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公开(公告)号：KR101610130B1
公开(公告)日：2016-04-08
申请号：KR1020140103467
申请日：2014-08-11
Abstract: 본발명은자동차내외장재용고분자수지조성물, 자동차내외장재용수지성형품및 이의제조방법에관한것으로서, 보다상세하게는폴리프로필렌수지, 폴리유산수지, 유리섬유, 에틸렌반복단위및 (메타)아크릴레이트계반복단위를포함하는공중합체, 및디카르복실산또는이의산무수물이그라프트된폴리프로필렌을포함하는자동차내외장재용고분자수지조성물과수지성형품에관한것이다. 상기자동차내외장재용고분자수지조성물및 수지성형품은바이오매스로부터유래된소재를일정함량이상포함하여친환경적이면서도내열성및 내충격성과같은기계적물성이우수하다.
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公开(公告)号：KR1020150128293A
公开(公告)日：2015-11-18
申请号：KR1020140055411
申请日：2014-05-09
Applicant: 현대자동차주식회사
Abstract: 본발명은 (A) 폴리프로필렌수지 80 ~ 83 중량%; 및 (B) 폴리유산수지 17 ~ 20 중량%를포함하는베이스수지 100 중량부에대해, (C) 충격보강제 5 ~ 10 중량부; (D) 실란계화합물로표면처리한목분 8 ~ 15 중량부; 및 (E) 상용화제 3 ~ 5 중량부를포함하는것을특징으로하는폴리프로필렌-폴리유산복합재조성물및 이의제조방법을제공한다. 본발명은실란계화합물로표면처리한목분을포함함으로써, 베이스수지와의계면상호작용성을증대시켜최종복합재의기계적, 열적물성을향상시키는, 고내열, 내충격성, 인장강도및 굴곡강도등의물성밸런스가우수하여자동차내장재부품으로더욱적합하게사용될수 있다.
Abstract translation: 提供聚丙烯 - 聚乳酸复合组合物及其制造方法。 该组合物包含：（C）5至10重量份的冲击增强剂; （D）8〜15重量份用硅烷类化合物表面处理的木粉; 和（E）相对于100重量份的基础树脂为3〜5重量份的相容剂，其包含：（A）80〜83重量％的聚丙烯树脂; 和（B）17〜20重量％的聚乳酸树脂。 通过包含用硅烷类化合物表面处理的木粉，可以更适当地使用组合物作为车辆内部部件，因为诸如高耐热性，高抗冲击性，抗拉强度，挠曲强度等的性能平衡， 通过增加与基础树脂的界面相互作用来提高最终复合材料的化学和热性能是优异的。
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公开(公告)号：KR101567196B1
公开(公告)日：2015-11-06
申请号：KR1020140028747
申请日：2014-03-12
Applicant: 현대자동차주식회사
Abstract: 본발명은고강성및 내열성이우수한폴리프로필렌-폴리유산복합재료조성물에관한것으로서, 더욱상세하게는폴리프로필렌수지와 L- 혹은 D-폴리유산수지가일정함량비로포함된수지성분에, 첨가제로서충격보강제, 유리섬유, 핵제및 상용화제가일정함량비로포함되어있음으로써폴리유산의내열성, 내충격성, 인장강도및 굴곡강도등의물성을크게보강하게되므로범용고분자소재의대체가가능한폴리프로필렌-폴리유산복합재료조성물에관한것이다.
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公开(公告)号：KR1020150106548A
公开(公告)日：2015-09-22
申请号：KR1020140028747
申请日：2014-03-12
Applicant: 현대자동차주식회사
Abstract: 본 발명은 고강성 및 내열성이 우수한 폴리프로필렌-폴리유산 복합재료 조성물에 관한 것으로서, 더욱 상세하게는 폴리프로필렌 수지와 L- 혹은 D-폴리유산 수지가 일정 함량비로 포함된 수지성분에, 첨가제로서 충격보강제, 유리섬유, 핵제 및 상용화제가 일정 함량비로 포함되어 있음으로써 폴리유산의 내열성, 내충격성, 인장강도 및 굴곡강도 등의 물성을 크게 보강하게 되므로 범용 고분자 소재의 대체가 가능한 폴리프로필렌-폴리유산 복합재료 조성물에 관한 것이다.
