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公开(公告)号：JP2011116885A
公开(公告)日：2011-06-16
申请号：JP2009276658
申请日：2009-12-04
Applicant: Ube Industries Ltd , 宇部興産株式会社
Inventor： MAEDA SHUICHI , NAKAGAWA TOMOYUKI , KURACHI KOICHIRO , OKUSHITA YOJI
Abstract: PROBLEM TO BE SOLVED: To provide a polyamide resin composition for an IC tray which, while having low water absorbency, achieves a sufficiently high molecular weight, has a wide moldable temperature range calculated from the difference between the melting point and the thermal decomposition temperature thereof, has excellent melt moldability and excellent electrical conductivity, and is more excellent in heat resistance, chemical resistance, hydrolysis resistance and the like as compared with conventional aliphatic polyamide resins. SOLUTION: The polyamide resin composition for an IC tray contains an electrical conductivity-imparting agent in a polyamide resin wherein the dicarboxylic acid component is composed of oxalic acid and the diamine component is composed of a mixture of 1,9-nonanediamine and 2-methyl-1,8-octanediamine (hereinafter called a C9 diamine mixture) and 1,6-hexanediamine (hereinafter called C6 diamine). The molar ratio between the C9 diamine mixture and C6 diamine is from 1:99 to 99:1. COPYRIGHT: (C)2011,JPO&INPIT
Abstract translation: 解决方案：为了提供一种IC托盘的聚酰胺树脂组合物，其具有低吸水性，达到足够高的分子量，具有从熔点和热量之间的差异计算的宽的成型温度范围 其分解温度优异，熔融成型性和导电性优异，与常规的脂肪族聚酰胺树脂相比，耐热性，耐化学性，耐水解性等优异。 解决方案：用于IC托盘的聚酰胺树脂组合物在聚酰胺树脂中含有导电性赋予剂，其中二羧酸组分由草酸组成，二胺组分由1,9-壬二胺和 2-甲基-1,8-辛二胺（以下称为C9二胺混合物）和1,6-己二胺（以下称为C6二胺）。 C9二胺混合物和C6二胺的摩尔比为1:99至99:1。 版权所有（C）2011，JPO＆INPIT
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公开(公告)号：JP2011063695A
公开(公告)日：2011-03-31
申请号：JP2009214596
申请日：2009-09-16
Applicant: Ube Industries Ltd , 宇部興産株式会社
Inventor： NAKAGAWA TOMOYUKI , OKUSHITA YOJI , MAEDA SHUICHI , KURACHI KOICHIRO , SHIMOKAWA MASAHITO
IPC: C08G69/26
Abstract: PROBLEM TO BE SOLVED: To provide a transparent member using a polyamide resin excellent in chemical resistance, hydrolysis resistance, and the like, particularly excellent in transparency, as compared with a conventional aliphatic polyamide resin, without impairing low water absorption properties seen in a linear aliphatic polyoxamide resin.
SOLUTION: The transparent member using a polyamide resin, which has a high molecular weight, is excellent in melt molding properties due to a large difference between the melting point and thermal decomposition temperature, and is excellent in chemical resistance and hydrolysis resistance, particularly excellent in transparency as compared with a conventional aliphatic polyamide resin, without impairing low water absorption properties seen in a linear aliphatic polyoxamide resin, can be obtained by using an oxalic acid diester as a source of oxalic acid and using, as a diamine component, a mixture of 1,9-nonane diamine and 2-methyl-1,8-octane diamine, wherein the molar ratio of 1,9-nonane diamine to 2-methyl-1,8-octane diamine is 40:60 to 99:1.
COPYRIGHT: (C)2011,JPO&INPITAbstract translation: 要解决的问题：与传统的脂族聚酰胺树脂相比，使用聚酰胺树脂的耐化学性，耐水解性等优异的透明性的透明构件，而不损害所观察到的低吸水性 在线性脂族聚酰胺树脂中。 解决方案：使用具有高分子量的聚酰胺树脂的透明构件由于熔点和热分解温度之间的差异而具有优异的熔体模塑性能，并且具有优异的耐化学性和耐水解性， 与常规脂肪族聚酰胺树脂相比，透明度特别优异，不损害线性脂肪族聚酰胺树脂中所见的低吸水性，可以通过使用草酸二酯作为草酸源，并使用二胺成分， 1,9-壬二胺和2-甲基-1,8-辛二胺的混合物，其中1,9-壬二胺与2-甲基-1,8-辛二胺的摩尔比为40:60至99:2。 1。 版权所有（C）2011，JPO＆INPIT
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23.发明专利Method for controlling molecular weight of polyoxamide resin and polyoxamide resin 审中-公开控制聚酰胺树脂和聚酰胺树脂分子量的方法
公开(公告)号：JP2011063694A
公开(公告)日：2011-03-31
申请号：JP2009214595
申请日：2009-09-16
Applicant: Ube Industries Ltd , 宇部興産株式会社
Inventor： SHIMOKAWA MASAHITO , OKUSHITA YOJI , ISOBE NORIYUKI , MAEDA SHUICHI , KURACHI KOICHIRO , NAKAGAWA TOMOYUKI
IPC: C08G69/28
Abstract: PROBLEM TO BE SOLVED: To provide a method for controlling the molecular weight of a polyoxamide resin, which conventional production methods of the polyoxamide resin failed to achieve.
