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公开(公告)号：KR1020030030421A
公开(公告)日：2003-04-18
申请号：KR1020010062556
申请日：2001-10-11
Applicant: 제일모직주식회사
IPC: C08L55/02
CPC classification number: C08L55/02 , C08J2300/22 , C08K5/523 , C08K5/56 , C08K2201/003 , C08L71/12 , C08L2201/02
Abstract: PURPOSE: Provided is a fire-retardant, thermoplastic resin composition which shows substantially improved fire retardancy without using a flame retardant, and uses phosphoric ester compound and organic titanium compound as a flame retardant. CONSTITUTION: The composition comprises (A) 40-100 parts by weight of resin based on rubber modified styrene consisting of (a1) 20-90 wt% of styrene-containing graft copolymer resin having 10-68 parts by weight of rubber component, and 18-65 wt% of unsaturated nitrile-based monomer except for rubber component, and (a2) 10-80 wt% of styrene-containing copolymer resin having 18-65 wt% of unsaturated nitrile-based monomer; (B) 0-60 parts by weight of polyphenylene ether resin; (C) 1-30 parts by weight of aromatic phosphoric ester with respect to 100 parts by weight of the base resins(A)+(B); and (C) 0.01-20 parts by weight of organic titanium compound.
Abstract translation: 目的：提供一种阻燃性热塑性树脂组合物，其在不使用阻燃剂的情况下显示出显着改善的阻燃性，并且使用磷酸酯化合物和有机钛化合物作为阻燃剂。 构成：组合物包含（A）40-100重量份基于由（a1）20-90重量％的含有10-68重量份橡胶组分的含苯乙烯的接枝共聚物树脂组成的橡胶改性苯乙烯的树脂，以及 18〜65重量％的除橡胶成分以外的不饱和腈系单体，和（a2）10-80重量％的含有18-65重量％的不饱和腈基单体的苯乙烯共聚物树脂; （B）0-60重量份聚苯醚树脂; （C）相对于100重量份的基础树脂（A）+（B），1-30重量份的芳族磷酸酯; 和（C）0.01-20重量份的有机钛化合物。
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公开(公告)号：KR1020030006805A
公开(公告)日：2003-01-23
申请号：KR1020010042730
申请日：2001-07-16
Applicant: 제일모직주식회사
IPC: C08K5/521
Abstract: PURPOSE: Provided is a fire retardant thermoplastic resin composition which has good fire retardancy irrespective of the kind of a resin by using en epoxy resin having a good char generating property together with a phosphorus-based compound. CONSTITUTION: The thermoplastic resin composition comprises 100 parts by weight of a thermoplastic resin; 0.1-50 parts by weight of an epoxy derivative represented by the formula 1; 1-50 parts by weight of a phosphorus-based compound; and optionally 0-50 parts by weight of at least one additive selected from the group consisting of a dropping preventer, a plasticizer, a heat stabilizer, an antioxidizing agent, a photo stabilizer, a compatibilizer, a pigment and/or dye and an inorganic additive. In formula 1, X is an alkyl group of C1-C34, an aryl group, an aryl group substituted with an alkyl group, an aralkyl group, or an O, N, P or S-containing alkyl, aryl or aryl group substituted with an alkyl group.