Abstract translation: 本发明涉及具有高强度和耐热性的聚丙烯 - 聚乳酸复合材料组合物。 更具体地，该组合物具有树脂组分，其包含聚丙烯树脂和具有预定含量比的L-聚乳酸树脂或D-聚乳酸树脂，以及添加剂如抗冲改性剂，玻璃纤维，成核剂， 和以预定含量比包含的增容剂。 因此，本发明能够显着地增强包括耐热性，赋予电阻，拉伸强度和弯曲强度的聚乳酸的物理性能并代替通用聚合物材料。
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公开(公告)号：KR101428340B1
公开(公告)日：2014-08-07
申请号：KR1020120157953
申请日：2012-12-31
Applicant: 현대자동차주식회사
IPC: C07D319/10 , B01J6/00 , C07B61/00
CPC classification number: C07D319/12
Abstract: 본 기술은 용매를 이용한 락타이드 제조방법으로서, 락타이드를 제조할 때 두번째 단계에서 이온성 액체를 용매로 사용하여 반응물의 모빌러티를 확보하여 반응 온도를 낮추고 반응 중 발생하는 수분을 이온성 액체에서 흡수하여 수분에 취약한 락타이드가 분해가 일어나지 않도록 할 수 있다. 뿐만 아니라 지속적인 올리고머 투입에 의한 연속적인 락타이드 제조가 가능하게 된다. 이온성 액체에 의해 반응 부산물에 의한 반응기 오염이 최소화되어 반응기 세척을 위한 용매가 불필요하게 된다. 더불어 이온성 액체의 높은 끓는점으로 인해 이온성 액체의 회수 및 재활용도 용이한 장점이 있다.
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Patent Agency Ranking
公开(公告)号：KR101338197B1
公开(公告)日：2013-12-06
申请号：KR1020120103979
申请日：2012-09-19
Applicant: 현대자동차주식회사
IPC: C09J167/04 , C08L67/04 , C09J7/02
CPC classification number: C09J167/04 , C08L67/04 , C09J7/35 , C09J7/385 , C09J2201/61
Abstract: The present invention relates to a polylactic acid resin composition for a hot-melt adhesive film, more specifically, to a polylactic acid resin composition for a hot-melt adhesive film, wherein the composition reduces foul odor and improves adhesion by mixing a linear low density polyethylene resin, an acrylate comonomer resin with good adhesion to a fiber material, and a low carbon polylactic acid resin obtained from biomass at an optimal ratio and can be utilized in environment-friendly automotive parts by containing 20% or more biomass.
Abstract translation: 本发明涉及一种用于热熔粘合剂膜的聚乳酸树脂组合物，更具体地说，涉及一种用于热熔粘合剂膜的聚乳酸树脂组合物，其中该组合物通过混合线性低密度 聚乙烯树脂，与纤维材料具有良好粘附性的丙烯酸酯共聚单体树脂和以最佳比例从生物质获得的低碳聚乳酸树脂，并且可以通过含有20％以上的生物质用于环境友好的汽车部件。
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公开(公告)号：KR1020130112463A
公开(公告)日：2013-10-14
申请号：KR1020120034861
申请日：2012-04-04
Applicant: 현대자동차주식회사
Abstract: PURPOSE: A method for preparing D-type lactic acids is provided to obtain high purity D-type lactic acids of high yield by separating generated lactic acids through selective absorption/desorption using an activated carbon stick and to largely save time and costs. CONSTITUTION: A method for preparing D-type lactic acids from sugar through fermentation comprises the steps of: adding microorganisms to sugar in a fermentation reactor and preparing a fermented liquid; adding a sterilized stick to the fermentation reactor and adsorbing lactic acids; isolating the lactic acid-adsorbed activated carbon stick from the fermentation reactor and precipitating the lactic acid-adsorbed activated carbon stick in a collection reactor; and desorbing lactic acids in an acetic solvent contained in the collection reactor and collecting D-type lactic acids. [Reference numerals] (AA) Fermentation reactor; (BB) Move after taking out
Abstract translation: 目的：提供一种制备D-型乳酸的方法，通过使用活性炭棒通过选择性吸收/解吸分离生成的乳酸，从而大大节省时间和成本，从而获得高产率的高纯度D型乳酸。 构成：通过发酵从糖制备D-型乳酸的方法包括以下步骤：在发酵反应器中加入微生物至糖并制备发酵液; 向发酵反应器中加入灭菌棒并吸附乳酸; 从发酵反应器中分离乳酸吸附的活性炭棒，并将收集反应器中的乳酸吸附的活性碳棒沉淀; 并在收集反应器中包含的乙酸溶剂中解吸乳酸并收集D型乳酸。 （标号）（AA）发酵反应器; （BB）取出后移动
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公开(公告)号：KR1020130022556A
公开(公告)日：2013-03-07
申请号：KR1020110085182
申请日：2011-08-25
IPC: C08G63/08 , C08G63/78 , C08L67/04 , C08L101/16
CPC classification number: C08G63/08 , C08G63/81 , C08J9/28 , C08J2367/04 , Y02P20/544
Abstract: PURPOSE: A manufacturing method for a polylactide stereoisomeric composite is provided to have excellent heat resistance and mechanical stability using a small amount of an organic solvent. CONSTITUTION: A manufacturing method for a polylactide stereoisomeric composite comprises: a step of putting a poly D-lactide-caprolactone copolymer and a poly L-lactide type polymer into a reactor; and a step of adding an organic solvent into the reactor, and putting a supercritical fluid in order to polymerize the two polymers to the polylactide stereoisomeric composite. The copolymerizing ratio of the poly D-lactide-caprolactone copolymer and the poly L-lactide type polymer is 99.5:0.5-70:30, and the poly D-caprolactone copolymer has a weight-average molecular weight of 70,000-300,000 Da.
