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公开(公告)号:JP2001181930A
公开(公告)日:2001-07-03
申请号:JP36473499
申请日:1999-12-22
Applicant: TORAY INDUSTRIES
Inventor: FUJIMORI MINORU , HASHIMOTO KOJI , UCHIDA MINORU
IPC: D01F6/84
Abstract: PROBLEM TO BE SOLVED: To solve a problem that a highly oriented fiber is excessively oriented to cause fuzzes, the breakage of the fiber, or the like, when drawn and false- twisted at a higher take-up speed than conventional take-up speeds. SOLUTION: This polyester raw fiber for drawing and false twisting is characterized by containing a phosphorus compound represented by the general formula (1) or (2) in an amount of 20 to 1,000 ppm as phosphorus atoms and having a birefringence of 0.08 to 0.16.
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公开(公告)号:JP2001172378A
公开(公告)日:2001-06-26
申请号:JP36204599
申请日:1999-12-21
Applicant: TORAY INDUSTRIES
Inventor: HONDA KEISUKE , UCHIDA MINORU , AOYAMA MASATOSHI
IPC: C08G63/78
Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a polyester at a higher productivity. SOLUTION: In a method for producing a polyester by the polycondensatin of a product formed by the esterification of a dicarboxylic acid with a diol, the molar ratio R1 (diol/dicarboxylic acid) of the diol to the dicarboxylic acid charged to be subjected to esterification is set at 1.10 or lower, and water in an amount of 10 wt.% or lower of the sum of the dicarboxylic acid and the diol is added when the mixture of the acid and the diol is prepared, thus enabling a polymer having a high degree of polymerization to be obtained in a shorter time.
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公开(公告)号:JP2001055634A
公开(公告)日:2001-02-27
申请号:JP2000165544
申请日:2000-06-02
Applicant: TORAY INDUSTRIES
Inventor: MOCHIZUKI KATSUHIKO , UCHIDA MINORU , MAEDA YUHEI
Abstract: PROBLEM TO BE SOLVED: To obtain the subject fiber as a conjugate yarn composed of a combination of two kinds of polyesters with the respective intrinsic viscosities(IV) satisfying specified relationships, improved in crimp developability under fabric restriction and crimp setting tendency, thereby capable of giving highly stretchable fabrics, by conjugate spinning of the above polyesters followed by conducting a drawing and heat-setting under specified conditions. SOLUTION: This highly crimpable polyester-based conjugate fiber with a U% of
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公开(公告)号:JP2000159984A
公开(公告)日:2000-06-13
申请号:JP33899998
申请日:1998-11-30
Applicant: TORAY INDUSTRIES
Inventor: UCHIDA MINORU , AOYAMA MASATOSHI
Abstract: PROBLEM TO BE SOLVED: To obtain a polyester composition good in thermal stability, transparency and polymer color tone, excellent in molding/forming processabilities, and useful for fibers, etc., by including specific phosphorus compound(s) and through polycondensation reaction without decline in the reactivity. SOLUTION: This polyester composition is obtained by including phosphorus compound(s) of formula I and/or II [R1 and R2 are each H, a 1-15C alkyl, phenyl, or the like; R3 is phenyl or a trivalent organic group; R4 and R5 are each carboxy, a hydroxyalkyl, or the like; R6 is (CH2)n (n is 2-4)] so as to be 20-1,000 ppm in the content based on the polyester polymer (calculated as phosphorus atom); wherein if an aromatic dicarboxylic acid or an ester-forming derivative thereof and a diol, or a low-molecular polyester oligomer is used as a starting material, it is preferable to incorporate the phosphorus compound(s) in the starting material.
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公开(公告)号:JPH09256221A
公开(公告)日:1997-09-30
申请号:JP7020996
申请日:1996-03-26
Applicant: TORAY INDUSTRIES
Inventor: UCHIDA MINORU , MAEDA YUHEI
Abstract: PROBLEM TO BE SOLVED: To provide the subject fibers having desired high dimensional stability, having high strength and excellent in durability by containing respectively a specific amount of a nickel compound and an antimony compound. SOLUTION: A polyester containing a nickel compound (e.g. nickel acetate) in an amount of 2-120ppm reduced to a nickel metal and an antimony compound (e.g. antimony trioxide) in an amount of 150-450ppm reduced to an antimony metal is fiberized and a total amount of intermediate elongation (elongation corresponding to 4.5g/d stress in a stress-strain curve; defined in this invention) and dry heat shrinkage (at 150 deg.C) is made to be 8-12% to obtain the objective polyester fiber.
