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公开(公告)号：JPH01249101A
公开(公告)日：1989-10-04
申请号：JP7967588
申请日：1988-03-31
Applicant: AGENCY IND SCIENCE TECHN
Inventor： MIZOGUCHI KENSAKU , YAMAMOTO MASAHIDE
Abstract: PURPOSE:To concentrate a soln. with high efficiency by saving energy consumption by evaporating a solvent in the soln. continuously from a side of a porous material exhibiting capillary phenomenon. CONSTITUTION:A porous material 1 is dipped in a soln. 2 by disposing the material perpendicularly to the soln. A solvent or a volatile component in the soln. rises through the porous material and is allowed to contact with air 4 at a neighborhood 3 of the highest part. The solvent or the volatile component in the soln. 2 is evaporated by the air stream, and an amt. of the soln. corresponding to the evaporated amt. rises through the porous material and concentrated continuously. A desired component is allowed to react efficiently by concentrating the component and carrying out the reaction in the concentrated state of the component if a catalyst, enzyme, or fungus body is previously deposited or immobilized to the porous material. If the process is applied to alcohol fermentation or hydrolysis of an ester, generated alcohol is removed with saved energy consumption, and the hydrolysis of the ester is prompted.
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公开(公告)号：JPH01171619A
公开(公告)日：1989-07-06
申请号：JP33108087
申请日：1987-12-26
Applicant: AGENCY IND SCIENCE TECHN , NICHIBI KK
Inventor： YAMAMOTO MASAHIDE , MIZOGUCHI KENSAKU , YAMAUCHI AIZO , KUMETA KAZUHIRO
Abstract: PURPOSE:To obtain a hollow yarn membrane having high gas separating capacity by using a soln. contg. a polymer which is soluble or dispersible in a coagulating liquid as an internal coagulating liquid in a stage of producing a poly(ether)sulfone type hollow yarn membrane. CONSTITUTION:A hollow yarn membrane is produced by feeding a spinning soln. comprising polysulfone or polyethersulfone together with an internal coagulating liquid contg. a polymer soluble or dispersible in a coagulating liquid such as polyethylene oxide, silicone, polyvinyl alcohol, etc., through a double spinning nozzle into a coagulating liquid. Thus, the polymer contained in the internal coagulating liquid is coated on the inside of a hollow yarn membrane, or the polymer is filled in defects such as pores or cracks. Thus, the yarn is reinforced. Thus, a hollow yarn membrane having high gas separation capacity useful for oxygen enrichment, etc., is obtd. by a simple one stage process.
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公开(公告)号：JPS6344638A
公开(公告)日：1988-02-25
申请号：JP18983486
申请日：1986-08-13
Applicant: AGENCY IND SCIENCE TECHN
Inventor： ITO SHOJI , MIZOGUCHI KENSAKU , SUDA MASAO
IPC: G02F1/19
Abstract: PURPOSE:To obtain a distinct image having high contrast and high resolution by sandwiching a soln. consisting of three components; a solvent, N-substd. acrylamide polymer are polyvinyl pyrolidone or PE glycol as a high-polymer dispersion stabilizer between a pair of substrates formed with heating elements on the surfaces. CONSTITUTION:This element has the substrate 1, a polymer liquid layer 2, a transparent protective plate 3 and an IR absorption layer 8 corresponding to the heating element. The polymer liquid layer 2 is the liquid layer consisting of the soln. contg. the N-substd. acrylamide polymer, for which; for example, the polymers obtainable from monomers such as N-isopropylacrylamide or N-isopropyl methacrylamide or the copolymers thereof or the copolymers essentially consisting thereof, etc., are adequate. Polyvinyl pyrolidone, PE glycol, etc., are adequate as the high-polymer dispersion stabilizer to be used.