Abstract translation: 目的：本发明提供阻燃热塑性树脂组合物，与具有良好的焦炭产生性能的环氧树脂以及磷系化合物一起，与树脂的种类无关，具有良好的阻燃性。 构成：热塑性树脂组合物包含100重量份的热塑性树脂; 0.1-50重量份由式1表示的环氧衍生物; 1-50重量份的磷系化合物; 和任选的0-50重量份的至少一种选自滴加防止剂，增塑剂，热稳定剂，抗氧化剂，光稳定剂，增容剂，颜料和/或染料和无机物的添加剂 添加剂。 在式1中，X是C1-C34的烷基，芳基，被烷基，芳烷基或被O，N，P或S取代的烷基，芳基或芳基取代的芳基 烷基。
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公开(公告)号：KR1020020053196A
公开(公告)日：2002-07-05
申请号：KR1020000082552
申请日：2000-12-27
Applicant: 제일모직주식회사
CPC classification number: C08L51/04 , C08J2300/22 , C08K3/22 , C08K5/523 , C08K2003/2248 , C08K2201/003 , C08L25/12 , C08L71/12 , C08L2201/02 , C08L2205/025
Abstract: PURPOSE: A thermoplastic flame retardant resin composition and a product prepared by using the composition are provided, to improve the flame retardancy by employing copper compounds without adding char compounds. CONSTITUTION: The composition comprises 100 parts by weight of a rubber-modified styrene-acrylonitrile copolymer resin which comprises (a1) 20-90 wt% of a styrene-acrylonitrile grafted copolymer resin whose rubber content is 10-68 wt% and whose acrylonitrile content except the rubber component is 18-65 wt%, and (a2) 10-80 wt% of a styrene-acrylonitrile grafted copolymer resin whose acrylonitrile content is 18-65 wt%; 2-30 parts by weight of an aromatic phosphate ester compound; and 0.01-20 parts by weight of at least one copper compound selected from the group consisting of oxides, sulfides, chlorides, fluorides, phosphates, sulfates, nitrates and salts of organic acids including monovalent or divalent copper. Optionally the composition comprises further 0-60 parts by weight of a polyphenylene ether resin.
Abstract translation: 目的：提供一种热塑性阻燃树脂组合物和通过使用该组合物制备的产品，以通过使用不添加焦炭化合物的铜化合物来改善阻燃性。 构成：该组合物包含100重量份橡胶改性的苯乙烯 - 丙烯腈共聚物树脂，其包含（a1）20-90重量％的橡胶含量为10-68重量％的苯乙烯 - 丙烯腈接枝共聚物树脂，其丙烯腈含量 橡胶成分为18-65重量％，（a2）10-80重量％丙烯腈含量为18-65重量％的苯乙烯 - 丙烯腈接枝共聚物树脂; 2-30重量份芳族磷酸酯化合物; 和0.01-20重量份的选自氧化物，硫化物，氯化物，氟化物，磷酸盐，硫酸盐，硝酸盐和包括一价或二价铜的有机酸盐的至少一种铜化合物。 任选地，组合物还包含0-60重量份的聚苯醚树脂。
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公开(公告)号：KR1020010055739A
公开(公告)日：2001-07-04
申请号：KR1019990057030
申请日：1999-12-13
Applicant: 제일모직주식회사
Abstract: PURPOSE: A thermoplastic and fire retardant resin composition is provided which has excellent mechanical properties, thermostability, fire retardancy and fluidity and does not contain a halogen compound that causes an environmental pollution when processing or burning the resin. CONSTITUTION: The composition comprises: (A) 40-95 part by weight of rubber denatured styrene resin that comprises (a1) 20-100 part by weight of styrene containing graft copolymer resin having an acrylonitrile content of 18-50 wt.% excepting a rubber part and (a2) 0-80 part by weight of styrene containing copolymer resin having an acrylonitrile content of 18-50 wt.%; (B) 5-60 part by weight of polyphenylene resin; (C) 2-30 part by weight of styrene-acrylonitrile copolymer resin having an acrylonitrile content of 5-18 weight based on 100 part by weight of (A)+(B); (D) 5-50 part by weight of polyethylene resin or rubber reinforced polystyrene resin based on 100 part by weight of (A)+(B); and (E) an aromatic phosphoric acid ester compound based on 100 part by weight of (A)+(B).
