公开(公告)号：KR820000487B1

公开(公告)日：1982-04-08

申请号：KR780001637

申请日：1978-05-30

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER N

IPC: B01J27/14

Abstract: Catalysts for oxidn. of C4 hydrocarbons to maleic anhydride(I) are prepd. by reducing V(V) compds., heating the aq. product with P(V) compds. at >120oC, drying, and calcining at 250-600oC, preferably in the presence of 0. Thus, 36.37g V2O5, 22.4 g black UOx, and 50 mL H2O are ball-milled 3 h, mixed with 600 mL H2O and 12.26 g W(particle size

公开(公告)号：KR810001374B1

公开(公告)日：1981-10-17

申请号：KR780002317

申请日：1978-07-28

Applicant: STANDARD OIL CO

Inventor： FITZGIBBONS W ,  WU HSIN CHIH

IPC: B01D3/40

Abstract: Acrylonitrile or methacrylonitrile was manufd. by the ammoxidn. of propylene or isobutylene and recovered from the reaction mixt. by contacting the product stream with a guenching liq. which forms a gaseous stream, absorbing the gas in water to form a soln. and distg. the soln. to recover acetonitrile by removing the major part of the byproduct and water. The bottom flow from the distn. column is recycled and used at least a part of the quenching liq.

公开(公告)号：KR810001298B1

公开(公告)日：1981-10-13

申请号：KR780003648

申请日：1978-12-04

Applicant: STANDARD OIL CO

Inventor： WAGNER D

IPC: C07C57/04

Abstract: An aq. soln. obtained from the oxidn. of propylene comprising 55% acrylic acid, water, HOAc, and impurities were fed into the top of a first column, contacted countercurrently with diisopropyl ether, and the ext. contg. 19% acrylic acid and 1 % HOAc was removed at the top. The stream was passed to the 15th stage of a 19stage solvent recovery column, the bottom was reboiled to provide the heat for distn., and an overhead contg. solvent, water, HoAc was removed and condensed. A vapor stream from the 7th stage was passed to the bottom of a column, HOAc was removed. By removal of the HOAc in this manner, a bottom stream of 99.9% acrylic acid could be recovered

公开(公告)号：KR800001503B1

公开(公告)日：1980-12-19

申请号：KR800002489

申请日：1980-06-24

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW W ,  TERRILL D

IPC: B01J23/16

公开(公告)号：KR800001414B1

公开(公告)日：1980-12-05

申请号：KR760000934

申请日：1976-04-16

Applicant: STANDARD OIL CO OHIO

Inventor： DOLHY S ,  BRIDGEMAN D ,  MILBERGER E

IPC: B01J12/00 ,  C07C27/14 ,  C07C47/20

Abstract: Unsaturated aldehyde and acid were manufd. by using 2 types of catalysts and controlling oxidation temp. in the fixed bed reactor. The first catalyst consists of partially porous inert supports and coated catalyst adhered to the outer surface of the supports, the second catalyst composed of catalyst materials. The first catalyst was reacted with reactants in the fixed bed reactor tube, and then the second catalyst was reacted with reactants. By above method, propylene or isobutylene were reacted with oxygen mixture in fixed bed to give the corresponding aldehyde or acid.

公开(公告)号：KR800000727B1

公开(公告)日：1980-07-30

申请号：KR770001085

申请日：1977-05-04

Applicant: STANDARD OIL CO OHIO

Inventor： CARLMILBERGER E ,  SHAW W ,  TORRILL D

IPC: B01J23/16

Abstract: Catalyst MoaVbSbcXdYeOf(x = Ag, Mg, Tl, Cd; Y= Mn, Co, Ni, Cu, Fe, Sn, Cr, Ti, Bi, As, P, Re, Zn), where a = 6-18, b = 0.1-6, c = 0.1-6, d = 0.01-6, e = 0-6, and f takes oxigen no. needed to satisfy valance requirements, was used in the preparation of unsatd. aliphatic acids from unsatd. aldehyde.

公开(公告)号：KR800000283B1

公开(公告)日：1980-04-10

申请号：KR750002078

申请日：1975-09-19

Applicant: STANDARD OIL CO

Inventor： COFFEY G

IPC: C08F220/44

Abstract: Residual t-butylmercaptan was removed from latexes of nitrile polymers (styrene, acrylonitrile, metacrylonitrile) contg. unpolymd.nitriles by stirring the latex for min-4hr at 15-75≦̸ and pH 9.5-10.5. The pH was adjusted by an aq. soln. of hydroxide ion of a metal selected from the Groups IA, IB, IIA. and IIB of the periodic table at 20-60≦̸C for 20-60min.

公开(公告)号：KR800000075B1

公开(公告)日：1980-01-30

申请号：KR760002360

申请日：1976-09-22

Applicant: STANDARD OIL CO

Inventor： PARTENHEIMER W

IPC: B01J21/20

Abstract: The P-V-O complex catalysts used for the oxidn. of hydrocarbons, esp. for the prodn. of maleic anhydride(I) from butane were reactivated by treatment with hydrogen halide b.p 250≦̸C. Thus, a catalyst having P-V at ratio 1.2 and V-Zn promoter at ratio 0.2 was used to oxidize butane at 450≦̸C, giving initial conversion 83% and I selectivity 62%, and conversion and selectivity 94% and 27%, after 18 hr. The catalyst was treated with CCl4 for 30min at 400≦̸C by adding the gaseous compd. to the butane-air feed at the normal residence time.

公开(公告)号：KR790001355B1

公开(公告)日：1979-09-28

申请号：KR750000006

申请日：1975-01-04

Applicant: STANDARD OIL CO OHIO

Inventor： ERNEST CARL MILBERGER ,  SERGE ROMAN DOLHYJ ,  NOEL JEROME BREMER

Abstract: A catalyst for the prepn. of acrylic acid from acrolein and the prepn. of methacrylic acid from methacrolein consists of U and (or) Th, W, V, and Mo oxides, and a small amt. of other metals. Thus, U2W1.2V3Mo12Ox was prepd. from an aq. suspension contg. MoO3,V2O5, and W powder which was refluxed 1hr and then treated with aq. UO2(OAc)2.2H2O.

公开(公告)号：KR790001046B1

公开(公告)日：1979-08-22

申请号：KR740002200

申请日：1974-04-16

Applicant: STANDARD OIL CO

Inventor： BOONE D E ,  FOTIS P JR

Abstract: Polymn. catalysts for ethylene were prepd. by reaction of magnesium trichloroacetate with AlCl3 and Ti or V salts, e.g., TiCl4. Thus, a mix, of 7.1g I and 5.1g AlCl3 was heated for 21hr at 100≦̸C and ground for 23hr to give a fine powder. This powder (2g) was heated with 2ml TiCl4 in xylene for 17hr at 100≦̸C to give a solid catalyst.