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34.发明专利
公开(公告)号：JPS62243608A
公开(公告)日：1987-10-24
申请号：JP8754986
申请日：1986-04-16
Applicant: AGENCY IND SCIENCE TECHN
Inventor： ITO SHOJI , MIZOGUCHI KENSAKU , SUDA MASAO
IPC: C08F20/56 , C08F20/52 , C08F120/56
Abstract: PURPOSE:To produce the titled polymer having thermal reversibility to become hydrophobic at high temperature and reversibly convertible between a water-soluble state at low temperature and water-insoluble state at high temperature, in high efficiency, by the radical polymerization of N-methyl-N- isopropylacrylamide. CONSTITUTION:The objective polymer of formula II is produced by the radical polymerization of N-methyl-N-isopropylacrylamide of formula I usually in the form of a 1-80wt% solution under radiation of actinic ray, heating in the presence of radical polymerization initiator or radiating light in the presence of a photo-sensitizer, etc. USE:Light-shielding material for greenhouse or chemical laboratory, etc., temperature sensor, toys, interior goods, mechanochemical element material, etc.
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公开(公告)号：JPS62242654A
公开(公告)日：1987-10-23
申请号：JP8755186
申请日：1986-04-16
Applicant: AGENCY IND SCIENCE TECHN
Inventor： ITO SHOJI , MIZOGUCHI KENSAKU , SUDA MASAO
IPC: C08F20/56 , C07C233/09 , C08F20/00 , C08F20/52
Abstract: NEW MATERIAL:A vinyl compound shown by the formula. USE:Useful as a raw material monomer for hydrophilic-hydrophobic heat reversible high polymer compound usable for glare protecting material, temperature sensor, adsorbent, toy, interior, printing agent, display, separating membrane, mechano-chemical element material, etc. PREPARATION:Acrylic acid chloride is reacted with methylisopropylamine and triethylamine in a solvent such as benzene, etc., at 0-10 deg.C to give a vinyl compound shown by formula.
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Patent Agency Ranking36.发明专利
公开(公告)号：JPS62152503A
公开(公告)日：1987-07-07
申请号：JP29395485
申请日：1985-12-26
Applicant: AGENCY IND SCIENCE TECHN
Inventor： MIZOGUCHI KENSAKU , YAMAMOTO MASAHIDE , SUDA MASAO
Abstract: PURPOSE:To regulate the concn. of a component by evaporating the desired component in a liquid to be treated not only from the surface of a liquid layer but also from the interior thereof, by a method wherein the liquid to be treated is supported by or a allowed to flow on the surface of a film a thin layer form and gas is transmitted through the liquid layer from the back surface of the film. CONSTITUTION:A liquid to be treated is pumped up from a liquid storage tank 7 by a pump 8 and passed through a flowmeter 9 and a thermostatic tank 10 to be sent into the inside route of a hollow yarn membrane through a pipeline 11. Further, gas passes through the thin layer of the liquid to be treated transmitted through the hollow yarn membrane and flowing down to be discharged. Because a gas flowing inside route is closed by a valve 16, the transmission of the gas from the inside of the hollow yarn membrane to the outside thereof is enabled. The treated liquid of which the concn. was regulated by evaporation flows out from the liquid side lower end outlet 12 of a membrane separator 6 to be stored in a liquid storage tank 13. The temp. in the separator can be measured by the thermocouple 14 inserted in said separator and the flow amount of the liquid to be treated can be regulated by the pump 8 and the flow amount of the gas can be regulated by a pressure regulating valve 2.