Abstract translation: 目的：提供一种聚丙交酯立体异构体复合体的制造方法，其具有优异的耐热性和使用少量有机溶剂的机械稳定性。 构成：聚丙交酯立体异构体复合体的制造方法包括：将聚D-丙交酯 - 己内酯共聚物和聚L-丙交酯型聚合物投入反应器的工序; 以及将有机溶剂添加到反应器中的步骤，以及将超临界流体置于聚丙交酯立体异构体复合物中以使两种聚合物聚合。 聚D-丙交酯 - 己内酯共聚物和聚L-丙交酯型聚合物的共聚比为99.5:0.5-70:30，聚D-己内酯共聚物的重均分子量为70,000〜300,000Da。
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公开(公告)号：KR1020130014717A
公开(公告)日：2013-02-12
申请号：KR1020110076017
申请日：2011-07-29
Applicant: 현대자동차주식회사 , 한국기술교육대학교 산학협력단
CPC classification number: C08J3/005 , C08J5/18 , C08J2367/04 , C08L67/04 , C08L2205/02
Abstract: PURPOSE: A manufacturing method of a polylactic acid film is provided to stably and effectively manufacture a film with stereocomplex crystals without homo polylactic acid. CONSTITUTION: A manufacturing method of a polylactic acid film comprises: a step of manufacturing poly-L-lactic acid and poly-D-lactic acid in a solvent; and a step of evaporating the solvent to cast a polylactic acid mixture solution. The solvent satisfies formula 1:y=0.0042x^2-0.2769x+10+/-5. In the formula 1, x is the boiling point of the solvent, and y is the time to evaporate the solvent. The comprised amount of the poly-L-lactic acid and poly-D-lactic acid are 5-10 parts by weight. [Reference numerals] (AA) L-type PLA resin; (BB) D-type PLA resin; (CC) Collecting solvent; (DD) Spraying L, D type LPA resin + solvent molten resin; (EE) Nitrogen
Abstract translation: 目的：提供聚乳酸膜的制造方法，以稳定且有效地制造没有均聚乳酸的立体络合物晶体的膜。 构成：聚乳酸薄膜的制造方法包括：在溶剂中制造聚-L-乳酸和聚-D-乳酸的工序; 以及蒸发溶剂以浇铸聚乳酸混合物溶液的步骤。 溶剂满足式1：y = 0.0042×^ 2-0.2769x + 10 +/- 5。 在式1中，x是溶剂的沸点，y是蒸发溶剂的时间。 聚-L-乳酸和聚-D-乳酸的含量为5-10重量份。 （AA）L型PLA树脂; （BB）D型PLA树脂; （CC）收集溶剂; （DD）喷涂L，D型LPA树脂+溶剂熔融树脂; （EE）氮
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公开(公告)号：KR1020130013226A
公开(公告)日：2013-02-06
申请号：KR1020110074749
申请日：2011-07-27
Applicant: 현대자동차주식회사
CPC classification number: C12P7/56
Abstract: PURPOSE: A method for preparing type D lactic acid is provided to quickly and cheaply prepare the type D lactic acid. CONSTITUTION: A method for preparing type D lactic acid with high optical purity comprises a step of culturing E.coli(KCTC 2223) at constant temperature and pH. The pH concentration is controlled by supplying an ammonium solution(NH_4OH). The optical purity of the type D lactic acid is 99% or more. The E.coli is cultured by batch culture or continuous culture under an anaerobic condition. [Reference numerals] (AA) Stain; (BB) Glucose; (CC) Fermenter; (DD) Fungus body separation; (EE) Culture medium; (FF) D lactic acid
Abstract translation: 目的：提供一种制备D型乳酸的方法，以快速，便宜地制备D型乳酸。 构成：用于制备高光学纯度的D型乳酸的方法包括在恒温和pH下培养大肠杆菌（KCTC 2223）的步骤。 通过提供铵溶液（NH_4OH）来控制pH浓度。 D型乳酸的光学纯度为99％以上。 大肠杆菌通过分批培养或在厌氧条件下连续培养来培养。 （附图标记）（AA）染色; （BB）葡萄糖; （CC）发酵罐; （DD）真菌分离; （EE）培养基; （FF）D乳酸
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