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公开(公告)号:JPH09256220A
公开(公告)日:1997-09-30
申请号:JP7020796
申请日:1996-03-26
Applicant: TORAY INDUSTRIES
Inventor: UCHIDA MINORU , MAEDA YUHEI
Abstract: PROBLEM TO BE SOLVED: To provide the subject fibers having desired high dimensional stability, excellent in heat resistance, and capable of replacing rayon by containing respectively a specific amount of a nickel compound and an antimony compound. SOLUTION: A polyester containing a nickel compound (e.g. nickel acetate) in an amount of 2-120ppm reduced to a nickel metal and an antimony compound (e.g. antimony trioxide) in an amount of 150-450ppm reduced to an antimony metal is fiberized and a total amount of intermediate elongation (elongation corresponding to 4.5g/d stress in a stress-strain curve; defined in this invention) and dry heat shrinkage (at 150 deg.C) is made to
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公开(公告)号:JPH0466928B2
公开(公告)日:1992-10-26
申请号:JP27669586
申请日:1986-11-21
Applicant: TORAY INDUSTRIES
Inventor: ITO YOSHIMITSU , UCHIDA MINORU , MINEO MASANORI
IPC: C08G63/18 , C08G63/183 , C08G63/78 , D01F6/62 , D01F6/92
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公开(公告)号:JPH0226918A
公开(公告)日:1990-01-29
申请号:JP17536888
申请日:1988-07-13
Applicant: TORAY INDUSTRIES
Inventor: TAKAHASHI HIROSHI , UCHIDA KAZUO , UCHIDA MINORU
IPC: D01F6/92
Abstract: PURPOSE:To obtain the title woolly fiber outstanding in color tone, sliminess, flexibility and frictional characteristics by incorporating a polyethylene terephthalate-based polyester with a specified amount of a specific aliphatic monocarboxylic triglyceride. CONSTITUTION:The objective fiber can be obtained by incorporating (A) 100 pts.wt. of a polyester with ethylene terephthalate as the main recurring unit with (B) 0.1-10.0 (pref. 0.5-8.0) pts.wt. of an aliphatic monocarboxylic triglyceride of the formula (R1-R3 are each >=10C monocarboxylic residue) (pref. tallow hardened oil
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公开(公告)号:JPS62187726A
公开(公告)日:1987-08-17
申请号:JP2977286
申请日:1986-02-13
Applicant: TORAY INDUSTRIES
Inventor: UCHIDA MINORU , ITO YOSHIMITSU , TAKAHASHI HIROSHI
IPC: C08G63/68 , C08G63/692 , D01F6/62 , D01F6/92
Abstract: PURPOSE:To obtain the titled polyester which can give a high-strength and high-Young's modulus fiber even by a super-high-speed spinning process, by adding a small amount of a specified phosphonic acid compound in the stage before completion of the polycondensation reaction in the production of a polyester. CONSTITUTION:Phosphoric acid compounds of formulas I and/or II [wherein R1 is phenyl or a 1-4C alkyl, R2 and R3 are each ydroxyl group, a 1-15C alkyl, phenyl or the like, R4 is (CH2)n and n is 2-4], e.g., phenylphosphonic acid or a cyclic ester thereof with ethylele glycol) is prepared. A polyester for high-speed spinning is obtained by adding 0.01-1wt%, based on the acid component which constitutes the polyester, phosphonic acid compounds of formulas I and/or II to the reaction system in the stage before completion of the polycondensation reaction in producing a polyester by using terephthalic acid (esterifiable derivative) and etylene glcyol as principal materials.
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公开(公告)号:JP2001336027A
公开(公告)日:2001-12-07
申请号:JP2000157826
申请日:2000-05-29
Applicant: TORAY INDUSTRIES
Inventor: UCHIDA MINORU , AOYAMA MASATOSHI , OZAKI MISA
Abstract: PROBLEM TO BE SOLVED: To produce a polyester fiber for reinforcing a rubber, capable of substituting a rayon because of excellent dimensional stability and heat resistance in the rubber. SOLUTION: This polyester fiber for reinforcing the rubber is a polyester fiber containing the residue of a complex oxide in which its metal elements consist essentially of titanium and silicon, and is characterized in that the fiber is composed of a polyester containing 0.5-300 ppm titanium expressed in terms of titanium atom, and the dimensional stability [middle elongation (elongation at 4 cN/dtex) + heat shrinkage in dry air] is
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