TREATMENT OF HEAT RESISTANT RESIN COMPOSITION

    公开(公告)号:JP2000327775A

    公开(公告)日:2000-11-28

    申请号:JP13715599

    申请日:1999-05-18

    Abstract: PROBLEM TO BE SOLVED: To treat the subject composition by a method by which an edge part of the cross section of a pattern is hardly sagged, and more rectangular shape can be provided by heat-treating the pattern formed on a substrate out of a specific polymer under a specified condition. SOLUTION: A pattern formed out of a polymer consisting essentially of a structural unit of the formula (R1 is a tri- to octa-valent organic group having two or more carbon atoms; R2 is a di- to hexa-valent organic group having two or more carbon atoms; R3 is H, an alkali metal ion, ammonium ion or a 1-20C organic group; (m) is 3-100,000; (n) is 0-2; and (p) is 0-4 with the proviso that n+q is larger than 0) on a substrate is heat-treated at (T±10) deg.C [T is the boiling point ( deg.C) of the solvent included in the polymer under 1 atm] for >=10 min in the treating method. The polymer consisting essentially of the structural unit of the formula can be obtained, for example, by selectively combining a tetracarboxylic acid dianhydride with a diamine, and reacting them in an adequate polar solvent or a solvent consisting essentially of γ- butyrolactone.

    POSITIVE PHOTOSENSITIVE COMPOSITION

    公开(公告)号:JP2000241974A

    公开(公告)日:2000-09-08

    申请号:JP3847399

    申请日:1999-02-17

    Abstract: PROBLEM TO BE SOLVED: To control a developing time and to increase the adhesiveness of a composition with a substrate by preparing the composition from a polymer which is soluble with an alkali aqueous solution, a compound which generates an acid by irradiation of active actinic rays, and a compound having sulfone groups. SOLUTION: The positive photosensitive composition used contains a polymer which is soluble with an alkali aqueous solution, a compound which generates an acid by irradiation of active actinic rays, and a compound having sulfone groups. As for the alkali-soluble polymer, for example, a polyamide acid as a polyimide precursor or polyhydroxyamide as a polybenzoxazole precursor are preferably used. As for the compound which generates an acid by active actinic rays, especially a naphthoquinone diazide sulfonate is preferable. The compound having sulfone groups is added to control the dissolving rate and to increase the adhesiveness with a substrate. As for the compound, for example, benzene sulfonamide and toluene sulfonamide can be used.

    PHOTOSENSITIVE RESIN PRECURSOR COMPOSITION

    公开(公告)号:JP2000187317A

    公开(公告)日:2000-07-04

    申请号:JP28548299

    申请日:1999-10-06

    Abstract: PROBLEM TO BE SOLVED: To provide a positive heat resistant photosensitive resin precursor composition developable in an alkaline solution in a short time and small in film thickness reduction in development on unexposed areas by incorporating the specified polyimide precursor and the specified naphthoquinone diazide compound. SOLUTION: The photosensitive resin precursor composition comprises the polyimide polymer composed essentially of structural units represented by formula I and at least one of quinone diazide compounds represented by formula II and in formula I and II, R1 is a 3-8 valent and >=2 C organic group; R2 is a 2-6 valent and >=2 C organic group; R3 is an H atom or a 1-10 C organic group; (n) is an integer of 10-100,000; (m) is 1 or 2; each of (p) and (q) is 0, 1, 2, 3, or 4, and each is not 0 at the same time; (x) is 0, 1, or 2; and all of plural Qs are not 0 in one quinonediazide compound.

    HEAT RESISTANT RESIN COMPOSITION AND SEMICONDUCTOR DEVICE PREPARED BY USING THE SAME

    公开(公告)号:JP2001049118A

    公开(公告)日:2001-02-20

    申请号:JP22781399

    申请日:1999-08-11

    Abstract: PROBLEM TO BE SOLVED: To obtain a heat resistant resin composition low in decrease of film properties useful as an interlayer dielectric or the like in the semiconductor field by using a polymer having a specific structural unit and a photo acid generating agent or the like. SOLUTION: This heat resistant resin composition comprises (a) a polymer mainly comprising a structural unit expressed by the formula (R1 is a 2-8 valent C>=2 organic group; R2 is a 2-6 valent C>=2 organic group; R3 is H, an alkali metal ion, ammonium ion or a 1-20C organic group; m is an integer of 3-100,000; n is an integer of 0-2 and in the case of n=2 then R3 may be the same or different; p and q are each an integer of 0-4; p+q>0) and (b) a photo acid generating agent and/or a dissolution adjusting agent, and the thermal weight decreasing rate of the photo acid generating agent and the dissolution adjusting agent at 200 deg.C to 350 deg.C is

    PRECURSOR COMPOSITION OF POSITIVE TYPE PHOTOSENSITIVE RESIN

    公开(公告)号:JP2000143980A

    公开(公告)日:2000-05-26

    申请号:JP31474598

    申请日:1998-11-05

    Abstract: PROBLEM TO BE SOLVED: To obtain the subject composition capable of being developed by an alkali, and excellent in resolution by compounding a polyimide precursor having a specific structure, with a new quinonediazide compound. SOLUTION: This composition comprises (A) a polymer consisting essentially of a structural unit of formula I (R1 is a >=2C tri- to octa-valent organic group; R2 is a >=2C di- to hexa-valent organic group; R3 is H or a 1-20C organic group; n is 10-100,000; m is 0-2; p and q are each 0-4, with the proviso that both of p and q are not simultaneously 0), and (B) a quinonediazide compound of formula II (X is a group of formulas III or IV; R4 and R5 are each a 1-10C monovalent organic group; b and c are each 0-2 with the proviso that both of b and c are not simultaneously 0; d and e are each 0-2). The component A can be obtained, for example, by reacting a tetracarboxylic dianhydride with a diamine compound at a low temperature. The component B is preferably the one having a hydroxy-containing naphthalene skeleton bonded to the sulfonyl group of naphthoquinonediazide by an ester bond.

    PHOTOSENSITIVE RESIN PRECURSOR COMPOSITION

    公开(公告)号:JP2000119519A

    公开(公告)日:2000-04-25

    申请号:JP28956798

    申请日:1998-10-12

    Abstract: PROBLEM TO BE SOLVED: To obtain a photosensitive resin precursor composition developable with an alkali aqueous solution in a short time, having excellent viscosity stability of photosensitive varnish by making the composition include a polymer of a specific structure and a quinonediazidosulfonic acid ester compound. SOLUTION: This photosensitive resin precursor composition comprises a polymer of cyclic structure composed of a structure of formula I and/or formula II [R0 and R3 are each a 3-30C monofunctional (Si-containing) organic group; R1(OH)p is at least one group of formula III (R4 is a >=2C 4-8 functional organic group; (r) is 0-4) or formula IV (R5 is a >=2C 3-8 functional organic group; R6 is H or a 1-10C organic group; (s) is 0-4; (t) is 0-1) or the like; R2 is >=2C bifunctional to hexafunctional; (n) is 1-100; (p) and (q) are each 0-4] as a main component and a quinonediazidosulfonic acid ester compound.

Patent Agency Ranking