Abstract translation: 目的：提供具有优异的机械性能，耐热性，阻燃性和流动性的热塑性和阻燃性树脂组合物，并且不含有在加工或燃烧树脂时引起环境污染的卤素化合物。 组成：该组合物包含：（A）40-95重量份的橡胶变性苯乙烯树脂，其包含（a1）20-100重量份的丙烯腈含量为18-50重量％的含苯乙烯的接枝共聚物树脂，除了 橡胶部分和（a2）0-80重量份丙烯腈含量为18-50重量％的含苯乙烯共聚物树脂; （B）5-60重量份的聚苯树脂; （C）基于100重量份的（A）+（B），丙烯腈含量为5〜18重量份的苯乙烯 - 丙烯腈共聚物树脂为2-30重量份; （D）基于100重量份的（A）+（B），5-50重量份的聚乙烯树脂或橡胶增强聚苯乙烯树脂; 和（E）基于100重量份的（A）+（B）的芳族磷酸酯化合物。
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公开(公告)号：KR1020000046093A
公开(公告)日：2000-07-25
申请号：KR1019980062769
申请日：1998-12-31
Applicant: 제일모직주식회사
CPC classification number: C08L55/02 , C08F12/36 , C08K3/16 , C08K3/22 , C08K3/26 , C08K5/372 , C08L25/04 , C08L25/12 , C08L55/005
Abstract: PURPOSE: A thermoplastic resin composition having a good plasticity and extruding stability is provided which contains one or more divalent compound selected from the group of a divalent metal salt, a divalent metal chloride, a divalent metal carbide and a divalent metal oxide, so it propers to manufacture large plastic goods or curved plastic goods. CONSTITUTION: A thermoplastic resin composition having a good plasticity and extruding stability is composed of 20-50 wt. pts. of copolymer(I) which is made by a copolymerization of rubber copolymer(B) with cyanovinyl compound(A) and aliphaticvinyl compound(S) or (A), (B) and monomer(E), and wherein the weight average molecular weight of the copolymer(II) is 120,000-600,000. The copolymerized weight average molecular weight is more 18,000 by containing 0.01-3 wt. pts. of composition composed of 1-99 wt% of multifunctional mercaptan and 99-1 wt% of vinyl benzene based compound, and contains an ingredient having more 0.6 of intrinsic viscosity. In addition, the thermoplastic resin composition contains 0.001-10 wt. pts. of one or more divalent compound.
Abstract translation: 目的：提供具有良好的塑性和挤出稳定性的热塑性树脂组合物，其含有一种或多种选自二价金属盐，二价金属氯化物，二价金属碳化物和二价金属氧化物的二价化合物，因此它可以 制造大型塑料制品或弯曲塑料制品。 构成：具有良好的塑性和挤出稳定性的热塑性树脂组合物由20-50wt。 点。 的共聚物（I），其通过橡胶共聚物（B）与氰乙烯基化合物（A）和脂族乙烯基化合物（S）或（A），（B）和单体（E）的共聚合而制备，并且其中重均分子量 的共聚物（II）为12万〜60万。 共聚的重均分子量通过含有0.01-3wt。 点。 的组成由1-99重量％的多官能硫醇和99-1重量％的乙烯基苯基化合物组成，并且含有特性粘度更高为0.6的成分。 另外，热塑性树脂组合物含有0.001-10重量％ 点。 的一种或多种二价化合物。
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Patent Agency Ranking
公开(公告)号：KR101611002B1
公开(公告)日：2016-04-08
申请号：KR1020130065013
申请日：2013-06-05
Applicant: 제일모직주식회사
Abstract: 본발명의난연성폴리아미드계수지조성물은난연성이우수하고결정성저하를방지할수 있는것으로서, 폴리아미드계수지; 충진제; 난연제; 및폴리페닐렌설파이드계수지를포함하며, 상기난연제는하기화학식 1로표시되는단위를포함하는중합체를포함하는것을특징으로한다: [화학식 1]상기화학식 1에서, A 및 B는각각독립적으로단일결합, C1-C5의알킬렌기, C1-C5의알킬리덴기, C5-C6의시클로알킬리덴기, -S- 또는 -SO-이고, 단, A 및 B는서로동일하지않으며, R 및 R는각각독립적으로치환또는비치환된 C1-C6의알킬기, 치환또는비치환된 C6-C20의아릴기, 또는 C6-C20의치환또는비치환된아릴옥시기이고, R, R, R및 R는각각독립적으로치환또는비치환된 C1-C6의알킬기, 치환또는비치환된 C3-C6의시클로알킬기, 치환또는비치환된 C6-C12의아릴기또는할로겐원자이며, a, b, c 및 d는각각독립적으로 0 내지 4의정수이고, m은 0 내지 500의정수이며, n은 1 내지 500의정수이다.
