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公开(公告)号:ES2059579T3
公开(公告)日:1994-11-16
申请号:ES89101850
申请日:1989-02-03
Applicant: BASF AG
Inventor: PAYNE ROBERT DR , GOETZ WALTER DR , WOLF UWE
IPC: C08L77/00 , C09D177/00
Abstract: The filler-containing thermoplastic moulding compositions contain, as essential components,… A) from 42 to 90 % by weight of a thermoplastic polyamide,… B) from 9.5 to 55 % by weight of fibrous or particulate fillers or mixtures thereof, and… C) from 0.5 to 3 % by weight of an impact-modifying rubber containing reactive groups.
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公开(公告)号:DE4231929A1
公开(公告)日:1994-03-31
申请号:DE4231929
申请日:1992-09-24
Applicant: BASF AG
Inventor: HURLEY JAMES DR , GOETZ WALTER DR , PELLKOFER ERICH , LOHRBAECHER VOLKER , FISCH HERBERT DR , ULMERICH KARLHEINZ , HOFMANN JUERGEN
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公开(公告)号:DE4202004C2
公开(公告)日:1994-03-24
申请号:DE4202004
申请日:1992-01-25
Applicant: BASF AG
Inventor: MCKEE GRAHAM DR , GOETZ WALTER DR , PIPPER GUNTHER , BLINNE GERD DR , SCHLICHTING KARL DR , CORDES CLAUS DR , FLOS JOSEF-GEORG DR , MATTERN GUENTHER DIPL ING , HILDENBRAND PETER DR , HURLEY JAMES DR
Abstract: A process for the preparation of filler-containing thermoplastic moulding compositions by mixing fillers with thermoplastics in the melt, where a) the fillers are mixed in a mixing device in the melt with a low-molecular-weight thermoplastic having a maximum melt viscosity of 30 Pas (measured at a temperature of 20 DEG C above the melting point of the thermoplastic and at a shear gradient of 1 000 s ), b) the resultant product is discharged from the mixing device, cooled and comminuted, and c) the comminuted product in the solid phase is subsequently subjected to post-condensation.
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公开(公告)号:ES2045693T3
公开(公告)日:1994-01-16
申请号:ES90116438
申请日:1990-08-28
Applicant: BASF AG
Inventor: MUEHLBACH KLAUS DR , GOETZ WALTER DR , OSTERMAYER BERTRAM DR
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公开(公告)号:DE59003323D1
公开(公告)日:1993-12-09
申请号:DE59003323
申请日:1990-08-28
Applicant: BASF AG
Inventor: MUEHLBACH KLAUS DR , GOETZ WALTER DR , OSTERMAYER BERTRAM DR
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公开(公告)号:DE4216042A1
公开(公告)日:1993-11-18
申请号:DE4216042
申请日:1992-05-15
Applicant: BASF AG
Inventor: GOETZ WALTER DR , BETZ WALTER DR
Abstract: Thermoplastic moulding compositions obtainable by mixing A) from 0.5 to 5% by weight of a carboxyl-containing polyethylene wax having a mean molecular weight Mn (number average) of from 500 to 20,000 and B) from 0 to 50% by weight of fibrous or particulate fillers, or mixtures thereof, into a melt of C) from 40 to 99.5% by weight of a polyamide prepolymer having a viscosity index of from 40 to 80 ml/g, and subsequently post-condensing the mixture in the solid phase.
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公开(公告)号:DE4207246A1
公开(公告)日:1993-09-09
申请号:DE4207246
申请日:1992-03-07
Applicant: BASF AG
Inventor: GOETZ WALTER DR
IPC: C08K3/04
Abstract: Low-wear thermoplastic moulding materials (I) are claimed, contg. (A) 39-99.99 wt.% thermoplastic polymer, (B) 0.01-5 wt.% of a fullerene and (C) 0-60 wt.% normal additives. (I) pref. contain 99-99.9 wt.% (A) and 0.1-1 wt.% (B). (A) pref. consists of polyamide, PPE, polystyrene, polyethylene, polypropylene, polyester, polycarbonate, polyoxymethylene, ABS, SAN, ASA or a mixt. thereof. (B) is an opt. fluorinated 60C and/or 70C carbon modification (fullerene). (B) is prepd., e.g. by high-temp. vaporisation of graphite (d.c. heating) in a noble gas atmos. to give "carbon soot", followed by chromatography, fractional sublimation or extn. to give a mixt. contg. 10-30% 60C and 10% 70C fullerenes. (C) are, e.g. impact modifiers, stabilisers, PE wax, pigments, fire retardants etc.. USE/ADVANTAGE - For prodn. of moulded prods.. Also claimed are moulded prods. obtd. from (I). The incorporation of fullerenes gives moulding materials with improved abrasion resistance, suitable esp. for the prodn. of machine components, e.g. ball-bearing cage
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公开(公告)号:DE59001378D1
公开(公告)日:1993-06-17
申请号:DE59001378
申请日:1990-01-03
Applicant: BASF AG
Inventor: GOETZ WALTER DR , MC KEE GRAHAM EDMUND DR
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公开(公告)号:DE4133515A1
公开(公告)日:1993-04-15
申请号:DE4133515
申请日:1991-10-10
Applicant: BASF AG
Inventor: BRIGHT THERESA ANNE DR , GOETZ WALTER DR , PLACHETTA CHRISTOPH DR , LAUN MARTIN DR
IPC: C08L67/02
Abstract: Compsns. (I) contain; (A) 40-99.5 % (all pts.wt.) thermoplastic polyester with viscosity no. (DIN 53 726, 0.5% in 1:1 mixt. of phenol and o-dichlorobenzene at 23 deg.C) (VA) 90-300 ml/g; (B) 0.5-10 % low mol. thermoplastic polyamide with viscosity no. (ISO 307, 0.5% in 96% H2SO4 at 25 deg.C) (VA) 30-100 ml/g, where VA-VB is at least 30; (C) 0-50% fibrous or particulate fillers or their mixts., (D) 0-40% rubber-elastic polymer; (E) 0-30% conventional additives. Pref. VA = 100-200 ml/g. VB = 40-80 ml/g. VA-VB is at least 50. (I) contain 50-99% (A) and 1-5% (B). (A) is PET and/or polybutylene terephthalate (II). (B) is polyhexamethylene adipamide (III) and/or polycaprolactam and/or partly aromatic partly crystalline copolyamide. USE/ADVANTAGE - Prepn. of fibres, films, and moulded articles partic. in the motor vehicle industry. (I) have improved flowability compared with compsns. not contg. (B), independently of amt. and type of (E), reduced cycle time, and improved toughness with greater plastic deformation before final break
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