SOLUTION: In the production method to obtain the polyoxamide resin by a polycondensation reaction of a diester of oxalic acid and a diamine, the method for controlling the molecular weight of the polyoxamide resin sets the temperature of contents upon initiation of mixing of raw materials to a predetermined temperature within the range of 20-240°C according to the target molecular weight.
COPYRIGHT: (C)2011,JPO&INPITAbstract translation: 待解决的问题：提供一种控制聚酰胺树脂的分子量的方法，其中聚酰胺树脂的常规生产方法未能实现。 解决方案：在通过草酸二胺的缩聚反应获得聚酰胺树脂的制备方法中，用于控制聚酰胺树脂的分子量的方法设定了原料混合开始时的内容物的温度 材料根据目标分子量在20-240℃的范围内达到预定温度。 版权所有（C）2011，JPO＆INPIT
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公开(公告)号：JP2001234066A
公开(公告)日：2001-08-28
申请号：JP2000047458
申请日：2000-02-24
Applicant: UBE INDUSTRIES
Inventor： HIRANO TETSUHARU , TANAKA SHOICHI , OKUSHITA YOJI
Abstract: PROBLEM TO BE SOLVED: To obtain a polyamide resin composition having a slow crystallizing rate and good drawability while hardly causing the reduction of the melting point of the polyamide component constituting the main component. SOLUTION: This polyamide resin composition comprises 100 pts.wt. polyamide resin and 0.05-10 pts.wt. rhodinic acids.
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公开(公告)号：JP2001129371A
公开(公告)日：2001-05-15
申请号：JP31845499
申请日：1999-11-09
Applicant: UBE INDUSTRIES
Inventor： YOSHIKAWA MASAKAZU , MURAKAMI AKIRA , OKUSHITA YOJI
Abstract: PROBLEM TO BE SOLVED: To provide a membrane containing agar and/or agarose and having a small dispersion of membrane thickness and a good surface smoothness, and its manufacturing method. SOLUTION: A mixture formed by adding sericin to a compound containing agar and/or agarose, and water as occasion demands is made into a sheet-like gel. Thereafter, while a load of 0.01-2 kgf/cm2 is applied to the sheet-like gel, the sheet-like gel is dried at 0-40 deg.C to obtain a membrane containing the agar and/or the agarose. A porous material and/or a water absorbing material are laminated on one side or both sides of the sheet-like gel comprising the mixture which contains the compound containing the agar and/or the agarose and the cericin. The laminate gel and material are dried at 0-40 deg.C while a load is being applied. Thereafter, by removing the porous material and/or the water absorbing material, the membrane containing the agar and/or the agarose can be more effectively manufactured.
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Patent Agency Ranking
公开(公告)号：JP2001002779A
公开(公告)日：2001-01-09
申请号：JP17494499
申请日：1999-06-22
Applicant: UBE INDUSTRIES
Inventor： OKUSHITA YOJI , TANAKA SHOICHI
Abstract: PROBLEM TO BE SOLVED: To provide a polyamide having excellent drawability and especially suitable for successive biaxial drawing. SOLUTION: The objective polyamide contains a unit composed of a lactam and/or an aminocarboxylic acid, a unit composed of a dicarboxylic acid and a unit composed of a diamine containing norbornanediamine. Concretely, the polyamide contains 50-99.8 mol% lactam and/or aminocarboxylic acid, 0.1-25 mol% dicarboxylic acid and 0.1-25 mol% diamine. Norbornanediamine accounts for 10-100 mol% of the diamine.