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公开(公告)号：KR101489956B1
公开(公告)日：2015-02-06
申请号：KR1020110147917
申请日：2011-12-30
Applicant: 제일모직주식회사
Abstract: 본 발명의 난연성 열가소성 수지 조성물은 방향족 비닐계 수지 및 폴리페닐렌 옥사이드 수지를 포함하는 기초수지 100 중량부; 및 하기 화학식 1로 표시되는 폴리포스포네이트 공중합체 0.1 내지 30 중량부를 포함한다:
[화학식 1]
(상기 식에서, A 및 B는 각각 독립적으로 단일 결합, C
1 -C
5 의 알킬렌, C
1 -C
5 의 알킬리덴, C
5 -C
6 의 시클로알킬리덴, -S- 또는 -SO2-이고, 단, A 및 B는 서로 동일하지 않으며, R5 및 R6은 각각 독립적으로 치환 또는 비치환된 C
1 -C
6 알킬기, 치환 또는 비치환된 C
6 -C
20 인 아릴기 또는 C
6 -C
20 인 치환 또는 비치환된 아릴옥시기이고, R1, R2, R3 및 R4는 각각 독립적으로 치환 또는 비치환된 C
1 -C
6 알킬기, 치환 또는 비치환된 C
3 -C
6 사이클로알킬기, 치환 또는 비치환된 C
6 -C
12 아릴기 또는 할로겐 원자이며, a 및 b는 각각 독립적으로 0 내지 4의 정수, n 및 m은 1 내지 500의 정수임).-
公开(公告)号：KR1020140082348A
公开(公告)日：2014-07-02
申请号：KR1020120152210
申请日：2012-12-24
Applicant: 제일모직주식회사
IPC: C07D307/33 , B01J23/40
CPC classification number: C07D307/33 , B01J21/00 , B01J23/40
Abstract: The present invention relates to a method for producing α-methylenelactone, wherein the method comprises a step of performing the carbonylation reaction of alkynol under the presence of a catalyst in which a platinum group element is dipped, a ligand including a phosphorous atom, and carbon monoxide, and the turn of number (TON) of the catalyst in which a platinum group element is dipped is 1,000 to 25,000. Using the minimum quantity of catalyst, α-methylenelactone can be produced. The catalyst can be easily collected so that the catalyst can be reused for continuous processes.
Abstract translation: 本发明涉及一种α-亚甲基内酯的制造方法，其中，该方法包括在浸渍有铂族元素的催化剂，含有磷原子的配体和碳原子的碳的存在下进行炔醇的羰基化反应的工序 铂族元素浸渍的催化剂的数量（TON）为1000〜25000。 使用最少量的催化剂，可以生产α-亚甲基内酯。 可以容易地收集催化剂，使得催化剂可以再次用于连续过程。
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公开(公告)号：KR1020130078739A
公开(公告)日：2013-07-10
申请号：KR1020110147851
申请日：2011-12-30
Applicant: 제일모직주식회사
IPC: C08G79/04 , C08L85/02 , C08L101/00
Abstract: PURPOSE: A polyphosphate copolymer is provided to improve flame retardancy, transparency, thermal resistance, impact strength, heat resistance, impact strength, and the exterior appearance. CONSTITUTION: A polyphosphate copolymer includes a repeating unit represented by chemical formula 1. In chemical formula 1, A and B is a single bond, a C1-5 alkylene, a C1-5 alkylidene, a C5-6 cycloalkylidene, -S-, or -SO2-; R5 and R6 is a substituted or unsubstituted C1-6 alkyl group, a substituted or unsubstituted C6-20 aryl group, or a C6-20 substituted or unsubstituted aryloxy group; each of R1, R2, R3, and R4 is a substituted or unsubstituted C1-6 alkyl group, a substituted or unsubstituted C3-6 cycloalkyl group, a substituted or unsubstituted C6-12 aryl group, or halogen; each of a and b is an integer from 0-4; and each of n and m is an integer from 1-500.