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公开(公告)号：JPS62148504A
公开(公告)日：1987-07-02
申请号：JP29010085
申请日：1985-12-23
Applicant: AGENCY IND SCIENCE TECHN
Inventor： ITO SHOJI , MIZOGUCHI KENSAKU , SUDA MASAO
IPC: C08F20/58 , C08F20/52 , C08F120/58 , C08K3/20 , C08L37/00
Abstract: PURPOSE:To produce the titled polymer, having thermal reversibility of becoming soluble in water at low temperatures and insoluble at high temperatures and useful for light shielding materials, temperature sensors, interiors, etc., by radically polymerizing a specific vinyl compound. CONSTITUTION:A polymer, obtained by radically polymerizing a vinyl compound expressed by formula I (R1 is H or CH3), e.g. N-tetra hydrofurfurylmethacrylamide, N-tetrahydrofurfurylmethacrylamide, etc., in a 1-80wt% solution prepared by dissolving in a solvent, preferably N,N- dimethylformamide, THF, etc., by a solution polymerization method and expressed by formula II (n is an integer of >=2). The vinyl compound expressed by formula I is obtained by reacting a (meth)acryloyl chloride expressed by formula III with tetrahydrofurfurylamine expressed by formula IV and triethylamine expressed by formula V in benzene at 0-10 deg.C.
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公开(公告)号：JPS62148478A
公开(公告)日：1987-07-02
申请号：JP29009985
申请日：1985-12-23
Applicant: AGENCY IND SCIENCE TECHN
Inventor： ITO SHOJI , MIZOGUCHI KENSAKU , SUDA MASAO
IPC: C07D307/14 , C07D307/52 , C08F20/52 , C08F20/58
Abstract: NEW MATERIAL:A vinyl compound of the formula (R1 is H, methyl). EXAMPLE:N-tetrahydrofrufrylacrylamide. USE:Starting monomer for hydrophilic-hydrophobic thermally reversible polymer which is used in light shielder, temperature sensor, adsorbent, toys, interior commodity, printing dye, display, separation membrane and mechanochemical element. PREPARATION:For example, the reaction of acryloyl or methacryloyl chloride with tetrahydrofrufrylamine is carried out in the presence of triethylamine in a solvent, preferably at 0-10 deg.C to give a compound of formula I.
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公开(公告)号：JPS61225166A
公开(公告)日：1986-10-06
申请号：JP6461785
申请日：1985-03-28
Applicant: AGENCY IND SCIENCE TECHN
Inventor： FURUYA SETSUKO , MIZOGUCHI KENSAKU
IPC: C07D215/38 , C08F12/00 , C08F112/14 , C09K3/00
Abstract: NEW MATERIAL:5-(4'Styrenesulfonylamino)quinoline shown by the formula. USE:A raw material for producing a polymer or copolymer useful as a metallic scavenger, a metal indicating polymer showing change in color depending upon kind of metallic ion, etc. PREPARATION:5-Aminoquinoline is reacted with 4-styrenesulfonyl halide in a molar ratio of 1:0.9-0.9:1 in a basic solvent such as pyridine while cooling them to
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公开(公告)号：JPH087870A
公开(公告)日：1996-01-12
申请号：JP14354694
申请日：1994-06-24
Applicant: HONDA MOTOR CO LTD , AGENCY IND SCIENCE TECHN
Inventor： MASUOKA TOSHIO , MIZOGUCHI KENSAKU , MINAMI TATSURO
IPC: H01M2/16
Abstract: PURPOSE:To increase retention of electrolyte, and enhance productivity and stability in quality by letting vinyl compounds be chemically reacted through graft polymerization after material made of resin in a polyolefin system has been treated through cold plasma process by radio waves. CONSTITUTION:Separator material W for a secondary battery in a alkaline system comes in a form of a film or unwoven cloth made out of resin in a polyolefin system stable against alkali, it is moistened by alcohol, and housed in a reaction tank 2 after it has been cleaned by pure water. The reaction tank 2 is filled with inert gas under a pressure of 0.05 to 5Torr, and the radio wave of 13.56kHz is irradiated from a radio wave irradiating electrode 3 so as to allow plasma process to be carried out. In this case, the output of radio waves to the material W shall preferably be 0.07 to 0.30W/cm , and process time shall preferably be 5 seconds to 10 minutes. Next, vapor of vinyl compound monomer M is introduced into the reaction tank 2 from a reservoir tank 9, and it is preferably processed within gaseous phase for 30 seconds to 10 minutes so as to be chemically reacted through graft polymerization. Since these reforming is carried out in a short time, productivity is thereby excellent.
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