23.
    发明专利
    未知

    公开(公告)号:DE69030314T2

    公开(公告)日:1997-08-14

    申请号:DE69030314

    申请日:1990-01-26

    Abstract: This invention relates to a composite semipermeable membrane of low-pressure high desalination type having an excellent chlorine resistance and a method for the production thereof. This membrane is composed of a microporous supporting membrane and an ultrathin membrane covering said supporting membrane, wherein the ultrathin membrane comprises a polyamide prepared by the polycondensation of a dicarboxylic acid halide with piperazine and ethylenediamine as the main component and a molar fraction of ethylenediamine polyamide constituents to piperazine polyamide constituents is regulated to be in the range of 0.01 to 0.25, so that the membrane has a high desalination rate, a high fresh water generation rate and a sufficient chlorine durability. Thus it can be used in a small ultrapure water generator and a household water purifier and as a reverse osmosis membrane for treating waste water or the like.

    24.
    发明专利
    未知

    公开(公告)号:DE69122934T2

    公开(公告)日:1997-04-03

    申请号:DE69122934

    申请日:1991-08-08

    Abstract: A composite semipermeable membrane which has a high electrolytes rejection even when the concentration of the electrolytes in feed water is very low and even if the pH of feed water is not less than 8 is disclosed. The composite semipermeable membrane of the present invention comprises a microporous substrate and a cross-linked polyamide-based ultra-thin membrane laminated on the microporous substrate, the ultra-thin membrane having a covalently bonded quaternary nitrogen atom.

    25.
    发明专利
    未知

    公开(公告)号:DK0503596T3

    公开(公告)日:1996-07-29

    申请号:DK92104191

    申请日:1992-03-11

    Abstract: A process of producing a composite semipermeable membrane with high performance, which does not involve a highly ignitable solvent or a chlorofluorocarbon solvent which destructs the environment is disclosed. In the process of the present invention, a polyfunctional amine solution and a polyfunctional acid halide solution in a hydrocarbon-based solvent with a flash point of not lower than 10 C are applied on a surface of a microporous substrate to allow interfacial polycondensation reaction so as to form a cross-linked polyamide-based ultra-thin membrane superposed on the microporous substrate. Then a gas is blown on the surface of the ultra-thin membrane so as to evaporate the hydrocarbon-based solvent, which gas has a velocity at the surface of 2 - 20 m/sec., a temperature of 10 - 80 C that is lower than the flash point of the hydrocarbon-based solvent, and an absolute humidity of not less than 1 g of water per 1 kg of dry gas.

    PROCESS FOR PRODUCING COMPOSITE SEMIPERMEABLE MEMBRANE

    公开(公告)号:CA2062638A1

    公开(公告)日:1992-09-13

    申请号:CA2062638

    申请日:1992-03-11

    Abstract: A process of producing a composite semipermeable membrane with high performance, which does not involve a highly ignitable solvent or a chlorofluorocarbon solvent which destructs the environment is disclosed. In the process of the present invention, a polyfunctional amine solution and a polyfunctional acid halide solution in a hydrocarbon-based solvent with a flash point of not lower than 10.degree.C are applied on a surface of a microporous substrate to allow interfacial polycondensation reaction so as to form a cross-linked polyamide-based ultra-thin membrane superposed on the microporous substrate. Then a gas is blown on the surface of the ultra-thin membrane so as to evaporate the hydrocarbon-based solvent, which gas has a velocity at the surface of 2 - 20 m/sec., a temperature of 10 - 80.degree.C that is lower than the flash point of the hydrocarbon-based solvent, and an absolute humidity of not less than 1 g of water per 1 kg of dry gas.

    30.
    发明专利
    未知

    公开(公告)号:DE69211731T2

    公开(公告)日:1996-10-31

    申请号:DE69211731

    申请日:1992-03-11

    Abstract: A process of producing a composite semipermeable membrane with high performance, which does not involve a highly ignitable solvent or a chlorofluorocarbon solvent which destructs the environment is disclosed. In the process of the present invention, a polyfunctional amine solution and a polyfunctional acid halide solution in a hydrocarbon-based solvent with a flash point of not lower than 10 C are applied on a surface of a microporous substrate to allow interfacial polycondensation reaction so as to form a cross-linked polyamide-based ultra-thin membrane superposed on the microporous substrate. Then a gas is blown on the surface of the ultra-thin membrane so as to evaporate the hydrocarbon-based solvent, which gas has a velocity at the surface of 2 - 20 m/sec., a temperature of 10 - 80 C that is lower than the flash point of the hydrocarbon-based solvent, and an absolute humidity of not less than 1 g of water per 1 kg of dry gas.

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