lubricant, (K) 0-30 pts.wt. of carbon black and (L) 0-10 pts.wt. of a hindered phenolic stabilizer and/or a phosphite-based stabilizer.
Abstract:
PROBLEM TO BE SOLVED: To obtain a flame retardant polybutylene terephthalate resin composition for coil bobbins excellent in flame retardance, dielectric breakdown voltage, heat and tracking resistances and impact strength and using a nonhalogen-based flame retardant. SOLUTION: This composition is obtained by compounding (A) 100 pts.wt. of a polybutylene terephthalate with (B) 1-200 pts.wt. of a polycarbonate and/or a polyethylene terephthalate, (C) 0.1-75 pts.wt. of a phenol resin and/or a phenoxy resin, (D) 0.1-50 pts.wt. of a red phosphorus having 0.1-1,000 μS/cm electroconductivity, (E) 1-200 pts.wt. of a fibrous reinforcing material, (F) a polyolefin resin, (G) an inorganic layer compound, (H) a fluorine-based resin, (I) a silicone-based compound, (J) a lubricant, (K) carbon black. and (L) a hindered phenolic stabilizer and/or a phosphite-based stabilizer.
Abstract:
PROBLEM TO BE SOLVED: To obtain a flame-retarded resin composition having high flame retardancy, tracking resistance, heat resistance, mechanical characteristics, and wet heat-resistant characteristics. SOLUTION: This flame-retarded resin composition comprises (A) 100 pts.wt. of polybutylene terephthalate resin, (B) 0.1-100 pts.wt. of a polycarbonate resin, (C) 0.01-30 pts.wt. of red phosphorus having an electric conductivity of 0.1-1,000 μS/cm (the electric conductivity of extracted water obtained by adding 100 mL of pure water to 5 g of red phosphorus, subjecting the mixture to an extraction treatment at 121 deg.C for 100 hr, filtering off the red phosphorus, and then diluting the filtrate into 250 mL of the diluted water), and (D) 0.1-50 pts.wt. of one or more metal salts selected from metal sulfates and metal silicates.
Abstract:
PROBLEM TO BE SOLVED: To provide a cylinder head cover which is capable of holding high mechanical strength and dimensional stability under a high temperature and further is excellent in durability for chemical such as calcium chloride at a high temperature by using specified polyketone resin. SOLUTION: An automobile cylinder head cover is formed by polyketone resin which is polyketone copolymer made of repeated units shown by expressions I, II and has 0.01 to 0.10 of y/x, preferably 0.05 to 0.10 or below when mole % of each polyketone copolymer shown by the expressions I, II in polymer is defined as each of x, y. If necessary, a fibrous and/or non-fibrous filling material 10 to 300 weight part may be blended in a polyketone resin 100 weight part and elastomer having a glass-transition temperature of 20 deg. or below, preferably olefine system elastomer may be blended in the polyketone resin 100 weight part.