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公开(公告)号：JP2000239375A
公开(公告)日：2000-09-05
申请号：JP1775899
申请日：1999-01-27
Applicant: UBE INDUSTRIES
Inventor： TANIOKA RIKIO , TANAKA SHOICHI , OKUSHITA YOJI
Abstract: PROBLEM TO BE SOLVED: To obtain a polyamide excellent in stretchability especially successive biaxial stretchability. SOLUTION: This polyamide comprises a diamine and a dicarboxylic acid including a 6-22C branched and saturated carboxylic acid as essential components. The preferable composition is 50-99.95 mol% lactam and/or aminocarboxylic acid, 0.025-25 mol% diamine and 0.025-25 mol% dicarboxylic acid wherein 5-100 mol% of the dicarboxylic acid is a 6-22C branched and saturated carboxylic acid. As the 6-22C branched and saturated carboxylic acid, 1,6-decanedicarboxylic acid is preferable.
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公开(公告)号：JP2000001544A
公开(公告)日：2000-01-07
申请号：JP9319299
申请日：1999-03-31
Applicant: UBE INDUSTRIES
Inventor： OKUSHITA YOJI , AMANE TAKASHI
Abstract: PROBLEM TO BE SOLVED: To provide a polyamide resin which can give a molding undergoing little change in its transparency and shape even when subjected to treatment with boiling water for a long time. SOLUTION: This resin a polyamide resin comprising units derived from (A) a dicarboxylic acid and units derived from (B) a diamine, wherein the carboxylic acid A comprises 50-100 mol.% units derived from (A-1) a 6-22C branched saturated dicarboxylic acid and 0-50 mol.% units derived from (A-2) isophthalic acid, and diamine B is a diamine represented by the formula [wherein R1 is a hydrocarbon group of the formula: CnH2n (wherein n=1-3); and R2 and R3 are each H or hydrocarbon group of the formula: CnH2n+1 (wherein n=1-3)], and the ratio of the number of moles of (A) to the number of moles of (B) is 100:95 to 100:105, or a polyamide resin comprising units derived from (C) an aliphatic aminocarboxylic acid and/or a lactam and units A and B, wherein C is used in an amount of above 0 to below 30 mol per 100 mol of the total of A and B.
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公开(公告)号：JPH10292042A
公开(公告)日：1998-11-04
申请号：JP10153397
申请日：1997-04-18
Applicant: UBE INDUSTRIES
Inventor： OKUSHITA YOJI , MIURA TADASHI , FUJIMURA HIDEKI , AMANE TAKASHI
Abstract: PROBLEM TO BE SOLVED: To obtain a polyamide which does not become cloudy in heat treatment, is excellent in clarity, and is soluble in a lower alcohol, etc., by selecting a polyamide comprising units derived from a dicarboxylic acid component mainly comprising 1,6-decanedicarboxylic acid, units derived from a diamine component, and units derived from an aliph. aminocarboxylic acid component and/or units derived from a lactam component. SOLUTION: This polyamide is produced by a two-stage polymn. process comprising the first polymn. step conducted at 160-320 deg.C under 0-50 kgf/cm G to produce a polyamide prepolymer having a number average mol. wt. of 800-5,000 and the second polymn. step conducted at 160-320 deg.C under 10-760 mmHg to produce a polyamide having a number average mol.wt. of 7,000-50,000. 50-100 wt.% of the dicarboxylic acid component is 1,6-decanedicarboxylic acid. An example of the diamine used is 1,4-diaminobutane; that of the aliph. aminocarboxylic acid, ε-aminocaproic acid; and that of the lactam, ε- caprolactam.
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公开(公告)号：JPH09316193A
公开(公告)日：1997-12-09
申请号：JP13855696
申请日：1996-05-31
Applicant: UBE INDUSTRIES
Inventor： OKUSHITA YOJI , MIURA TADASHI , FUJIMURA HIDEKI , AMANE TAKASHI
Abstract: PROBLEM TO BE SOLVED: To obtain a process for producing a polyamide which has m- xylylenediamine units as essential units, does not gel nor yellow, and has a homogeneous quality and a good film-forming properties by using specific components. SOLUTION: An oligomer having a number average mol.wt. of 1,000 or higher and comprising 25-50mol% diamine units comprising 20-100mol% units derived from m-xylylenediamine and 0-80mol% units derived from an aliph. and/or alicyclic diamine having a 4-18C alkylene group, 25-50mol% dicarboxylic acid units comprising 10-80mol% units derived from an arom. dicarboxylic acid represented by the formula (wherein Ar is a 6-14C arom. hydrocarbon group) and 20-90mol% units derived from a 6-18C linear aliph. dicarboxylic acid, and 0-50mol% 4-12C aliph. ω-aminocarboxylic acid units is produced by the prepolymn. at 220 deg.C or lower. The oligomer is subjected to melt polymn. at a temp. at least 10 deg.C higher than the m.p. of the resulting polymer but not higher than 280 deg.C and/or is subjected to solid phase polymn. at a temp. not lower than the glass transition point of the polymer but at least 10 deg.C lower than the m.p.
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