Abstract translation: 目的：提供聚磷酸酯共聚物以改善阻燃性，透明性，耐热性，冲击强度，耐热性，冲击强度和外观。 构成：聚磷酸酯共聚物包括由化学式1表示的重复单元。在化学式1中，A和B是单键，C1-5亚烷基，C1-5亚烷基，C5-6亚环烷基，-S-， 或-SO 2 - ; R5和R6是取代或未取代的C1-6烷基，取代或未取代的C6-20芳基或C6-20取代或未取代的芳氧基; R 1，R 2，R 3和R 4各自为取代或未取代的C 1-6烷基，取代或未取代的C 3-6环烷基，取代或未取代的C 6-12芳基或卤素; a和b各自为0-4的整数; n和m各自为1-500的整数。
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公开(公告)号：KR1020130078604A
公开(公告)日：2013-07-10
申请号：KR1020110147629
申请日：2011-12-30
Applicant: 제일모직주식회사
Abstract: PURPOSE: A flame retardant thermoplastic resin composition is provided to have physical property balance including not only excellent fire retardant but also excellent transparency, heat resistance, impact strength, and appearance by including biphenyl polyphosphonate in which a biphenyl group is introduced as flame retardant. CONSTITUTION: A flame retardant thermoplastic resin composition comprises; a basic resin which includes an aromatic vinyl resin and polyphenylene oxide resin of 100.0 weight part; and biphenyl polyphosphate of 0.1-30 weight part which is indicated as a chemical formula. The R is hydrogen, a substitution or non-substitution C1-5 alkyl group, a substitution or non-substitution C2-5 alkenyl group, a substitution or non-substitution C5-6 cycloalkyl group, a substitution or non-substitution C5-6 cycloalkenyl group, a substitution or non-substitution C6-20 aryl group, or a substituted or non-substituted C6-20 aryloxy group. The R1 and the R2 are respectively a substitution or non-substitution C1-6 alkyl group, a substitution or the non-substitution C5-6 cycloalkyl group, a substitution or non-substitution C6-12 aryl group, or halogen. The a and b are respectively the fixed number of 0-4. The n is the fixed number of 4-500.
Abstract translation: 目的：提供一种阻燃热塑性树脂组合物，其具有不仅具有优异的阻燃性，而且还包括通过引入联苯基作为阻燃剂的联苯基聚膦酸酯，具有优异的透明性，耐热性，冲击强度和外观的物理性能平衡。 构成：阻燃热塑性树脂组合物包含： 包含100.0重量份的芳族乙烯基树脂和聚苯醚树脂的碱性树脂; 以及重量份为0.1-30重量份的联苯聚磷酸酯，以化学式表示。 R为氢，取代或未取代的C 1-5烷基，取代或未取代的C 2-5烯基，取代或未取代的C 5-6环烷基，取代或未取代的C 5-6 取代或未取代的C6-20芳基，或取代或未取代的C6-20芳氧基。 R1和R2分别为取代或非取代C1-6烷基，取代或非取代C5-6环烷基，取代或未取代的C6-12芳基或卤素。 a和b分别为0-4的固定数。 n是4-500的固定数。
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